新型常温捕收剂DN-6对磷灰石的捕收性能研究

为降低北方磷矿厂的选矿成本，提高浮选指标，东北大学研制了一种常温磷灰石捕收剂DN-6。为检测DN-6的浮选性能，进行了单矿物浮选试验，并通过Zeta电位检测和傅里叶变换红外光谱分析对该捕收剂在磷灰石表面的作用机理进行了研究。单矿物浮选试验结果表明，在矿浆pH=7.6，矿浆温度28 ℃，DN-6用量为166.7 mg/L的浮选条件下，捕收剂DN-6对磷灰石单矿物的浮选回收率可达97.59%。Zeta电位和傅里叶变换红外光谱分析表明，pH＜4时，DN-6在磷灰石表面发生键合吸附。     

应用磷灰石裂变径迹分析(AFTA)方法研究沉积盆地古地温

在应用磷灰石裂变径迹 (AFTA)方法研究沉积盆地古地温的原理、研究现状以及应用中应该注意一些问题 ,并以具体例子进行了说明。可以看出 ,应用磷灰石裂变径迹方法研究沉积盆地古地温是一种行之有效的方法 ,能够为古地温场的研究提供可靠的依据 ,并且可用于研究盆地构造运动。     

溶胶-凝胶法制备HAP骨水泥材料的研究

文章对用溶胶－凝胶法（简称SOL－GEL）烧结制备HAP骨水泥材料的工艺条件进行了研究，并探索了HAP粉剂与柠檬酸水溶液构成和凝结体系的可行性，结果显示出该材料作为医用骨水泥材料的可能性。     

Preparation of Laminin-apatite-polymer Composites Using Metastable Calcium Phosphate Solutions

A synthetic polymer with a laminin-apatite composite layer on its surface would be useful as a percutaneous device. The preparation of such a composite was attempted in the present study using poly（ ethylene terephthalate ） （PET） and polyethylene （PE） as the synthetic polymer. PET and PE plates and those pretreated with an oxygen plasma were alternately dipped in calcium and phosphate ion solutions, and then immersed in a metastable calcium phosphate solution supplemented with laminin （ LCP solution ）. The PET and PE plates pretreated with an oxygen plasma formed a uniform and continuous layer of a laminin-apatite composite on their surfaces. In contrast, the PET and PE plates that had not been pretreated with an oxygen plasma did not form a continuous layer of a laminin-apatite composite on their surfaces. The hydrophilic functional groups on the PET and PE surfaces introduced by the plasma treatment were responsible for the successful laminin-apatite coruposite coating.     

羟基磷灰石涂层人工关节的应用研究

采用人工合成高纯度的羟基磷灰石粉末，喷涂在具有注册证的钛合金和钴铬钼合金人工关节上。通过生物学基础检测、动物实验和临床试用，证明所制作的各种羟基磷灰石涂层人工关节，能诱发骨质生长，起生物固定作用，对治疗丧失功能的骨胳效果甚佳。     

HAP陶瓷合成的研究

本文对生物陶瓷材料－羟基磷灰石的合成进行了研究。试验将激光合成与湿法合成对比分析，着重探讨了在激光辐照下生物陶瓷的形貌，粒度，化学组成和结构等的变化规律，对激光涂敷生物陶瓷涂层有一定的指导意义。     

溶胶-凝胶生物玻璃多孔材料显微结构和生物活性的扫描电镜及红外光谱分析

本文利用溶胶．凝胶法制备了CaO-P2O5-SiO，系统生物活性玻璃，并以其为原料制备了用于骨修复及骨组织工程支架的块状生物活性材料。利用体外实验方法(invitro)结合x射线衍射(XRD)、扫描电子显微镜(SEM)和傅立叶变换红外光谱分析(FTIR)技术对不同烧结工艺制备的材料结构、晶相和生物活性的影响进行了分析研究。研究表明，经800℃和1100℃烧结5min的两种材料均有硅磷酸钙Ca5(PO4)2SjO4微晶相析出。烧结温度越高，析出微晶相的体积比例越大，材料的生物活性则越低。在模拟生理溶液中碳酸羟基磷灰石(HCA)只在烧结体中的玻璃颗粒表面形成，而在其硅磷酸钙Ca5(PO4)2SiO4微晶相表面未发现HCA形成。     

Sol-gel Preparation and Preliminary in vitro Evaluation of Fluorapatite／Hydroxyapatite Solid Solution Films

Fluorapatite/hydroxyapatite solid solution has better biological properties than other apatites, especially used as films or coatings. In this work, sol-gel preparation and in vitro behavior of fluorapatite/hydroxyapatite solid solution films on titanium alloy were investigated. Ca(NO3)2-4H20 and PO(OH)x(OEt)3-x were selected as precursors, and hexafluorophosphoric acid (HPFo) was used as a fluorine containing reagent. The Ca and P precursors were mixed with HPFo to keep the Ca/P molar ratio 1.67. The mixtures refluxed for 12 h were used as dipping sols for the preparation of the films. The phase of the films obtained at 600℃ was apatite. The F contents in the films increased with the concentrations of HPF6 in the dipping sols. The solid solution films were shown to have better stability than hydroxyapatite films, and a reasonably good bioactivity in the in vitro evaluation.     

迁安精矿粉高碱度烧结矿试验研究

对迁安地区磁选精矿粉添加磷石粉和Ｂ２Ｏ３，生产二元碱率为２．０左右的高碱度烧结矿，在实验室和现场进行了试验。结果表明：加入少量磷灰石粉或硼即可完全抑制烧结矿冷却过程中的自然粉化现象；ＭｇＯ含量对烧结矿质量影响明显；烧结矿的冶金性能良好。