长江口北支盐水倒灌南支对青草沙水源地的影响

自1978年以来，在长江口的几个关键岸段（例青龙港、新建、高桥、堡镇等）设置盐度观测站；1992－1994年的枯季、在青草沙水源地的南、北两侧各抛测量船一般，在一个完整的大、中、小潮期间、连续逐时观测流速、流向、水深、盐度等，同时在青龙港等处设置6个岸边观测点同步取样；1995－1996年在船站位置各设置氯离子自动监测仪一台；1996年3月又进行了一次大规模的长江口水文测验。本文对大量的现场资料作了分析计算。研究结果表明，青草沙水源地盐水来源主要有北支倒灌咸水团和外海咸水入侵。前者的特征为，氯度的半月变化是小潮期（或小潮后的寻常潮）的氯度反高于大潮期，氯度的潮周日变化是日最高值出现在落憩附近，日最低值出现在涨憩附近，氯度的垂向分层不明显。这与外海盐水入侵引起的氯离子浓度在半月和潮周日内的变化特征正好相反。     

Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.     

长江口泥沙的来源分析与数量计算的研究

本文根据地学原理，建立了长江口泥沙的来源分析与数量计算的模式。定量分析了长江口泥沙来源，计算了泥沙的数量。通过验证表明沙量的计算值与验证值两者十分吻合。     

无线电掩星反演大气参数误差分析及应用进展

本文详细分析了影响空间GPS无线电掩星反演大气参数方法的主要误差源，其中包括信噪比误差，精密定轨误差，电离层模制误差，多路径效应和时钟改正等误差，并且介绍了国内外在无线电掩星领域的一些应用研究进展。     

云南毛坪铅锌（银、锗）矿床流体包裹体特征及成矿流体来源

云南毛坪铅锌(银、锗)矿床是川滇黔成矿域滇东北地区以碳酸盐岩为主岩的中-大型铅锌(银)矿床的典型代表。矿体空间分布严格受 NE 向层间断裂带和猫猫山倒转背斜的控制。主要脉石矿物(铁方解石、方解石及白云岩)中的流体包裹体发育,一般较小(3～15μm),主要为纯液相和液相包裹体,常沿矿物结晶面密集成群展布。成矿流体属 Na~ -K~ -Ca~(2 )-CI~- -F~- 型,流体包裹体均一温度为180～218(C,盐度为4.1 wt%～9.5 wt% NaCl,成矿压力为406×10~5～570×10~5Pa。在主要脉石矿物流体包裹体中,Na~ /K~ (1.54～4.53)与 Cl~-/F~-(0.72～156.33)较高,而重晶石流体包裹体中 Na~ /K~ (0.32～8.36)与 Cl~-/F~-(1.06～16.77)较低。成矿流体的(D 为-23‰～-64‰,方铅矿、闪锌矿和黄铁矿中流体包体(~(18)O_(v-SMOW)依次为0.3‰～6.2‰,-9.0‰～3.4‰和-6.8‰～-12.7‰。脉石矿物的(~(13)C_(v-PDB)为-1.1‰～-3.7‰。以上信息更好地揭示了成矿流体是变质水、岩浆水和建造水混合的产物,它们与沉积作用、昆阳群基底的变质作用及岩浆热液作用有关。该矿床本身可能是富含铅、锌、银等成矿流体对流循环沿构造"贯入"而成。该矿床不同于典型的 MVT 型铅锌矿床,是一碳酸盐岩为主岩的铅锌多金属硫化物矿床。     

四颗射电源在依巴谷和PPM星表中的光学定位

利用北京天文台施密特望远镜的CCD巡天资料（BATC）中的20次观测,用IRAF软件处理得到星象中心位置,以依巴谷星表和PPM星表作为参考星表,用底片常数法进行处理,得到4颗河外射电源0851 202,1228 126,1442 101,1749 701的光学位置。文中还对所得到的位置与射电位置作了比较。     

