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1.
《Ceramics International》2021,47(20):28203-28209
Vanadium carbide (VC) as excellent ceramic and functional material is usually prepared by carbothermal reduction of V2O5 which must be extracted from a typical V slag by complex processes. Pollutants, such as ammonia-nitrogen wastewater, NH3 and CO2 are inevitably discharged. A novel and green method for VC preparation was proposed by one-step co-electrolysis of soluble NaVO3 and CO2 in molten salt. It was found that VC with high purity was easily obtained by reducing electrolysis temperature and CO2 flow rate to 600 °C and 10 mL min−1 at 3.0 V. Besides VC with particles and layered stacking structure in products, a small amount of carbon and oxygen elements existed. The atomic percentage contents of C, V, and O elements in VC were about 50.0%, 44.5% and 3.8%, respectively. During electrolysis, CO32− and VO3− was reduced at about −0.55 V (vs. Ag/AgCl) and −1.38 V (vs. Ag/AgCl), respectively. CO32− ions were more easily reduced than VO3−, and was firstly reduced to CO22− and then converted to C. Then, VC was prepared by two routes from CO2 and NaVO3. One route is that VO3− ions are firstly electroreduced to VO2− ions and then are further electroreduced to VC with C. Another route is that VO3− ions are electroreduced to V which in-situ reacted with C to VC. Both VO3− and CO32− ions are electroreduced by two-step process. In final, VC is in-situ deposited on cathode. It provides a novel and green way to prepare VC and also achieves the high value-added utilization of vanadium slag and CO2. 相似文献
2.
《Ceramics International》2021,47(22):31268-31276
The relationship between the tensile strength of corroded domestic second-generation (2ed-gen) SiC fibers at various temperatures for 500 h in 46.5LiF-11.5NaF-42.0KF (mol. %) eutectic salt and the typical microstructure was studied. Weibull theory was used to analyze the critical defects that caused the tensile fracture, and the microstructure of fibers before and after corrosion was characterized. It is concluded that the decrease of tensile strength after corrosion at 800 °C is caused by the surface injury of fibers, which led to the shift of critical defects from the internal defects of virgin fibers to surface defects. Moreover, corrosion at higher temperature accelerates the corrosion process and dissolve the surface O-contained layer thoroughly. This shifts the critical defects back to the internal defects and will be helpful for the recovery of tensile strength of corroded fibers at the higher temperature. 相似文献
3.
T. Galvin N.C. Hyatt W.M. Rainforth I.M. Reaney D. Shepherd 《Journal of the European Ceramic Society》2018,38(14):4585-4589
The molten salt method was used to synthesise the MAX phase compounds Ti2AlC and Ti3AlC2 from elemental powders. Between 900–1000?°C, Ti2AlC was formed alongside ancillary phases TiC and TiAl, which decreased in abundance with increasing synthesis temperature. Changing the stoichiometry and increasing the synthesis temperature to 1300?°C resulted in formation of Ti3AlC2 alongside Ti2AlC and TiC. The type of salt flux used had little effect on the product formation. The reaction pathway for Ti2AlC was determined to be the initial formation of TiC1-x templating on the graphite and titanium aluminides. 相似文献
4.
济阳坳陷新近系地层油藏特征--以太平油田为例 总被引:12,自引:8,他引:4
由于河流相沉积受控于古地貌形态,并在凸起边缘部位形成地层超覆圈闭,因此济阳坳陷新近系具有良好的油气成藏条件。太平油田主要含油层段为新近系馆陶组下亚段,根据构造演化、沉积储层特征及油源对比分析,认为“网毯式”输导体系是该油田油气运移的主要通道;古地貌控制了地层的分布和储层的发育程度;地层超覆边界控制了各砂层组的含油性,从而形成了典型的地层油藏组合。 相似文献
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A kinetic model for simulation of the MTO process over SAPO-18 catalyst in a wide range of operating conditions has been proposed. The kinetic model predicts the experimental evolution of reaction products with time on stream, which follows three consecutive periods: initiation (where olefin production increases), a period of maximum olefin production and a period in which this production decreases. The kinetic scheme takes into account these three steps that evolve with time on stream: formation of active intermediate compounds, an step where olefins are formed by reaction of oxygenates (methanol/DME) with these intermediates and deactivation of intermediates by degradation to coke. The presence of water in the reaction medium attenuates the reaction rate of these steps. Discrimination of kinetic equations and calculation of the parameters of best fit have been carried out by solving the mass conservation equations of the individual components of the kinetic scheme together with the kinetic equation for deactivation and taking into account the effect of water on the kinetics of each step. 相似文献
8.
郯庐断裂带是中国东部一条巨型断裂构造带,该文从其基本构造特征入手,分析了它的几何学、运动学和动力学特征,并进一步研究其含油气特点,认为:a)郯庐断裂带对中国东部诸多中新生代含油气盆地的形成及演化有重要的控制作用,不同演化阶段产生并控制了不同的沉积盆地(如松辽盆地和渤海湾盆地);b)郯庐断裂带对油气藏的形成及演化有重要的控制作用,不仅控制盆地烃源岩的发育、基本的储集层和盖层条件,以及圈闭的形成等等,而且对油气的生成、运移及聚集成藏、大中型油气田的形成及分布等有重要的控制作用. 相似文献
9.
General relationships between organisms and their habitat, consistent across spatial scales and regions, suggest the existence of repeatable ecological processes and are useful for the management of stream networks. From published data, we defined four guilds of European fish species with contrasting preferences for microhabitat hydraulics within stream reaches. At the scale of stream reaches and across 139 French sites (590 460 fishes sampled), we analysed how fish guild proportions were related to reach hydraulics (proportion of pools vs. riffles %POOL; median discharge by unit width Q50/W). The strongest correlations were observed between two fish guilds and %POOL (p < 0.001, r2 ≥ 0.41) and between one fish guild proportion and Q50/W (p < 0.001, r2 = 0.10). These reach–scale relationships were consistent across six large French basins, and consistent with the analyses made at the microhabitat scale. Therefore, microhabitat preferences for hydraulics are strong enough to generate consistent reach‐scale community responses to hydraulics across regions, despite the influence of other filters such as temperature, nutrient levels or history. The distribution of basic geomorphic features (pools, riffles) in streams and their modification (by dams, weirs and dikes) can modify the proportion of fish guilds by up to 80%, probably contributing to the long‐term decline of riffle‐dwelling species in Europe. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
10.
本文简略介绍云南某硫酸盐浆厂污水处理工程采用的国内不多见的污水单元技术,并对其先进性和实用性效果进行评价和探讨。 相似文献