Diffusional behavior of multi-arm star polymers by H pulsed field gradient spin-echo NMR method

The diffusional behavior of multi-arm star-shaped p(tBMA) was investigated in a concentration range from dilute to semidilute region with ¹H pulsed field gradient spin-echo NMR (PFGSE-NMR). An 142-arm star-shaped p(tBMA) showed two diffusional mode, which reflected the coexistence of liquid ordering phase and liquid phase near the ordering transition. On the other hand, for star-shaped p(tBMA) with 55 arms showed a single diffusional relaxation in all concentration ranges during observation time. In the semidilute region, the relationship between the diffusion coefficient against the polymer concentration was affected strongly not only the arm number but also liquid ordering structure.     

一种新型的转炉炉底车

本文介绍了一种作业效率高、省时省力新型的转炉炉底车，其特点是转盘转动灵活，炉底车上项盘径向任意方向均能平稳倾斜一定角度，以保证炉底圆周所受项力均匀可靠，满足炉底安装要求。     

球头碗球面加工组合机床设计

根据球面形成原理,利用铣刀和工件的两个圆运动,合成球头碗的不完整内球面。采用组合机床,结构简单,调整、维护方便,主轴弹性卡头便于工件装卸。对零件尺寸、形状和位置误差进行了分析。通过对铣刀和主轴电机的变频调速,找出最佳切削参数,实现了内球面的高效率高精度加工。     

不锈钢网架(壳)技术及其应用

本文总结了多年来不锈钢网架的研究成果 ,并介绍了部分不锈钢网架的工程应用     

Intermolecular interactions and formation of the hydration sphere in phosphonic acid model systems as an approach to the description of vinyl phosphonic acid based polymers

Molecular model systems based on propyl phosphonic acid (ppa) were studied by means of density functional theory calculations in order to describe the acid-acid interaction and the formation of the hydration sphere. The formation of ppa dimers is reported and the energetic difference between two dimer structures is presented. The hydration sphere of ppa was represented by model systems ppa(H₂O)_n, for which the system with n=4 formed the first hydration sphere (h¹), while n=7 can be considered a good approximation to the complete inner hydration sphere around the phosphonic acid group. The study of the ppa-H⁺ (H₂O)_n model systems showed an interesting structural behavior comparatively to the ppa(H₂O)_n systems. The protonated acids exhibited equivalent phosphorous-oxygen bonds and a general molecular structure is proposed to represent these protonated species.     

Parametric circles and spheres

Formulations for parametric circles and spheres in terms of rational Gaussian (RaG) curves and surfaces are introduced. With the proposed formulations, a full circle is generated by interpolating a closed RaG curve to the vertices of an equilateral triangle, and a full sphere is generated by interpolating a closed RaG surface to the vertices of an octahedron with equilateral triangular faces. Generation of circles and spheres in this manner is very intuitive and easy to remember as the weights are all 1 and the nodes are all unique and uniformly spaced.     

招远金矿集中区金矿富集规律及找矿标志

招远金矿集中区是我国最大的金矿集中区，区内金矿床在时间和空间上的分布规律十分明显。该区矿化类型主要有石英脉型、蚀变岩型及二者之间的过渡类型，其在空间上的分布规律为综合信息找矿及矿床定位预测提供地质信息，并可作为进一步的找矿标志。     

Advanced New Lightweight Materials: Hollow‐Sphere Composites (HSCs) for Mechanical Engineering Applications

“Lightweight” is a major trend in machine tool design to ensure higher speed and higher acceleration of elements, which results from state‐of‐the‐art technology, such as the new linear drive and the control system.^[1] Research is being carried out in institutes worldwide into lightweight construction by either design and/or choice of material. One type of advanced lightweight engineering material to reduce the mass of the moving parts of machine tools is hollow‐sphere composites. Investigations of their thermal and mechanical properties show the superior quality of HSCs compared with alternative materials. Example applications of hollow‐sphere composites include the table of a milling machine and robot arms.     

The Cubooctahedron Shape──A Suboptimal Cell Shape for 3－Dimensional Cellular System

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Molecular Diffusion Coefficients of Organic Compounds in Water at Different Temperatures

Molecular (or tracer) diffusion coefficient data were obtained for 2-naphthol, benzoic acid, salicylic acid, camphor, and cinnamic acid in water at temperatures that differ significantly from ambient value. Experimental values were determined for the dissolution of 2-naphthol in water at 283 to 368 K, of benzoic acid in water at 283 to 338 K, of salicylic acid in water at 283 to 343 K, of camphor in water at 283 to 318 K, and of cinnamic acid in water at 283 to 318 K. Empirical correlations are presented for the prediction of molecular diffusion coefficient over the entire range of temperatures studied, and they are shown to predict the obtained data with very good accuracy.