天然气水合物和天然气脱水新工艺探讨

探讨了天然气水合物的发展过程、形成条件以及对天然气输送管道的腐蚀堵塞作用,对我国天然气脱水创新技术———膜法脱水、汽提脱水的原理与工艺过程进行了全面论述。考察了气体处理量及操作压力等对我国1.2×105m3/d天然气膜法脱水的工业试验装置的脱水过程的影响。     

关于天然气水合物钻采工艺技术进展的研究

目前全球正面临着前所未有的能源危机，天然气水合物由于储量大、能量密度高而将成为一种诱人的新型能源。天然气水合物主要存在于冻土带和海洋，在地下处于低温和高压状态，以现有的技术，钻井和开采都存在很大的困难。简要介绍了天然气水合物的性质及储量，阐述了天然气水合物钻井的六个挑战及目前国外天然气水合物的两种钻探方法；同时阐述了以热力法、降压法和化学试剂注入法为主的天然气水合物开采方法，并针对天然气水合物钻采技术现状指出了下一步的研究方向。     

Effect of surfactants and liquid hydrocarbons on gas hydrate formation rate and storage capacity

Hydrate formation rate plays an important role in making hydrates for the storage and transport of natural gas. Micellar surfactant solutions were found to increase gas hydrate formation rate and storage capacity. With the presence of surfactant, hydrate could form quickly in a quiescent system and the energy costs of hydrate formation reduced. Surfactants (an anionic surfactant, a non‐ionic surfactant and their mixtures) and liquid hydrocarbons (cyclopentane and methylcyclohexane) were used to improve hydrate formation. The experiments of hydrate formation were carried out in the pressure range 3.69–6.82 MPa and the temperature range 274.05–277.55 K. The experimental pressures were kept constant during hydrate formation in each experimental run. The effect of anionic surfactant (sodium dodecyl sulphate (SDS)) on natural gas storage in hydrates is more pronounced compared to a non‐ionic surfactant (dodecyl polysaccharide glycoside (DPG)). The induction time of hydrate formation was reduced with the presence of cyclopentane (CP). Cyclopentane and methylcyclohexane (MCH) could increase hydrate formation rate, but reduced hydrate storage capacity The higher methylcyclohexane concentration, the lower the hydrate storage capacity. Copyright © 2003 John Wiley & Sons, Ltd.     

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本文简要介绍了国外在开发超酸性气体过程中遇到的材料选择、腐蚀监测、水化物堵塞、超酸性气的处理和加工等问题所采取的措施和办法。     

Baseline assessment of metals and hydrocarbons in the sediments of Lake Mulwala, Australia

An assessment of hydrocarbon and metal/metalloids (arsenic, cadmium, copper, lead, mercury, selenium, zinc) contamination in sediments from Lake Mulwala, Australia, was undertaken. The objectives of the study were: (i) to determine the extent of contamination in the lake sediments, compared to Australian and international sediment quality guidelines, and (ii) to attempt to identify the contaminant sources to the lake. With the exception of a few samples containing elevated levels of arsenic and/or mercury, the levels of all contaminants in the sediment samples taken from the lake were below the ‘lower trigger’ of the Australian Sediment Quality Guidelines that would warrant further investigation. High molecular weight hydrocarbons (up to 700 mg kg⁻¹) were found in most sediment samples. Non‐metric statistical analysis indicated that the contaminant distribution was different in different parts of the lake, with the lowest concentrations generally found at the influent to the lake. No definitive source(s) of contamination could be identified for either metalloids or hydrocarbons.     

天然气的储存

随着能源结构的调整,天然气在一次能源中的比重逐步增大,天然气的储存成为人们日益关注的课题,作者就此作一综述。     

Influence of Coherent Flow Structures on the Dynamics of Suspended Sediment Transport in Open-Channel Flow

The influence of suspended sediments on coherent flow structures has been studied by simultaneously measuring the longitudinal and vertical components of the instantaneous velocity vector and the instantaneous suspended particle concentration with an acoustic particle flux profiler. The measurements were carried out in clear water and in particle-laden open-channel flows. In both cases, they clearly show the predominance of ejection and sweep phases that are part of a burst cycle. The analysis further demonstrates the importance of the ejection and sweep phases in sediment resuspension and transport. Ejections pick up the sediment at the bed and carry it up through the water column close to the surface. It is shown that ejections and sweeps are in near equality in the near-bottom layer, whereas ejections clearly dominate in the remaining water column. The implications of these results for sediment transport dynamics are discussed.     

