Effect of the addition of silver compounds during the pyrolysis of manganese nitrate on tantalum anodic oxide film

A study of the pyrolysis of an aqueous solution of manganese nitrate in the presence of silver compounds has been carried out. Thermal analysis showed that the MnO₂ formation temperature and the transformation temperature from MnO₂ to Mn₂O₃ shifted towards a lower temperature in the presence of silver acetate. A large particle-size and high crystallinity MnO₂ was formed; this may be a useful method of making an excellent tantalum capacitor with high capacitance.     

MIM capacitor fabrication and assessment for GaAs MMICs

Metal-insulator-metal, MIM, capacitors have been fabricated using plasma deposited silicon nitride, SiN_x, films deposited under varying deposition conditions. The electrical properties of the MIM capacitors and the corresponding physical properties of the SiN_x films have been determined. The breakdown field strength of the films, which varied between 0.4–3.0 MVcm⁻¹, has been related to the amount of hydrogen incorporated in the SiN_x layers during deposition. Frenkel-Poole conduction through the silicon nitride has been observed at room temperature and this conduction mechanism is shown to be predominant and independent of the breakdown field strength, for the films investigated.     

Topological domain-engineered antiferroelectric-like behavior with enhanced energy storage properties in ferroelectric hexagonal Cr-doped YMnO3

We present the observation of the peculiar antiferroelectric (AFE)-like behavior, characterized by the polarization-electric field (P−E) double hysteresis loops and zero remnant polarization (P_r), in the ferroelectric (FE) Cr-doped YMnO₃ (YMCO) single crystals. The AFE-like behavior in YMCO is in sharp contrast with the FE P−E single loop with high P_r in the undoped YMnO₃ (YMO). The topological cloverleaf domains with ferroelectricity are observed in both YMO and YMCO. It is revealed unambiguously that the AFE-like behavior in YMCO arises from the Cr-substitution induced domain pattern transition from type-II with nonzero net macroscopic polarization to type-I with zero net polarization, as well as the recoverable type-I domain pattern after electric field sweeping. In addition, it is found that both the recoverable energy density and energy storage efficiency are significantly enhanced due to the AFE-like behavior in YMCO compared to YMO. Our results suggest for the first time that, in addition to the mechanism of the antiparallel arrangement of adjacent electric dipoles, the AFE-like behavior can be also achieved by domain engineering in a FE, which provides a possible new strategy to obtain high energy storage performance.     

Phase equilibria and dielectric properties of Bi3+(5/2)xMg2−xNb3–(3/2)xO14−x cubic pyrochlores

Subsolidus pyrochlores with the proposed formula, Bi_3+(5/2)xMg_2−xNb_3−(3/2)xO_14−x (0.14≤x≤0.22) were successfully synthesised at the firing temperature of 1025 °C using conventional solid-state reaction. The excess Bi³⁺ charge was offset by removal of relative proportion of Mg²⁺ and Nb⁵⁺ together with creation of oxygen non-stoichiometry in order to preserve electroneutrality of the system. These samples were crystallised in cubic structure with space group of Fd3m, No. 227 and their refined lattice parameters were in the range of 10.5706 (3)–10.5797 (7) Å. The surface morphologies of the samples as confirmed by scanning electron microscopy analysis were of irregular shaped grains while their crystallite sizes of ~30–85 nm were calculated using the Scherrer equation and the Williamson–Hall method. No thermal event was discernable indicating these pyrochlores were thermally stable within a studied temperature range of ~30–1000 °C. The recorded dielectric constants of Bi_3+(5/2)xMg_2−xNb_3−(3/2)xO_14−x (0.14≤x≤0.22) subsolidus pyrochlores were generally above ~160 and their dielectric losses were in the order of 10⁻⁴–10⁻³ at the frequency of 1 MHz and temperature of ~30 °C. Meanwhile, these ceramic samples also exhibited negative temperature coefficient of relative permittivity between −528 and −742 ppm/°C in the temperature range of ~30–300 °C.     

