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羊蹄子山-磨石山钛矿床的钛矿物主要为锐钛矿、金红石和钛铁矿。锐钛矿化学成分的特点是FeO含量明显比金红石要低;主要X光粉晶谱线为3.518(100)、2.377(14)和1.667(11);晶胞参数a()=3.786,c()=9.513;拉曼光谱谱线(cm-1)为516、395、195和143。金红石的主要X光粉晶谱线为3.250(100)、1.688(40)和2.488(29);晶胞参数为a()=4.595,c()=2.962;拉曼光谱谱线(cm-1)为610和446。钛铁矿的成分特点是富锰贫镁,与攀西地区岩浆型钒钛磁铁矿矿床中的钛铁矿正好相反。所有上述钛(铁)氧化物矿物学特征,进一步说明该矿床是在中元古代在海底与基性火山活动有关的热水沉积后经区域变质和局部又遭受后期热液改造而成。 相似文献
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Ore and Skarn Mineralogy of the Yamato Mine,Yamaguchi Prefecture,Japan, with Emphasis on Silver‐, Bismuth‐, Cobalt‐, and Tin‐bearing Sulfides 下载免费PDF全文
Assemblages and chemical compositions of ore minerals from the Yamato mine, Yamaguchi Prefecture, Japan, were investigated in detail to clarify its characteristics as a skarn deposit. Special attention was paid to silver‐, bismuth‐, cobalt‐, and tin‐bearing sulfide minerals and native gold at the mine, which are described here for the first time. Samples of arsenopyrite‐dominant massive ore, and garnet‐rich, clinopyroxene‐garnet‐rich, and wollastonite‐bearing skarn ores were collected from the mine dump. Arsenopyrite is the most abundant ore mineral (>80 vol.%) in the massive ore, in association with both As‐poor/free and As‐bearing pyrite. The major ore minerals in the skarn specimens are pyrite, pyrrhotite, arsenopyrite, chalcopyrite, galena, and sphalerite, along with minor argentite, Ag‐Pb‐Bi sulfate, matildite, bismuthinite, native bismuth, molybdenite, scheelite, stannite, stannoidite, cassiterite, cobaltite, gersdorffite, and Co‐rich violarite. In addition, native gold is observed in the interstices of gangue minerals. Based on the mineral assemblages and textures of the specimens examined, the major ore minerals formed in the early stage of mineralization, and the Bi‐, Ag‐, Co‐, Ni‐, As‐ and Sn‐mineralization occurred in the middle stage. Native gold was deposited in the late stage. The estimated formation temperature of the middle mineralization stage was 312±5 °C, according to iron and zinc partitioning between stannite and coexisting sphalerite. The mineralogical properties and mineralization process of the Yamato mine are consistent with those of common skarn‐ and vein‐type ore deposits associated with ilmenite‐series granitoids in the San‐yo and San‐in districts. 相似文献
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Apatite Composition of Representative Magnetite‐series and Ilmenite‐series Granitoids in Japan 下载免费PDF全文
Apatites of representative magnetite‐series and ilmenite‐series granitoids were studied in the Japanese Islands. Concentrations of the volatile components F, Cl and SO3 are differently distributed in apatites of these granitoid series. Apatites are always fluoroapatite. They have weakly higher F content in the ilmenite series than in the magnetite series. In contrast, Cl and SO3, are significantly concentrated in apatites of the magnetite series compared to the ilmenite series. These characteristics reflect the original concentrations of these components in the host granitic magmas. A high fO2 seems most important for the S‐concentration as sulfate in apatite of the magnetite series. REE and Y are only erratically high in the studied apatites. 相似文献
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Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification 下载免费PDF全文
Zhen Li Zhaochu Hu Detlef Günther Keqing Zong Yongsheng Liu Tao Luo Wen Zhang Shan Gao Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(4):477-491
