全文获取类型
收费全文 | 4723篇 |
免费 | 231篇 |
国内免费 | 114篇 |
学科分类
工业技术 | 5068篇 |
出版年
2024年 | 14篇 |
2023年 | 36篇 |
2022年 | 62篇 |
2021年 | 93篇 |
2020年 | 94篇 |
2019年 | 84篇 |
2018年 | 73篇 |
2017年 | 100篇 |
2016年 | 114篇 |
2015年 | 104篇 |
2014年 | 192篇 |
2013年 | 239篇 |
2012年 | 280篇 |
2011年 | 320篇 |
2010年 | 263篇 |
2009年 | 305篇 |
2008年 | 253篇 |
2007年 | 289篇 |
2006年 | 293篇 |
2005年 | 270篇 |
2004年 | 249篇 |
2003年 | 195篇 |
2002年 | 177篇 |
2001年 | 166篇 |
2000年 | 134篇 |
1999年 | 153篇 |
1998年 | 111篇 |
1997年 | 98篇 |
1996年 | 64篇 |
1995年 | 48篇 |
1994年 | 36篇 |
1993年 | 29篇 |
1992年 | 29篇 |
1991年 | 20篇 |
1990年 | 13篇 |
1989年 | 12篇 |
1988年 | 11篇 |
1987年 | 7篇 |
1986年 | 6篇 |
1985年 | 8篇 |
1984年 | 10篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1959年 | 1篇 |
1956年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有5068条查询结果,搜索用时 515 毫秒
1.
《International Journal of Hydrogen Energy》2020,45(57):32856-32864
The electrode ionomer is a key factor that significantly affects the catalyst layer morphology and fuel cell performance. Herein, sulfonated poly(arylene ether sulfone)-based electrode ionomers with polymers of various molecular weights and alcohol/water mixtures were prepared, and those comprising the alcohol/water mixture showed a higher performance than the ones prepared using higher boiling solvents, such as dimethylacetamide; this is owing to the formation of the uniformly dispersed ionomer catalyst layer. The relation between ionomer molecular weight for the same polymer structure and the sulfonation degree was investigated. Because the chain length of polymer varies with molecular weight and chain entanglement degree, its molecular weight affects the electrode morphology. As the ionomer covered the catalyst, the agglomerates formed were of different morphologies according to their molecular weight, which could be deduced indirectly through dynamic light scattering and scanning electron microscopy. Additionally, the fuel cell performance was confirmed in the current-voltage curve. 相似文献
2.
Vaidhegi Kugarajah Moogambigai Sugumar Elamathi Swaminathan Nagaraj Balasubramani Sangeetha Dharmalingam 《International Journal of Hydrogen Energy》2021,46(42):22134-22148
Hydrothermally prepared zinc oxide nanorods are sulphonated (S–ZnO NR) and incorporated into 15% Sulphonated Poly (1,4-Phenylene Ether Ether Sulfone) (SPEES) to improve the hydrophilicity, water uptake and ion transfer capacity. Water uptake and ion transfer capacity increased to 34.6 ± 0.6% and 2.0 ± 0.05 meq g?1 from 29.8 ± 0.3% and 1.4 ± 0.04 meq g?1 by adding 7.5 wt% S–ZnO NR to SPEES. Morphological studies show the prepared S–ZnO NR is well dispersed in the polymer matrix. SPEES +7.5 wt% S–ZnO NR membrane exhibits optimum performance after three-weeks of continual operation in a fabricated microbial fuel cell (MFC) to produce a maximum power density of 142 ± 1.2 mW m?2 with a reduced biofilm compared to plain SPEES (59 ± 0.8 mW m?2), unsulphonated filler incorporated SPEES (SPEES + 7.5 wt% ZnO, 68 ± 1.1 mW m?2) and Nafion (130 ± 1.5 mW m?2) thereby suggesting its suitability as a sustainable and improved cation exchange membrane (CEM) for MFCs. 相似文献
3.
The potential energy profile of the reaction between dimethyl disulfide and OH? radicals is explored by utilizing ab initio and hybrid meta density functional theory methods. Having the energies and structural data of the stationary points, statistical rate theories, such as transition state theory and variable reaction coordinate-transition state theory, are employed to compute the overall rate constants, and discuss the mechanism and product channels. On the basis of the calculations, the overall rate coefficient is predicted to be 2.49?×?10?10?cm3?molecule?1?s?1 at 298?K. It is found that in the most favorable pathway, the reaction proceeds via formation of the relatively unstable intermediate CH3S?(OH)SCH3 decomposing rapidly to yield CH3S?+CH3SOH. 相似文献
4.
