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1.
In this research, maleic anhydride-α-octadecene copolymer and its derivative with phenylethylamine was synthesized and its effect on the crystallization of paraffins was investigated. This derivative, when added into second cut of vacuum gas oil and forth cut of vacuum gas oil, increases the size and improves aggregation of paraffin crystals observed by polarizing light microscopy, increases onset temperature and enthalpy of paraffin crystallization determined by differential scanning calorimetry, improves the dewaxing efficiency with dosage of 100?ppm explored by MEK-toluene dewaxing. 相似文献
2.
Gibbs energies of formation of CoF2 and MnF2 have been measured in the temperature range from 700 to 1100 K using Al2O3-dispersed CaF2 solid electrolyte and Ni+NiF2 as the reference electrode. The dispersed solid electrolyte has higher conductivity than pure CaF2 thus permitting accurate measurements at lower temperatures. However, to prevent reaction between Al2O3 in the solid electrolyte and NiF2 (or CoF2) at the electrode, the dispersed solid electrolyte was coated with pure CaF2, thus creating a composite structure. The free energies of formation of CoF2 and MnF2 are (± 1700) J mol−1; {fx37-1} The third law analysis gives the enthalpy of formation of solid CoF2 as ΔH° (298·15 K) = −672·69 (± 0·1) kJ mol−1, which compares with a value of −671·5 (± 4) kJ mol−1 given in Janaf tables. For solid MnF2, ΔH°(298·15 K) = − 854·97 (± 0·13) kJ mol−1, which is significantly different from a value of −803·3 kJ mol−1 given in the compilation by Barinet al. 相似文献
3.
采用DSC对不同分子量的聚醚酰亚胺的等温及动态热焓松弛行为进行了研究,并以KWW方程对实验数据进行了非线性拟合。结果表明,分子量对热焓松弛的影响是由高分子端基引起自由体积的差异所致。不同分子量的聚醚酰亚胺分子具有不同数量的端基,淬冷时端基数目的差异将产生不同数量的过剩自由体积,从而影响松弛热焓及松弛速率、低分子量的聚醚酰亚胺松弛相对较快,且起始热焓高,松弛的表观活化能亦较小。 相似文献
4.
本文推荐陈林根编著的《工程化学》对化学热力学基本公式△G=△H-T△S的引出方法,试探基础教学的改革。 相似文献
5.
从汽轮机回热系统的实际情况出发,运用非线性规划理论和计算机技术,解决了给水焓升设计中的最优分配问题。结合具体实例,针对国产200MW汽轮机回热系统给水焓升的分配进行了说明。 相似文献
6.
J. Gajdoš Kljusurić 《Sadhana》2003,28(6):991-998
This work is an experimental study of the differential scanning calorimetry characterisation of polymer materials used in
food packaging materials, such as polypropylene (0.03 mm), polyethylene (0.1 and 0.03 mm), poly(D-(-)-Β-hydroxybutyrate) (powder),
two-layered polypropylene (0.064 mm), and two-layered polypropylene with poly-vinylidene-chloride (0.012/0.021). The polymer
stability was checked by simulation of conditions during food preparation in microwave ovens, sterilisation or rapid freezing.
The materials were tested in the temperature range from 40 to 200‡C at different scan rates from 2 to 30°C min−1 during heating or cooling. The enthalpies show a high correlation coefficient (0.964) with scan rate. All samples undergo
phase change in the temperature range from 107 to 173°C during heating and enthalpies are in the range from 31.8 to 71.1Jg−1. Upon subsequent cooling from 200°C, the temperature range of phase changes is shifted to lower temperatures from 86 to 102°C
with enthalpies ranging from 30.4 to 57.8 J g−1.
Experiments with exposure of polymers to microwave radiation and freezing prove that the phase change considering the temperature
range is very similar in all experiments. 相似文献
7.
Sipra Mahapatra Turaga P. Prasad 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1992,53(2):201-203
Hydrolysis of Fe(OH)SO4 was carried out in the presence of metallic iron in order to prevent the formation of iron(III) oxides with strongly bonded sulphate. Under the conditions of the experiment, the products were found to be mixtures of ?-Fe2O3 and α-FeOOH. The occluded sulphate, if any, could be easily washed out with water. The hydrolysis reaction passes through an equilibrium state before coming to completion. The entropy with enthalpy of the hydrolysis corresponding to the equilibrium state were found to be 4 e.u. and 0·5 kJ/mol, respectively. The activation energy of the hydrolysis reaction was found to be 21 kJ/mol. 相似文献
8.
Wire-shaped zinc samples were resistively volume heated as part of a fast-capacitor discharge circuit. Time-resolved measurements with submicrosecond resolution of the current through the specimen, the voltage drop across it, and the thermal expansion of the specimen as a function of time allow determination of the enthalpy, electrical resistivity, and density at different temperatures up to superheated liquid states of zinc far above the normal boiling point. High static pressures, up to 3800 bar of the ambient medium water, were used. An estimate of the critical pressure for zinc is given by investigations of the stability of the sample with a framing CCD camera, taking pictures of different samples varying the ambient static pressure. The critical volume and the critical temperature are obtained by means of an extrapolation of measured data at different pressures.Paper presented at the Fourth International Workshop on Subsecond Thermophysics, June 27–29, 1995, Köln, Germany. 相似文献
9.
10.
蒸发式冷凝在制冷工艺上的应用 总被引:3,自引:0,他引:3
分析对比制冷工艺中几种冷凝方式,指出发展蒸发式冷凝技术对制冷系统节能的重要意义;通过分析蒸发式冷凝的换热机理,在试验和实践的基础上讨论了影响蒸发式冷凝器性能的几个重要因素。 相似文献