Ilmenite (FeTiO3) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised 57Fe and 49Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm?2 and fs‐LA‐ICP‐MS. 相似文献
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Alfons M. van den Kerkhof Geoffrey H. Grantham 《Contributions to Mineralogy and Petrology》1999,137(1-2):115-132
In the Port Edward area of southern Kwa-Zulu Natal, South Africa, charnockitic aureoles up to 10 m in width in the normally
garnetiferous Nicholson's Point Granite, are developed adjacent to intrusive contacts with the Port Edward Enderbite and anhydrous
pegmatitic veins. Mineralogical differences between the country rock and charnockitic aureole suggest that the dehydration
reaction Bt + Qtz → Opx + Kfs + H2O and the reaction of Grt + Qtz → Opx + Pl were responsible for the charnockitization. The compositions of fluid inclusions
show systematic variation with: (1) the Port Edward Enderbite being dominated by CO2 and N2 fluid inclusions; (2) the non-charnockitized granite by saline aqueous inclusions with 18–23 EqWt% NaCl; (3) the charnockitic
aureoles by low-salinity and pure water inclusions (<7 EqWt% NaCl); (4) the pegmatites by aqueous inclusions of various salinity
with minor CO2. As a result of the thermal event the homogenization temperatures of the inclusions in charnockite show a much larger range
(up to 390 °C) compared to the fluid inclusions in granite (mostly <250 °C). Contrary to fluid-controlled charnockitization
(brines, CO2) which may have taken place along shear zones away from the intrusive body, the present “proximal” charnockitized granite
formed directly at the contact with enderbite. The inclusions indicate contact metamorphism induced by the intrusion of “dry”
enderbitic magma into “wet” granite resulting in local dehydration. This was confirmed by cathodoluminescence microscopy showing
textures indicative for the local reduction of structural water in the charnockite quartz. Two-pyroxene thermometry on the
Port Edward Enderbite suggests intrusion at temperatures of ∼1000–1050 °C into country rock with temperature of <700 °C. The
temperature of aureole formation must have been between ∼700 °C (breakdown of pyrite to form pyrrhotite) and ∼1000 °C. Charnockitization
was probably controlled largely by heat related to anhydrous intrusions causing dehydration reactions and resulting in the
release and subsequent trapping of dehydration fluids. The salinity of the metamorphic fluid in the contact zones is supposed
to have been higher at an early stage of contact metamorphism, but it has lost its salt content by K-metasomatic reactions
and/or the preferential migration of the saline fluids out of the contact zones towards the enderbite. The low water activity
inhibited the localized melting of the granite. Mineral thermobarometry suggests that after charnockite aureole genesis, an
isobaric cooling path was followed during which reequilibration of most of the aqueous inclusions occurred.
Received: 8 November 1998 / Accepted: 21 June 1999 相似文献
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金红石中铁的存在形式的研究 总被引:4,自引:2,他引:4
本文对我国不同地区和不同成因类型矿床及人工合成的金红石的20个样品进行了矿物学研究。结果表明,大多数金红石样品中都含有钛铁矿的嵌晶,金红石和嵌晶钛铁矿晶粒中多含有含钛赤铁矿(Titano-hematite)的出溶相。金红石晶粒中的含钛赤铁矿于600℃消失;而钛铁矿中的含钛赤铁矿于800℃消失,且整个晶粉转变成亚铁假板钛矿(Ferro-pseudobrookite)。总结出金红石中铁的三种存在形式:类质同象置换钛的Fe~(3+)、固溶体出溶相含钛赤钛铁矿中的Fe~(3+)及钛铁矿中所含的Fe~(2+)。 相似文献
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钛矿资源及其开发利用 总被引:3,自引:0,他引:3
钛金属因其特殊性能和广泛用途被称为“第三金属”,90%以上的钛矿物被用于TiO2颜料的生产,其次为宇航工业等。金红石和钛铁矿是提炼金属钛的主要原料。我国钛铁矿储量居世界之首,其精矿可满足国内钛工业需要,金红石资源较贫乏,原料供不应求。目前世界钛工业总形势是供大于求 相似文献