中国第一口超千米深水钻井液技术

LW3-1-1探井位于中国南海珠江口盆地，作业水深1480m，完钻井深为3843m，地层以大套灰色泥岩和页岩为主，具有强水敏性．要求钻井液具有良好的流变性、润滑性、抑制性，良好的抗盐、抗钙、抗高温和抗低温能力，以及强的天然气水合物抑制能力。该井采用了PFMX钻井液体系，钻井周期为49d，介绍了钻井液工艺及现场应用情况。PFMX体系表现出很多油基钻井液的优点，如好的润滑性、高的钻进速率、膜效应、强的井眼稳定及页岩抑制性，解决了强水敏性地层的井壁稳定等问题，还解决了深水钻井中遇到的挑战，如低的破裂压力梯度、天然气永合物、浅层水流、深水低温等问题，满足了该区块作业需要。     

Monitoring water quality in reservoirs with IRS-1A-LISS-I

An attempt has been made to quantify the relationship between the variation in IRS-IA-LISS-I (Indian Remote Sensing Satellite-1A Linear Imaging Self-Scanning System) radiance data and field measured change in secchi disc depth. Secchi disc depth was measured for 47 predetermined sampling locations on reservoir surface water. At extinction depth (secchi depth), water samples were collected from all the sampling locations. Suspended sediments of eight locations representing various reaches of the reservoir were selected for mineralogical, particle size and optical properties analysis. The LISS-I radiance value in band 1 (0.45–0.52µm) band 2 (0-52–0.59 µm) and band 3 (0.62–0.68 µm) were used in a regression analysis. The absorption infrared band 4 (0.77–0.86 µm) was not included in the analysis. In these, the dependable variable was secchi depth (SD) and the LISS-I-radiance data was the estimator variable. Forty-seven data sets of 20 October 1988 from Tawa reservoir surface water were used to obtain an estimator equation for SD. The verification of the estimator equation was tested by applying it to a data set of 21 measurements of 28 September 1988 for this reservoir. The coefficient of correlation between observed and estimated values for the 28 September 1988 data set wasr=0.92 for SD, indicating that the equation could accurately predict the water clarity (SD) for this reservoir on new occasions from IRS-IA-LISS-I spectral data. It is shown that mineral composition and optical properties of suspended sediments influence the reflected radiance of water quality. It is concluded that IRS-IA-LISS-I data provide a useful means of mapping water quality in reservoir.     

高黏原油和石英砂复配体系中水合物生成实验研究

在油井开采原油时,会产生伴生气,而在高压和低温环境中会生成天然气水合物,进而堵塞运输管道,因此研究油砂体系（含原油的体系）和纯石英砂体系（不含原油的体系）中水合物生成情况具有重要意义。在初始压力为4.00、6.00、8.00 MPa,石英砂粒径为20、30、60、80目,温度恒定的条件下,研究了油砂体系和纯石英砂体系中甲烷水合物的生成情况以及最终耗气量。结果表明,在初始压力相同的油砂体系中,石英砂粒径越小,水合物生成诱导期越短,水合物生成速率越大。研究石英砂粒径对水合物生成最终耗气量的影响发现,随着石英砂粒径的减小,耗气量先增加后减少,当石英砂粒径为60目时,耗气量达到最大,其值为0.19 mol。同时,对油砂体系和纯石英砂体系中水合物生成情况进行了对比。结果表明,由于两种体系中都存在SDS（十二烷基硫酸钠）溶液,因此水合物生成速率相差不大;在石英砂粒径相同的条件下,油砂体系中最终耗气量小于纯石英砂体系中的最终耗气量,这说明原油对水合物生成具有抑制作用。在油砂体系中,压力越大,越有利于水合物的生成。