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1.
《International Journal of Hydrogen Energy》2022,47(72):30830-30842
Carbon dioxide (CO2) and methane (CH4) are the primary greenhouse gases (GHGs) that drive global climate change. CO2 reforming of CH4 or dry reforming of CH4 (DRM) is used for the simultaneous conversion of CO2 and CH4 into syngas and higher hydrocarbons. In this study, DRM was investigated using Ag–Ni/Al2O3 packing and Sn–Ni/Al2O3 packing in a parallel plate dielectric barrier discharge (DBD) reactor. The performance of the DBD reactor was significantly enhanced when applying Ag–Ni/Al2O3 and Sn–Ni/Al2O3 due to the relatively high electrical conductivity of Ag and Sn as well as their anti-coke performances. Using Ag–Ni/Al2O3 consisting of 1.5 wt% Ag and 5 wt% Ni/Al2O3 as the catalyst in the DBD reactor, 19% CH4 conversion, 21% CO2 conversion, 60% H2 selectivity, 81% CO selectivity, energy efficiency of 7.9% and 0.74% (by mole) coke formation were achieved. In addition, using Sn–Ni/Al2O3, consisting of 0.5 wt% Sn and 5 wt% Ni/Al2O3, 15% CH4 conversion, 19% CO2 conversion, 64% H2 selectivity, 70% CO selectivity, energy efficiency of 6.0%, and 2.1% (by mole) coke formation were achieved. Sn enhanced the reactant conversions and energy efficiency, and resulted in a reduction in coke formation; these results are comparable to that achieved when using the noble metal Ag. The decrease in the formation of coke could be correlated to the increase in the CO selectivity of the catalyst. Good dispersion of the secondary metals on Ni was found to be an important factor for the observed increases in the catalyst surface area and catalytic activities. Furthermore, the stability of the catalytic reactions was investigated for 1800 min over the 0.5 wt% Ag-5 wt% Ni/Al2O3 and 0.5 wt% Sn-5 wt% Ni/Al2O3 catalysts. The results showed an increase in the reactant conversions with an increase in the reaction time. 相似文献
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In this investigation, low-cement castables were prepared using 70% alumina grog aggregates obtained from crushed alumina brick waste. The aggregates were thermally treated at 1550 °C for 3 h. Four types of low-cement castables were prepared with various types of aggregates (alumina grog with or without thermal treatment) and fillers (with or without zircon addition), and they were evaluated in terms of their physical, thermal, and chemical properties. Microstructural analysis via scanning electron microscopy (SEM) was performed on the castables before and after slag attack. Compared to the other fabricated castables, the thermally treated alumina grog castables with zircon showed better physical properties, such as a higher bulk density, cold crushing strength, and modulus of rupture and a lower apparent porosity and water absorption. In addition, they had a higher positive linear thermal expansion, refractoriness under load, permanent linear change, and hot modulus of rupture. The results of the SEM with energy dispersive X-ray analysis of the prepared castables confirmed that the mullite and anorthite phases were predominant when zircon was not added and the zircon–mullite phase additionally appeared upon the incorporation of zircon. A quantitative elemental analysis via X-ray fluorescence spectroscopy was employed to determine the composition of the castables. X-ray diffraction analysis showed that the alumina grog castables had a high mullite and low anorthite content, and the thermally treated alumina grog had a high anorthite, low mullite, and high zircon content. The improvement in the mechanical and thermo-mechanical properties of the castables with thermally treated alumina grog and added zircon can be attributed to the formation of the zircon–mullite phase with a low mullite phase content. 相似文献
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为抑制铝碳质长水口使用过程中石墨的氧化,其表面会涂覆含 20%~30%Al2O3的抗氧化涂层,但切割丝钢等特种钢冶炼过程必须严格控制钢液中夹杂的 Al2O3的含量,因此需要制备低氧化铝含量的抗氧化涂层。本文通过调节涂料组成、加水量和水玻璃加入量制备了低铝抗氧化涂层,并利用扫描电镜分析了抗氧化实验后试样断口的显微结构。结果表明:以粘土粉、钾长石粉和硅砂为主要原料,添加 10%硼砂的涂料可在 800 ℃形成良好的釉层,此时涂料中 A12O3的含量可降至 12%,得到了低铝涂料;当加入占涂料质量 80%的水和 40%的水玻璃时,涂层具有最佳的涂覆性能和抗氧化性能,涂层和长水口基体结合致密,保护了长水口中的石墨不被氧化。 相似文献
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分析了乐滩灌区工程北干渠溯河隧洞段长约1.06 km穿合山煤矿采空区的地质情况.借鉴高速公路煤矿采空区的成功处理经验,通过科学分析,对采空区变形和区域内覆岩的稳定性做了评价,论述了输水线路穿采空区段采取全充填压力注浆法的工程处理方法. 相似文献
10.
研究了采用超临界流体萃取技术(SFEF),以减压渣油和催化裂化油浆为原料,制备重交通道路沥青产品的可行性.结果表明:当原料中油浆掺入量为10%~30%时,可以生产出牌号为AH70,AH90,AH110的重交通道路沥青产品.工业试验表明,生产牌号为AH70,AH90的重交通道路沥青,采用此技术方案是可行的. 相似文献