Effect of Paraffin and Silica Matrix Phase Change Materials on Properties of Portland Cement Mortars

In the search for methods to incorporate Phase Change Materials (PCM) into Portland cement mortar mixtures, PCM based on paraffins adhered to a silica-based matrix appear as a suitable option. However, paraffin particles have been observed to escape from the silica matrix when water is added. There are only limited data on how the use of such PCM affects the behaviour of mortars. To evaluate the effect of this PCM addition, Portland mortar mixtures were elaborated with 5%, 10% and 15% of PCM content, and using CEM 42.5 I R and CEM I 52.5 R cement types. Physical properties such as density, open porosity, air content and water absorption were analysed for fresh and dry samples. The results obtained show that the PCM-added mixtures require greater water and cement amounts than the standard mortar mixtures to achieve similar compressive strengths. Compared to non-PCM mixtures the PCM-added mortars present a density lowering of 37% for fresh mixtures and near 45% for dry state forms. A maximum compressive strength of 15.9 MPa was reached for 15% PCM mixtures, while values beyond 40 MPa were achieved for 5% PCM mixtures. Thus, the proposed study contributes to broad the available knowledge of PCM cement mortar mixtures behaviour and their mix design.     

小柴胡汤加减治疗浆细胞性乳腺炎30例

目的:观察小柴胡汤加减治疗浆细胞性乳腺炎的临床疗效。方法:选取本院30例浆细胞性乳腺炎确诊患者,均为女性,采用小柴胡汤加减合用平消胶囊并外敷金黄膏治疗,观察治疗后临床疗效及不良反应。结果:30例患者全部治愈,无一例住院与手术。结论:运用小柴胡汤加减配合平消胶囊并外用金黄膏治疗浆细胞性乳腺炎疗效显著。     

ADAPTATION IN PROTEIN CALORIE MALNUTRITION (PCM)

Endocrine adaptation to starvation and low protein hypocaloric diets is discussed as a basis for understanding the clinical expression of PCM. Infections common in PCM increase acute phase reactants, which may contribute to the derangement of homeostasis in PCM.     

Study of Fresh and Hardening Process Properties of Gypsum with Three Different PCM Inclusion Methods

Gypsum has two important states (fresh and hardened states), and the addition of phase change materials (PCM) can vary the properties of the material. Many authors have extensively studied properties in the hardened state; however, the variation of fresh state properties due to the addition of Micronal® DS 5001 X PCM into gypsum has been the object of few investigations. Properties in fresh state define the workability, setting time, adherence and shrinkage, and, therefore the possibility of implementing the material in building walls. The aim of the study is to analyze, compare and evaluate the variability of fresh state properties after the inclusion of 10% PCM. PCM are added into a common gypsum matrix by three different methods: adding microencapsulated PCM, making a suspension of PCM/water, and incorporating PCM through a vacuum impregnation method. Results demonstrate that the inclusion of PCM change completely the water required by the gypsum to achieve good workability, especially the formulation containing Micronal® DS 5001 X: the water required is higher, the retraction is lower (50% less) due to the organic nature of the PCM with high elasticity and, the adherence is reduced (up to 45%) due to the difference between the porosity of the different surfaces as well as the surface tension difference.     

Form-Stable Phase Change Materials Based on Eutectic Mixture of Tetradecanol and Fatty Acids for Building Energy Storage: Preparation and Performance Analysis

This paper is focused on preparation and performance analysis of a series of form-stable phase change materials (FSPCMs), based on eutectic mixtures as phase change materials (PCMs) for thermal energy storage and high-density polyethylene (HDPE)-ethylene-vinyl acetate (EVA) polymer as supporting materials. The PCMs were eutectic mixtures of tetradecanol (TD)–capric acid (CA), TD–lauric acid (LA), and TD–myristic acid (MA), which were rarely explored before. Thermal properties of eutectic mixtures and FSPCMs were measured by differential scanning calorimeter (DSC). The onset melting/solidification temperatures of form-stable PCMs were 19.13 °C/13.32 °C (FS TD–CA PCM), 24.53 °C/24.92 °C (FS TD–LA PCM), and 33.15 °C/30.72 °C (FS TD–MA PCM), respectively, and latent heats were almost greater than 90 J/g. The surface morphologies and chemical stability of form-stable PCM were surveyed by scanning electron microscopy (SEM) and Fourier-transform infrared (FT-IR) spectroscopy, respectively. The thermal cycling test revealed that the thermal reliability of these three form-stable PCMs was good. Thermal storage/release experiment indicated melting/solidification time was shortened by introducing 10 wt % aluminum powder (AP). It is concluded that these FSPCMs can act as potential building thermal storage materials in terms of their satisfactory thermal properties.     

The Screen for Cognitive Impairment in Psychiatry: Proposal for a polytomous scoring system

The Screen for Cognitive Impairment in Psychiatry is a simple, fast, and easy to administer scale that has been validated in clinical and community samples. The aim of this study was to propose a polytomous scoring system for the Screen for Cognitive Impairment in Psychiatry and to demonstrate its functioning, thus providing new and complementary information regarding the utility and precision of this screening tool. Three hundred seventy‐six Spanish patients diagnosed with schizophrenia spectrum disorder were evaluated. A polytomous scoring system was generated and analyzed by means of the partial credit model. Category assessment revealed optimal functioning after collapsing the 7‐category system to 1 with either 5 or 4 categories, depending on the item. The proposed polytomous scoring system shows good psychometric properties and an adequate fit to the partial credit model. These results provide further confirmation of the test's utility in clinical settings and of its suitability for detecting cognitive impairment.     

