白钨矿浮选731捕收剂低温乳化试验研究

介绍了731捕收剂在低温条件下试验的情况。试验研究结果表明，采用A和B药剂以5：6的比例混合组成的复合乳化剂对731进行乳化，低温时乳化体系稳定性好，浮选过程中降低乳化731的用量，同时提高了选择性，降低了浮选成本，实现了低温环境下白钨矿正常浮选作业，达到选矿技术攻关指标。     

细磨活化对白钨矿浸取行为的影响SCIEI

本文研究了细磨活化对白钨矿浸取行为的影响.实验结果表明,细磨活化后白钨矿在HCl-Na_3PO_4介质中的浸出速率显著加快,钨的浸出率由原来的约8％提高到99％以上.红外光谱和X射线分析结果表明,细磨除了使白钨矿比表面积显著增大外,还在固体的表面和内部产生缺陷结构,增加了矿物表面的反应活性,改善了白钨矿的分解,使得白钨矿的浸出能在较低的温度顺利进行。     

掺钡白钨矿型CaWO4:Ba2+荧光材料的制备与表征

以氯化钙、氯化钡和硝酸钠为原料,采用沉淀法制备出纯CaWO4、BaWO4粉体,采用固相反应法制备出CaWO4:Ba2+(CaxBa1-xWO4)粉体,研究了钡离子的掺杂量对CaWO4:Ba2+荧光材料的发光性能的影响.通过XRD、FT-IR对样品的晶体尺寸进行表征,以及PL分析了样品的发光特性.研究结果表明:掺杂后钨酸盐中的晶胞参数随Ba2+的掺杂量增加而增大,且晶体结构中WO2-4四面体构型发生畸变;钨酸钙的在370 cm-1、430 cm-1附近有明显发光,当钡离子掺入量较低时,CaWO4:Ba2+的发光强度增加,但当钡离子掺入量增加时,发光强度却下降.     

A decomposing technique for scheelite concentrate and low-grade scheelite concentrate

The effect of different decomposition conditions on tungsten recovery for scheelite concentrate has been examined. The results show that tungsten recovery can be more than 98% under decomposing conditions as follows: the amount of caustic soda is 2.2 and 3.2 times of theoretical respectively, ratio of water and ore is 0.7-0.8, temperature is 160℃, and preservation time is 2.0 h for scheelite concentrate (63.21% WO3) and low grade scheelite concentrate (55.17% WO3).     

Production of high purity APT from scheelite and complex tungsten raw material with high Mo content

More than 73% of the tungsten resources in China are scheelite and 41% are high molybdenum content ores, and their dressing becomes increasingly difficult. Such situation calls for new and advanced processes that can treat complex ores and still attain high overall recovery of tungsten. The novel NaOH digestion process and selective precipitation process was developed. The former is universal for leaching tungsten from various tungsten materials,including scheelite concentrate and keeps most of the impurity elements P, As and Si in residue; while the latter is effective for removing impurities such as Mo and Sn. Combined with the traditional ion exchange process, the new process can be used to produce APT that confirms with the Chinese National Standard GB10116-88APT-0 with crystallization ratio of 95%. When treating high molybdenum scheelite concentrate from Shizhuyuan Deposit with WO3 content of 50%-55%, recovery of the new process may reach up to about 95% which is grossly the same as that from the traditional way for treating standard wolframite concentrates.     

电化学法制备BaMoO_4和SrMoO_4薄膜的生长特性比较研究(I):共性分析

采用恒电流电化学技术直接在金属钼片上制备了具有白钨矿结构的钼酸盐(BaMoO4、SrMoO4)薄膜,对制备时间分别为10s直到50min的BaMoO4薄膜和制备时间分别为1min直到100min的SrMoO4薄膜的生长情况进行了SEM测试,并对相应结果进行了对比分析。研究表明:用电化学法制备BaMoO4和SrMoO4晶态薄膜,其生长特性既具有共性,也具有鲜明的个性。其共性特征是:1)成膜机制相同;2)薄膜生长初期就有比较完整的晶核生成;3)晶核和晶粒优先选择在金属基体缺陷(折叠、划痕、缺陷、凹凸不平等)处堆砌和生长;4)基体上晶粒的数量随着制备时间的增加而增加,晶粒的尺寸也随着时间的延长而长大,晶粒逐渐从稀疏分布到布满整个基体;5)在具有白钨矿结构的钼酸盐晶态薄膜的生长过程中,晶体的{111}面总是显露的。其鲜明的个性特征将在另文中讨论。该研究结果对功能晶态薄膜的生长(特别是利用电化学技术制备功能晶态薄膜的生长)和了解及预测白钨矿结构的晶态薄膜的生长习性,均具有重要意义。     

工艺参数对白钨矿直接炼钢的影响

通过实验研究了工艺参数对白钨矿收得率的影响规律。完全用白钨矿冶炼含钨高的合金钢(9%W)是可行的。硅铁还原白钨矿时,炉渣碱度应控制在1.5以下。碳粉还原白钨矿时,渣中最好不要添加CaF2。硅铁和碳混合还原剂还原白钨矿时,碳还原白钨矿比例控制在30%以下能取得较好的还原效果。     

从浮选尾矿中回收白钨矿试验研究

为充分利用矿产资源,提高企业效益,经过近2年的技术攻关,直接从硫化矿浮选尾矿中浮选回收白钨矿试验获得成功。通过粗选工业试验和粗精矿加温小型试验,在白钨入选品位0.25%的条件下,取得了白钨精矿65.046%、回收率50.47%的较好指标。对项目进行可行性研究论证,预计投产后能大幅提高企业效益。     

白钨矿浸出工艺的现状及发展方向

本文从热力学和动力学角度对我国白钨矿浸出的几种主要工艺进行了分析介绍,并指出了白钨矿分解方法的发展趋势及方向。