Sources and sinks of atmospheric methane

In 1972 average mixing ratio of methane in the troposphere was 1.41 ppm and 1.3 ppmv for the northern and southern hemisphere, respectively, which corresponds to a total amount of 4×10¹⁵ g of CH₄ present in the atmosphere. Most is of recent biologic origin.¹⁴C analyses show that no more than 20 percent is released by fossil sources. The various ecosystems producing CH₄ are discussed and the total annual production is estimated to lie between 5.5×10¹⁴ g/yr and 11×10¹⁴ g/yr. The corresponding turnover times for atmospheric CH₄ range from 4 to 7 yrs. The destruction of CH₄ takes place mainly in the troposphere, most probably through the reaction of CH₄ + OH CH₃ + H₂O. About 10 percent of the CH₄ is destroyed in the stratosphere. The CH₄ cycle contributes on the order of 1 percent to the atmospheric carbon cycle.     

Occurrence and fate of polycyclic aromatic hydrocarbons in the coastal surface microlayer

Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air-sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3+/-9.1 vs. 13.1+/-10.0 ng L(-1) in the dissolved phase; 709+/-207 vs. 158+/-111 ng g(-1) in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.     

西藏冈底斯-念靑唐古拉成矿带典型矿床硫化物Pb同位素特征——对成矿元素组合分带性的指示

冈底斯-念青唐古拉成矿带矿床成矿元素组合由南向北存在着Cu-Au、Cu-Mo向Pb-Zn-Cu-Fe、Pb-Zn过渡的变化规律,但引起该变化规律的原因目前少研究。本文通过对成矿带典型矿床Pb同位素特征较为系统的总结,并结合成矿年代学和区域构造演化研究成果,从成矿物质来源的角度对该分带性进行了初步探讨。研究表明成矿带由南到北成矿物质来源存在着差异:最南端Cu-Au矿床Pb同位素组成具幔源特征(207Pb/204Pb和208Pb/204Pb平均值分别为15.490和38.016),反映成矿物质来自于俯冲过程中的交代地幔楔;最北端的Pb-Zn矿床Pb同位素组成与念青唐古拉群基底片麻岩相近(207Pb/204Pb和208Pb/204Pb分别变化于15.641～15.738和38.976～39.362),反映成矿物质来自于基底片麻岩。Pb-Zn-Cu-Fe矿床Pb同位素组成介于幔源Pb和上地壳Pb之间,且具混合线特征,反映了同碰撞期成矿物质同时从俯冲板片和念青唐古拉基底片麻岩活化的混源模式;而Cu-Mo矿床不具混合线特征的造山带Pb同位素组成,反映了成矿物质来源于俯冲阶段楔形地幔部分熔融并底侵到地壳底部与地壳发生物质交换后所形成的新生下地壳源区。甲马Cu多金属矿床Pb同位素组成具幔源和造山带两个端元,推测除新生下地壳源区提供成矿物质外,叶巴组火山岩也提供了部分成矿物质。由南向北成矿物质来源的差异很大程度上与板片俯冲的"距离效应"有关,正是由于成矿物质来源的差异导致成矿带成矿元素分带性的形成。     

开滦苯加氢精制工程环境风险评价

以某苯加氢精制工程为例,探讨了焦化行业环境风险评价方法;利用该项目所在地近3 a地面常规气象观测资料,分析了当地的污染气象特征;采用风险识别、源项分析、后果计算、风险评价等环境风险评价技术方法,筛选出主要风险因子并进行风险预测,采用多烟团模式并考虑气象因素进行风险计算。结果表明：污染事故发生后,苯类物质的地面浓度最大值为3 214 mg/m^3,位于距离事故发生源WNW方向约50 m处超标1 339倍,由此可知近距离污染严重;高浓度污染物主要集中在污染源附近,随着距离的延长,污染物浓度不断向下风向扩散,超标范围在6 km内。利用简化分析法,定量给出此项工程的最大可信事故风险值为7.6×10^-6/a,小于化工行业风险值8.33×10^-5/a,此工程风险值水平与同行业比较在可接受的范围内。