反凝析现象对雅克拉凝析气处理工艺的影响

雅克拉凝析气田位于塔里木盆地北部，地处新疆维吾尔自治区阿克苏地区境内，它是中国石化集团公司西北分公司探明并投入开发的最大凝析气田，采用衰竭式开采。通过对井口物流的相态研究，认识了凝析气的反凝析规律，采取了提高凝析气中C^＋₃收率的方法，以确保外输干气的烃露点达到管输要求，并提高该气田开发的经济效益。在工艺方案设计过程中，通过多种工艺方案比选，确定选用膨胀机进口压力为6.0 MPa的膨胀机制冷工艺， C^＋₃收率达到92％以上，外输干气烃露点满足管输要求。     

严寒地区双层窗的防冷凝研究

本探讨了北方双层窗的严重的冷凝现象及其给室内环境带来的危害。并提出了防止双层窗冷凝的GM－I型和GM－Ⅱ型设计方案，并以大量实验数据为依据，证实了该所提方案的实际应用价值。     

邻—(4—乙基苯甲酰基)苯甲酸的研究

本文阐述了通过Friedel-Crafts反应合成邻-(4-乙基苯甲酰基)苯甲酸的方法.研究了影响产物质量的因素,提出了适宜的工艺条件.     

Asymmetric Hydrogenation of Activated Ketones on Platinum: Relevant and Spectator Species

The heterogeneous enantioselective hydrogenation of activated ketones over chirally modified platinum is reviewed with emphasis on identifying the role of the various species observed in this catalytic system. The past years have witnessed a continuous broadening of the scope of this catalytic system including new reactants and modifiers affording over 97% ee. New reaction pathways have been uncovered and the kinetic and mechanistic studies have been faced with a number of complicating factors caused by spectator species and interactions in solution and on the Pt surface. The previously proposed mechanistic models are critically assessed in the light of these new findings.     

Synthesis and characterisation of copolyesters from poly(ethylene terephthalate) and poly(hexamethylene terephthalate)

Copolyesters containing poly(ethylene terephthalate) and poly(hexamethylene terephthalate) (PHT) were prepared by a melt condensation reaction. The copolymers were characterised by infrared spectroscopy and intrinsic viscosity measurements. The density of the copolyesters decreased with increasing percentage of PHT segments in the backbone. Glass transition temperatures (T_g). melting points (T_m) and crystallisation temperatures (T_c) were determined by differential scanning calorimetry. An increase in the percentage of PHT resulted in decrease in T_g, T_m and T_c. The as-prepared copolyesters were crystalline in nature and no exotherm indicative of cold crystallisation was observed. The relative thermal stability of the polymers was evaluated by dynamic thermogravimetry in a nitrogen atmosphere. An increase in percentage of PHT resulted in a decrease in initial decomposition temperature. The rate of crystallisation of the copolymers was studied by small angle light scattering. An increase in percentage of PHT resulted in an increase in the rate of crystallisation.     

濮城油田濮67块低渗凝析难动用气藏挖潜技术研究

濮67块具有埋藏深、物性条件差、储量难动用程度低等特点，目前气藏采出程度很低，开发效果差。通过对濮67块天然气储量再认识，落实了该块储量；通过对濮67块各砂组剩余天然气分布规律的研究，明确了剩余气的下步挖潜方向；并开展了配套的剩余天然气挖潜技术研究，通过在生产中应用，取得了较好的增产效果，提高了气藏的采收率。     

A Convenient Synthesis of Some Coumarin Derivatives Using SnCl2 · 2H2O as Catalyst

Some substituted coumarins have been synthesized by von-Pechmann condensation using SnCl₂ · 2H₂O (10 mol %) as catalyst in ethanolic medium. The reactions are simple, easy in handling and environmentally benign.     

负载型固体碱催化合成亚苄基丙酮

研究了用固体碱 KOH/Al_2O_3催化合成苯叉丙酮,确定了合成的最佳工艺条件:n(苯甲醛)∶n(丙酮)=1∶4.催化剂用量2g,催化剂最佳负载量12mmol/g,反应温度40～45℃,反应时间为3h,产率达88%以上。     

AHMED experiments on hygroscopic and inert aerosol behaviour in LWR containment conditions: experimental results

Hygroscopic NaOH, CsI, CsOH and inert Ag aerosol behaviour at different temperatures and relative humidities (RH) has been studied in a well instrumented and controlled vessel of 1.81 m³ total free volume. Homogeneous thermal-hydraulic conditions for aerosol measurement in the vessel were achieved. The aerosol number and mass concentration were measured continuously during the experiments using a Condensation Nucleus Counter and a Tapered Element Oscillating Microbalance. The particle size distribution and chemical composition in the test conditions were measured by Berner low pressure impactors. In the case of NaOH the half life of the aerosol mass concentration was more than four times longer at low RH (22%) as compared to high RH (96%). The half lives of the CsOH and CsI aerosols were only twice as long at low RH as compared to high RH. Thus at high RH (96–97%) the half lives of CsOH and CsI were twice as long as the half life for the NaOH aerosol. The faster decay of the NaOH aerosol is due to the smaller density decrease of NaOH during water condensation. CsOH particles grew rapidly to their equilibrium size at all humidities. The measured equilibrium size for CsOH aerosol agree well with the calculated particle size at different RHs. Experimental results were also compared with calculations obtained by severe accident computer codes. These calculated results will be presented in a later paper.