《International Journal of Hydrogen Energy》2020,45(16):9803-9810
High ion selectivity and mechanical strength are critical properties for proton exchange membranes in vanadium redox flow batteries. In this work, a novel sulfonated poly(ether sulfone) hybrid membrane reinforced by core-shell structured nanocellulose (CNC-SPES) is prepared to obtain a robust and high-performance proton exchange membrane for vanadium redox flow batteries. Membrane morphology, proton conductivity, vanadium permeability and tensile strength are investigated. Single cell tests at a range of 40–140 mA cm−2 are carried out. The performance of the sulfonated poly(ether sulfone) membrane reinforced by pristine nanocellulose (NC-SPES) and Nafion® 212 membranes are also studied for comparison. The results show that, with the incorporation of silica-encapsulated nanocellulose, the membrane exhibits outstanding mechanical strength of 54.5 MPa and high energy efficiency above 82% at 100 mA cm−2, which is stable during 200 charge-discharge cycles. 相似文献
5.
6.
二氧化碳加氢直接合成二甲醚催化剂的研究——沉淀次序对复合催化剂结构和性能的影响 总被引:2,自引:0,他引:2
以草酸乙醇溶液为沉淀剂,采用不同的沉淀次序(并流、反加和正加)制备了CuO-ZnO-Al2O3/HZSM-5复合型催化剂,对CO2加氢直接合成二甲醚反应的催化活性顺序为:并流法催化剂>反加法催化剂>正加法催化剂。3种复合催化剂的还原温度由低到高的顺序为:并流法催化剂<反加法催化剂<正加法催化剂。在沉淀过程中,反加法和正加法均形成类胶体沉淀,相应催化剂的比表面积也较大。IR研究发现,催化剂在1101cm-1处表现Cu/Zn/Al氧化物与HZSM-5分子筛之间相互作用的IR吸收峰强度与其催化活性间存在对应关系。XRD结果表明,并流法得到的催化剂前驱体中有铜锌同形取代现象,有利于催化剂活性的发挥。 相似文献
7.
分子筛绿色化合成技术的开发 总被引:3,自引:0,他引:3
对现有分子筛合成废液中氨氮及还原性物质的来源进行分析,确定降低排放废水中氨氮浓度及COD的方案。对现有ZRP-5分子筛制备流程进行优化,增加母液及赶胺水回用工序;建立母液浓缩装置,将钛硅分子筛及Β分子筛的合成母液及重排母液应用于ZSM-5分子筛的合成,实现废液的梯级利用。上述措施既解决了因分子筛生产废液的排放造成的环境污染,亦因废物资源化降低了ZSM-5分子筛的生产成本。 相似文献
8.
9.
SIMULATION STUDIES OF THE REMOVAL OF WATER FROM ETHANOL BY A CATALYTIC DISTILLATION PROCESS 总被引:1,自引:0,他引:1
Christina B. Dirk-Faitakis Karl T. Chuang 《Chemical Engineering Communications》2005,192(11):1541-1557
A new approach based on catalytic distillation (CD) technology was proposed to remove water from ethanol. Isobutylene was introduced to react with water in the CD column. The commercial software simulation tool Aspen Plus was used to investigate the effects of key design factors such as operating pressure and temperature, reactant ratios, reflux and distillate to feed ratios, number of separation and reaction stages, and feed and reaction zone location. It was found that the CD technology offers potential advantages of reduced energy consumption and reduced capital cost over traditional approaches for the removal of water from ethanol. 相似文献
10.
Andrés Rigail-Cedeño 《Polymer》2005,46(22):9378-9384
Cure reactions of the stoichiometric mixtures of diglycidyl ether of bisphenol A (DGEBA) and two very low molecular weight aliphatic polyether diamines (PED) were studied by using fluorescence and mid- and near-IR spectroscopic techniques. As the cure proceeded, the primary amine groups in PED are converted to the secondary and the tertiary amines. Near-IR spectral analysis was used to calculate the concentration of the three amine groups as a function of cure time. The decrease in the fluorescence intensity of DGEBA at about 307 nm was observed due to more effective quenching of the tertiary amine groups in PED, in comparison to the primary and the secondary amine groups. A large decrease in fluorescence intensity at 75 and 95 °C cure was observed. The amount of all the amine species was estimated from NIR spectra to shed light on the cure kinetics of PPO (polypropylene oxide) in comparison with PEO (polyethylene oxide) epoxy, as well as to explain their fluorescence behavior.The fluorescence intensity changes were correlated to the extent of epoxy reaction obtained by mid- and near-IR spectroscopy. 相似文献