Compatibility Tests between Three Commercially Available Organic PCMs and Metals Typically Used in Fin-and-Tube Heat Exchangers

Energy storage is one of the most effective ways to increase energy savings and efficiency of heating and air conditioning systems. Phase change materials (PCMs) are increasingly used in latent heat thermal energy storage (LHTES) systems to increase their capacity. In such systems, costs are a very important factor of viability so the typical heat transfer elements like fin-and-tube heat exchangers are used to construct the LHTES. The problem of this approach is a possibility of corrosion of metals in contact with PCM that shortens the life cycle of LHTES. Therefore, the main objective of this work is an experimental study of the compatibility of metals typically used in fin-and-tube heat exchangers (copper and aluminum) with three commercially available organic PCMs (RT15, RT18HC, and RT22HC). Compatibility of PCMs with copper and aluminum was tested for a period of approximately two months, during which a total of 35 heating and cooling cycles were carried out, each with a complete phase transition of the tested materials. In the course of the tests it was assessed whether the PCM caused corrosion of the tested metals. The evaluation was based on the gravimetric method, calculation of corrosion rate, and visual observations and measurements of the features on the metal sample’s surface using optical microscope. It was determined that RT15, RT18 HC, and RT22 HC show low corrosion rates for aluminum and copper samples. The visual tests indicate that there was no change in the PCM solutions during the tests, only a sediment was observed for the samples with the combination of copper and aluminum. Microscopic examination of the surface of the samples did not show any significant surface changes, except for the aluminum samples, on the surface of which local microdefects were observed. It follows from the present results that copper and aluminum can be used to design the heat transfer surface in contact with the chosen PCMs.     

Prediction of the Delamination at the Steel and CFRP Interface of Hybrid Composite Part

The purpose of this study was to predict the adhesive behavior of steel and carbon-fiber-reinforced plastic (CFRP) hybrid parts based on the cohesive zone model (CZM). In this study, the steel sheet and CFRP were joined by epoxy resin in the CFRP prepreg during the curing process, which could generate delamination at their interface because of the springback of steel or the thermal contraction of the CFRP. First, double cantilever beam (DCB) and end-notched flexure (ENF) tests were performed to obtain various adhesion properties such as the critical energy release rate of mode I, mode II (G_I, G_II), and critical stress (σ_max). A finite element (FE) simulation was performed to predict delamination using CZM, which was also used to describe the interfacial behavior between the steel sheet and the CFRP. Finally, a U-shape drawing test was performed for the steel/CFRP hybrid parts, and these results were compared with analytical results.     

Study of the Interfacial Bond Behavior between CFRP Grid–PCM Reinforcing Layer and Concrete via a Simplified Mechanical Model

This paper presents the results of pull-out tests conducted to investigate the interfacial bond behavior between a carbon-fiber-reinforced polymer (CFRP) grid–polymer cement mortar (PCM) reinforcing layer and existing concrete, and proposes a simplified mechanical model to further study the interface bond mechanism. Four specimens composed of a CFRP grid, PCM, and concrete were tested. The influence of the type of CFRP grid and the grid interval on the interface bond behavior was discussed. The failure patterns, maximum tensile loads, and CFRP grid strains were obtained. The change process of interface bond stress was investigated based on the grid strain analysis. In addition, the simplified mechanical model and finite element model (FEM) were emphatically established, and the adaptability of the simplified mechanical model was validated through the comparative analysis between the FEM results and the test results. The research results indicate that a CFRP grid with a larger cross-sectional area and smaller grid interval could effectively improve the interface bond behavior. The tensile stress was gradually transferred from the loaded edge to the free edge in the CFRP grid. The interface bond behavior was mainly dependent on the anchorage action of the CFRP grid in the PCM, and the bond action between the PCM and the concrete. The FEM results were consistent with the test results, and the simplified mechanical model with nonlinear springs could well describe the interface bond mechanism between the CFRP grid–PCM reinforcing layer and concrete.     

Electronic structures and spectra of quinoline chalcones: DFT and TDDFT-PCM investigation

The structures and electronic absorption spectra of quinoline chalcones have been investigated with density functional theory (DFT) and time-dependent density functional theory (TDDFT). The relationship between the structure and absorption spectrum and the effects of substituents, solvents, elongation of the conjugate chain as well as differing positions of the carbonyl group in the conjugate chain on electronic spectra have been discussed. It turns out that the hybrid PBE1PBE functional with the 6-31G basis set provide reliable λ_max when the solvent effects are included in the model. Comparisons with experimental values lead to a mean absolute error of 21.5 nm (0.20 eV). Moreover, the observed substituent and solvent effects are reproduced by calculation qualitatively. The calculation reveals that the maximum absorption band mainly results from the π → π^* transition from HOMO to LUMO.