Low temperature sintering of barium titanate ceramics assisted by addition of lithium fluoride-containing sintering additives

By addition of LiF-containing sintering additives to commercial BaTiO₃ powder, more than 98% of the theoretical density was reached at a sintering temperature of 900 °C both on powder compacts and laminates. Dielectric measurements were performed on ceramic samples in the temperature and frequency ranges from −20 °C to 125 °C and from 10³ to 10⁶ Hz, respectively. High relative permittivity (_r  3160) and low dielectric loss (tan δ  0.014) were measured for tapes of the favoured material. The breakdown strength for tapes with a thickness of about 80 μm is 30 kV/mm. The microprobe analysis showed, that no interfacial reaction between the dielectric layer and the Ag-electrode had occurred.The newly developed barium titanate ceramics completely densifying at 900 °C turned out to be promising for integration of buried capacitors in LTCC multilayers.     

Preparation and electrical properties of SrTiO3 ceramics doped with M2O3–PbO–CuO

SrTiO₃ dielectric ceramics were fabricated in air by using M₂O₃–CuO–PbO as dopants (M=Sm,Nd,La,Yb). The obtained ceramics exhibited a high dielectric constant (₂₅>4880) with stable temperature characteristics. With doping the rare-earth ions from Sm → Nd → La → Yb, the corresponding dielectric constant regularly decreased. The investigation of microstructure showed that Yb additives benefited to the grain growth and CuO additives mainly segregated at the grain boundaries to form the insulation layers. According to the results, the conduction mechanism of SrTiO₃–M₂O₃–CuO–PbO system was discussed.     

Electrophoretically deposited manganese oxide coatings for supercapacitor application

In the present study, manganese oxide electrodes with promising pseudo-capacitive properties were prepared by electrophoretic deposition (EPD) using needle-like manganese dioxide powders. As-deposited coating exhibited a porous microstructure where the size and shape of the starting powders can be observed. The electrochemical performance of the as-deposited coating was then evaluated by cyclic voltammetry (CV) up to 300 times. The initial specific capacitance was 236 F/g which dropped to 200 F/g after 25 CV tests, and decreased gradually to 190 F/g thereafter. The electrochemical behaviors during EPD and CV were examined by synchrotron X-ray absorption spectroscopy techniques from which it was deciphered that a reduction reaction from Mn⁴⁺ to Mn³⁺ occurred during EPD concomitant with re-oxidization during repetitive CV cycles.     

Hydrogen-induced degradation in SrTiO3-based grain boundary barrier layer ceramic capacitors

Hydrogen-induced degradation in SrTiO₃-based grain boundary barrier layer ceramic capacitors was studied through electrochemical hydrogen charging, in which the capacitors were placed in 0.01 M NaOH solution with hydrogen deposited on their electrodes from the electrolysis of water. The properties of the capacitors were greatly degraded after 0.5 h of treatment: The capacitance was dramatically decreased and the dielectric loss was dramatically increased over the frequency range of 10²–10⁵ Hz, the leakage current was increased by orders of magnitude. It was proposed that atomic hydrogen diffused relatively easily along the grain boundaries and induced a reduction reaction to the grain boundary layer, which resulted in the degradation observed. Hydrogen-induced degradation is more serious in SrTiO₃-based grain boundary barrier layer ceramic capacitors than in other ceramic capacitors and great efforts should be made to prevent hydrogen-induced degradation in them.     

薄膜电容器的失效分析和试验方法

薄膜电容器失效的主要原因在于其保护层防潮性能不好和实际应用中存在交流电。文中先介绍薄膜电容器的生产工艺和电子镇流器的使用环境,再介绍潮湿对电容器的危害作用,以及电容器的失效分析。作者运用详细的原理解释,结合用不同的潮湿试验条件和施加直流电压或交流电压的方法来评估薄膜电容器的实际承受能力,通过优化选择和数据对比,得出结论"85℃,85%RH,施加交流电压"是最有效的试验方法。总之,增强防潮和抗交流电能力可以保证薄膜电容器以及电子镇流器处于高质量水平。