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Quantification of river water infiltration in shallow aquifers using acesulfame and anthropogenic gadolinium 下载免费PDF全文
This study has investigated the use of the artificial sweetener acesulfame and the magnetic resonance imaging contrast agent gadolinium as quantitative tracers for river water infiltration into shallow groundwater. The influence of a river on alluvial groundwater in a subalpine catchment in western Europe has been assessed using the ‘classical’ hydrochemical tracer chloride and the trace contaminants acesulfame and anthropogenic gadolinium. Mixing ratios for riverine bank filtrate with ambient groundwater and the uncertainties associated with the temporal and spatial tracer variability were calculated using acesulfame and gadolinium and compared with those obtained using chloride. The temporal variability of tracer concentrations in river water of gadolinium (standard deviation SD: 63%) and acesulfame (SD: 71%) both exceeded that of chloride (SD: 27%), and this was identified as the main source of uncertainty in the mixing analysis. Similar spatial distributions were detected in the groundwater for chloride and gadolinium, but not for acesulfame. Mixing analyses using acesulfame resulted in calculated mixing ratios that differed from those obtained using gadolinium and chloride by up to 83% and 92%, respectively. At the investigated site, which had oxic conditions and moderate temperatures, acesulfame was found to be a less reliable tracer than either gadolinium or chloride, probably because of natural attenuation and input from other sources. There was no statistically significant difference between the mixing ratios obtained using chloride or gadolinium, the mixing ratios obtained using gadolinium were 40–50% lower than those obtained using chloride. This is mainly due to a bias of the mean gadolinium concentration in river water towards higher values. In view of the uncertainties of the two tracers, neither could be preferred over the other for the quantification of bank filtrate in groundwater. At this specific site gadolinium was able to reliably identify river water infiltration and was a more precise tracer than chloride at low mixing ratios (<20%), because of the exclusive occurrence of gadolinium in river water and its high dynamic range. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Takashi Sano Toshiaki Hasenaka Hiroyuki Sawahata Takaaki Fukuoka 《Geostandards and Geoanalytical Research》2006,30(1):31-37
Prompt gamma neutron activation analysis was applied to the determination of the titanium, potassium, samarium and gadolinium contents of nine Geological Survey of Japan (GSJ) reference materials (JB-1, 1a, 2, 3; JA-1, 2, 3; JR-1, 2). Firstly, the values in JB-1 were determined by the standard addition method: pressed powder disks of JB-1 were used for neutron irradiation and gamma-ray measurements, after known quantities of standard reagents had been added. Secondly, the contents of eight other reference materials were determined by comparison methods using JB-1 as the comparative standard. The precision of analyses were obtained by replicate determinations on these samples. The relative standard deviation was generally less than 5%. For most samples, analysed values agreed well (< 5%) with the recommended values. 相似文献
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