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壳聚糖是一种生物聚合物。壳聚糖纺丝可制备具有可吸收性的医用手术缝线。本研究主要探讨壳聚糖的分子结构特征及化学性能,寻求壳糖纺丝的最佳工艺条件和成纤方法,为壳聚糖的深度开发应用提供基础、数据及方法。 相似文献
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Isothermal melt spinning experiments have been conducted using two polyethylene melts of low density (LDPE) and high density
(HDPE) to produce steady state spinline profiles. The data revealed the threadline extensional viscosity exhibiting a contrasting
picture : extension thickening behavior for LDPE and extension thinning one for HDPE. A White-Metzner model having a strain
rate-dependent relaxation time was then found to be able to simulate this dichotomy in melt spinning fairly well: the fluids
whose relaxation times have smaller strain rate-dependence can fit LDPE data with extension thickening extensional viscosity
whereas the fluids whose relaxation times have larger strain rate-dependence can fit HDPE data with extension thinning extensional
viscosity. This dichotomous nature of viscoelastic fluids is also believed to be able to explain other similar contrasting
phenomena exhibited by polymer melts, such as vortex/no vortex in entry flows, cohesive/ductile fracture modes in extension,
and more/less stable draw resonance than Newtonian fluids. 相似文献
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铝合金熔体旋转喷吹除气净化过程模拟 总被引:1,自引:0,他引:1
采用计算机模拟方法对铝合金熔体旋转喷吹除气净化过程的温度场以及流场进行分析。结果表明,在转杆内部放置一个导气管,可以显著降低气体温度,从而可以有效地解决旋转喷头由于熔剂因高温变软而堵塞的问题;旋转速度和进气流量对铝合金熔体旋转喷吹除气净化效果具有重要影响,应该根据具体情况选择合适的工艺参数。熔池为方形结构时,气体主要从对角处出去,而远离对角处的体积分数却显著降低,甚至可能发生吸气。 相似文献
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Chris I. Chiwetelu Graham H. Neale Vladimir Hornof 《Chemical Engineering Communications》1989,84(1):13-20
In reacting systems, dynamic interfacial tension (IFT) values above 10-20 mN/m are often encountered. For such high tension values, infinitely long oil droplets will not be realised in spinning drop tensiometry. Hence, Vonnegut's solution will not be strictly valid. The experimentalist is then compelled to use one of the several alternative solution schemes proposed in the literature. We have obtained dynamic IFT data for 0.3125 mM oleic acid in hexadecane contacted with various NaOH solutions by the use of a novel experimental scheme called photo-micropendography. These tension values were then compared with spinning drop tensiometer data calculated by using three alternative solution schemes, namely, Vonnegut's method, the formula of Slattery and Chen and the analysis of Princen el al. The comparison showed that when the droplet's length/width ratio was below 2.5, Vonnegut's formula was severely in error. The solution scheme proposed by Slattery and Chen gave tension values close to those found by photo-micropendography over the entire range of IFT values exhibited by the oleic acid/caustic systems. However, the most consistent and reasonably accurate tension values resulted from the use of Table I in the paper by Princen, Zia and Mason. A simplified computer algorithm has been proposed for calculating dynamic interfacial tensions using the formulas and tables proposed by the latter authors. However, at length/width ratios above 2.5, the agreement between interfacial tensions determined by micropendography and spinning drop data calculated by the use of Vonnegut's solution was quite good. 相似文献
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以QSn7-0.2锡青铜为试验材料,以减薄率、道次分配比、一道次进给比和二道次进给比为试验参数,设计正交试验,以成形件内外轴线直线度误差为评价指标,利用Simufact软件对二道次错距旋压进行数值模拟,利用Taguchi方法分析仿真结果的信噪比,优化试验参数,得到各参数对滑动轴承内外轴线直线度误差的影响程度顺序与最优工艺参数组合,并进行试验验证。结果表明,Taguchi方法可有效降低工件内外轴线直线度误差,提高产品性能。 相似文献
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