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排序方式: 共有1735条查询结果,搜索用时 359 毫秒
1.
在Fe-As(Ⅲ)-Cu(Ⅱ)-H2O体系中, 研究了酸性废水中As(Ⅲ)、Cu(Ⅱ)与金属铁粉的反应行为, 考察了反应过程中As在气、液、固三相中的分配比。结果表明, As(Ⅲ)和Cu(Ⅱ)离子被Fe还原为单质As和Cu后, As、Cu进一步结合成Cu5As2等金属间化合物, 从而促进As(Ⅲ)沉淀反应的发生, 且无AsH3生成。在反应时间40min、铁粉过量系数1.2、溶液初始pH=0.0、温度40 ℃、Cu/As摩尔比1.0条件下, As在气、液、固三相中的分配比分别为0、20.7%和79.3%, 沉砷率为79.3%。 相似文献
2.
Cora Chmielowska Dorota Korsak Barbara Szmulkowska Alicja Krop Kinga Lipka Martyna Krupiska Dariusz Bartosik 《International journal of molecular sciences》2020,21(22)
Listeria monocytogenes is a pathogen responsible for severe cases of food poisoning. Listeria spp. strains occurring in soil and water environments may serve as a reservoir of resistance determinants for pathogenic L. monocytogenes strains. A large collection of Listeria spp. strains (155) isolated from natural, agricultural, and urban areas was screened for resistance to heavy metals and metalloids, and the presence of resistance determinants and extrachromosomal replicons. Of the tested strains, 35% were resistant to cadmium and 17% to arsenic. Sequence analysis of resistance plasmids isolated from strains of Listeria seeligeri and Listeria ivanovii, and the chromosome of L. seeligeri strain Sr73, identified a novel variant of the cadAC cadmium resistance efflux system, cadA6, that was functional in L. monocytogenes cells. The cadA6 cassette was detected in four Listeria species, including strains of L. monocytogenes, isolated from various countries and sources—environmental, food-associated, and clinical samples. This resistance cassette is harbored by four novel composite or non-composite transposons, which increases its potential for horizontal transmission. Since some cadAC cassettes may influence virulence and biofilm formation, it is important to monitor their presence in Listeria spp. strains inhabiting different environments. 相似文献
3.
P. M. Solozhenkin E. A. Deliyanni V. N. Bakoyannakis A. I. Zouboulis K. A. Matis 《Journal of Mining Science》2003,39(3):287-296
The original method is developed for producing the new inorganic sorption material of akaganeite bgr-FeO(OH). The material in question is characterized relative to arsenic contained in aqua. The possibility is established for removing arsenate ions from water by contemporary physicochemical methods. 相似文献
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Vinh Q. Nguyen Jas S. Sanghera Brian Cole Pablo Pureza Frederic H. Kung Ishwar D. Aggarwal 《Journal of the American Ceramic Society》2002,85(8):2056-2058
Arsenic sulfide glass optical fibers typically possess extrinsic absorption bands in the infrared wavelength region associated with residual hydrogen and oxygen related impurities, despite using purified precursors. We report a purification process based on the addition of tellurium tetrachloride (TeCl4 ) to the glass. During melting, the chlorine from TeCl4 reacts with the hydrogen impurities to produce volatile products (e.g., HCl) that can be removed by subsequent dynamic distillation. The processing conditions have been modified accordingly to produce optical fibers with significantly reduced loss due to hydrogen sulfide impurity content (1.5 dB/m). 相似文献
7.
镇沅金精矿选择性固砷焙烧—氰化浸出新工艺研究 总被引:6,自引:0,他引:6
对云南镇沅金矿的难当金精矿进行了选择性固砷焙烧-氰化浸出的试验研究,取得了满意结果。砷固定率大于92%,硫挥发率为78%-84%,金浸出率可达91%-93%。选择性固砷焙烧-氰化浸出新工艺可有效消除砷害,综合利用有价成分硫,特别适宜于含砷高硫,同时含碳等杂质的细粒浸染型难浸金矿石的处理,在我国有较大的发展前景。 相似文献
8.
针对流域突发性重金属污染,不同浊度下的泥沙对重金属有一定的去除效果。以浊度为指示指标,通过试验研究了常温(25 ℃)和低温(5 ℃)条件下浊度50~650 NTU(Nephelometric Turbidity Unit)范围内泥沙对重金属镉、铅、砷吸附去除的影响。试验结果表明:泥沙对重金属镉、铅、砷的去除效果为铅>镉>砷,其中铅的去除率达到99%。浊度与能处理达标的最高重金属浓度呈线性关系,常温下浊度与能处理达标的最高镉、铅、砷浓度关系曲线的相关系数分别为0.996、0.998、0.999,低温下其相关系数分别为0.999、0.996、0.998。常温较低温更利于泥沙对重金属镉、铅、砷的去除,能去除更高浓度的重金属,达到生活饮用水卫生标准。 相似文献
9.
针对河套盆地开展了历时多年的水文地质环境地质调查,利用采集的298组浅层地下水样品以及收集并甄选的382个水文地质钻孔记录分析发现:河套盆地内95%的高砷地下水(As质量浓度10μg/L)集中在黄河决口、改道形成的古河道影响带及黄河决口扇裙带。其中,盆地南部首次发现了较为集中的高砷地下水,其分布范围与黄河北岸的晚更新世以来黄河决口、改道形成的4个大型决口扇,在空间上有着良好的对应关系。黄河古河道带及决口扇裙带表现为较强的还原环境及蒸发浓缩作用以及较弱的地表水补给强度。受pH值、含铁氧化物的还原性溶解等因素影响,决口扇裙带浅层地下水中砷的含量略低于平原中部黄河古河道带。结果表明:黄河古河道带及决口扇裙带特定的沉积环境控制着地下水的水文地球化学过程,进而对高砷地下水的分布具有决定性的作用。 相似文献
10.
Novel technology of purification of copper electrolyte 总被引:10,自引:1,他引:10
The effects of arsenic with different valence states on the purification of copper electrolyte were studied and a novel technology of purification of copper electrolyte by copper arsenite was proposed. The results show that the purification performance of As(Ⅲ) compounds is better than that of As(Ⅴ) compounds. The purification technology by copper arsenite has the advantages of simple operation, high purification performance and low cost in comparison with other technologies and its appropriate purification conditions are that copper arsenite concentration is 18 g/L, reaction temperature is 65 ℃ and reaction time is 8 h. The removal rates of Sb and Bi are 53.22% and 58.67% respectively under these conditions. The purification principle show that a kind of yellow precipitate mainly composed of arsenic, antimony ( Ⅴ ), bismuth and oxygen forms in electrolyte after copper arsenite is added, and consequently antimony and bismuth are removed from electrolyte. 相似文献