Predicting the thermodynamics of aluminum dross denitrification of flue gas

Existing alumina extraction and material production methods result in the formation of harmful ammonia gas or ammonia water originating from aluminum nitride (AlN) in dross. Therefore, in this study, aluminum dross was used as a denitration reagent to eliminate nitrogen oxides in flue gas and AlN in dross. Based on the proposed scheme, thermodynamic calculations were performed to investigate the denitrification effect and reduction of aluminum dross in flue gas. The results show that equilibrium concentrations of NO, NO₂, and HF in the flue gas were influenced mainly by temperature; their concentrations increased with an increase in the temperature, reaching 4.4 × 10⁻²⁰, 1.7 × 10⁻³⁸, and 7.0 × 10⁻⁸ g/m³, respectively, at 923 K. The Gibbs free energy corresponding to the reaction of CO₂ with Al/AlN in aluminum dross was −377/–120 kJ/mol. HF, originating from the reaction of NaF and water vapor, maintained an extremely low concentration of 6.99 × 10⁻⁸ g/m³ at 923 K. These results indicate that aluminum dross processing may clean the flue gas and increase the calorific value while eliminating the hazards of AlN. The results obtained herein will provide theoretical guidance toward new avenues of aluminum dross utilization.     

烟气轮机叶片寿命的影响因素和评估方法

合理准确预测烟气轮机叶片寿命,是催化裂化装置安全运行的必要保障。文章研究了影响烟气轮机叶片疲劳寿命的因素;评述了叶片疲劳寿命评估方法;选取并介绍了适合烟气轮机叶片寿命的评估方法;阐明了目前存在有关叶片寿命的关键问题。     

烟气轮机特殊状态下的保护

从烟气轮机超速的极限开始 ,分别按照阀门的关闭时间为 1 .5s和 6s的两种典型状态 ,对烟机在联轴节断裂等特殊工况下的超速情况进行了分析。最后 ,对烟气轮机在特殊工况下的保护提出了建议。     

腐殖酸对烤烟根系生长和生理活性的影响

对腐殖酸和基肥混施进行了烤烟盆栽试验。结果表明 ,腐殖酸能有效刺激根系的生理活性 ,提高根系抗坏血酸氧化酶、多酚氧化酶等呼吸酶的活性 ,增强根系的活力 ,并能有效促进烤烟根系生长 ,根干重、体积和长度均有提高。     

Predictive modeling of mercury speciation in combustion flue gases using GMDH-based abductive networks

Modeling mercury speciation is an important requirement for estimating harmful emissions from coal-fired power plants and developing strategies to reduce them. First-principle models based on chemical, kinetic, and thermodynamic aspects exist, but these are complex and difficult to develop. The use of modern data-based machine learning techniques has been recently introduced, including neural networks. Here we propose an alternative approach using abductive networks based on the group method of data handling (GMDH) algorithm, with the advantages of simplified and more automated model synthesis, automatic selection of significant inputs, and more transparent input–output model relationships. Models were developed for predicting three types of mercury speciation (elemental, oxidized, and particulate) using a small dataset containing six inputs parameters on the composition of the coal used and boiler operating conditions. Prediction performance compares favourably with neural network models developed using the same dataset, with correlation coefficients as high as 0.97 for training data. Network committees (ensembles) are proposed as a means of improving prediction accuracy, and suggestions are made for future work to further improve performance.     

催化裂化再生系统设备应力腐蚀开裂成因分析及解决对策

通过对催化裂化装置再生系统设备裂纹断口分析 ,以及对再生烟气的组分、冷凝水酸度及露点等的分析及对设备焊接残余应力测试 ,阐明了设备应力腐蚀开裂发生的原因 ,指出了富氧操作、高露点温度和高应力水平对再生系统设备应力腐蚀的影响作用 ,并重点提出了解决和防止应力腐蚀开裂的一系列有效措施和部分应用情况     

烟气轮机长周期高负荷运行的途径和方法

北京燕山分公司2000kt/a催化裂化装置的烟气轮机机组,在投运的几年内,存在电仪故障多、气轮机轴振动大及回收率低等一系列问题。通过技术攻关及操作优化,烟气轮机的轴振动值最大不超过70μm,发电量提高至13000kW·h以上,每年停机检修的时间可控制在15天以内,全年的净收效益将达到5460万元,每年可提高效益1620万元。与装置同步运转率由2004年的87%提高到96%,显著提高了经济效益和社会效益。     

改造加热炉系统 提高加热炉热效率

分析了重整装置加热炉热效率低的原因，介绍了提高加热炉热效率采取的几项措施。     

麻石烟气脱硫装置耐酸胶泥的研究

通过对用于麻石烟气脱硫装置的2^#和3^#耐酸胶泥的单因素对比试验的研究，得出2^#胶泥耐酸度较好，因而防腐蚀性能也较好。这不仅回收了固废，而且还具有可观的环境效益。     

采用有机盐─石膏脱硫剂的烟气脱硫新工艺

介绍一种利用有机羧酸盐作为吸收剂、以熟石灰作还原剂的烟气脱硫系统，在日本投入生产运行，其脱硫效率达９０％以上。