A stepwise method for determining the number of component distributions in a mixture

This paper considers the problem of estimatingm, the number of components in a finite mixture of distributions from a parametric family. A step-up procedure using the bootstrap method is proposed. Some properties of the procedure are illustrated with simulation studies. An example of the method, applied to orientation of beach clasts, is given.     

A micromechanical finite element model for linear and damage‐coupled viscoelastic behaviour of asphalt mixture

This study presents a finite element (FE) micromechanical modelling approach for the simulation of linear and damage‐coupled viscoelastic behaviour of asphalt mixture. Asphalt mixture is a composite material of graded aggregates bound with mastic (asphalt and fine aggregates). The microstructural model of asphalt mixture incorporates an equivalent lattice network structure whereby intergranular load transfer is simulated through an effective asphalt mastic zone. The finite element model integrates the ABAQUS user material subroutine with continuum elements for the effective asphalt mastic and rigid body elements for each aggregate. A unified approach is proposed using Schapery non‐linear viscoelastic model for the rate‐independent and rate‐dependent damage behaviour. A finite element incremental algorithm with a recursive relationship for three‐dimensional (3D) linear and damage‐coupled viscoelastic behaviour is developed. This algorithm is used in a 3D user‐defined material model for the asphalt mastic to predict global linear and damage‐coupled viscoelastic behaviour of asphalt mixture. For linear viscoelastic study, the creep stiffnesses of mastic and asphalt mixture at different temperatures are measured in laboratory. A regression‐fitting method is employed to calibrate generalized Maxwell models with Prony series and generate master stiffness curves for mastic and asphalt mixture. A computational model is developed with image analysis of sectioned surface of a test specimen. The viscoelastic prediction of mixture creep stiffness with the calibrated mastic material parameters is compared with mixture master stiffness curve over a reduced time period. In regard to damage‐coupled viscoelastic behaviour, cyclic loading responses of linear and rate‐independent damage‐coupled viscoelastic materials are compared. Effects of particular microstructure parameters on the rate‐independent damage‐coupled viscoelastic behaviour are also investigated with finite element simulations of asphalt numerical samples. Further study describes loading rate effects on the asphalt viscoelastic properties and rate‐dependent damage behaviour. Copyright © 2006 John Wiley & Sons, Ltd.     

贻贝粉酶解液提取复合氨基酸

报道了以脱脂后的贻贝粉为原料，采用酶解法从其酶解液中分离提取复合氨基酸的工艺。其收率为２０％，纯度约为９０％。其中必需氨基酸（不计色氨酸）约占复合氨基酸总量的５５％，其氨基酸模式与ＦＡＯ／ＷＨＯ组织确定的模式及人乳模式进行了对照，通过适量添加个别氨基酸可使其配比接近人乳模式。     

基于高光谱Hyperion数据的线性光谱混合模型与神经网络模型的比较

混合像元问题是定量遥感中的热点问题之一,为了改进从遥感数据中提取定量信息,人们建立了各种混合光谱分解技术,其中线性光谱混合模型和神经网络模型就是两种比较成熟的方法。以陕西省横山地区的高光谱Hyperion数据为研究基础,通过最小噪声变换(MNF)、像元纯度指数(PPI)转换和RMS误差分析的迭代方法相结合提取影像中的纯净像元作为终端端元。分别运用神经网络模型和线性光谱混合模型对影像进行光谱分解,得到各个组分的分解图像。以标准植被指数(NDVI)影像为衡量标准,选取训练样本点,分别对两种模型进行回归分析,结果显示NDVI影像与线性光谱混合模型植被分解图像的判定系数(R2=0.91)要大于其与神经网络模型的判定系数(R2=0.81)。进一步分析表明在一般情况下,线性光谱混合模型具有比神经网络模型略高的分离精度,但是神经网络模型对细部信息的提取的效果要好于线性光谱混合模型,最后提出了端元均方根误差(EAR)指数,一种新的混合像元分解的思路。     

A sub-pixel analysis of urbanization effect on land surface temperature and its interplay with impervious surface and vegetation coverage in Indianapolis,United States

This study developed an analytical procedure based upon a spectral unmixing model for characterizing and quantifying urban landscape changes in Indianapolis, Indiana, the United States, and for examining the environmental impact of such changes on land surface temperatures (LST). Three dates of Landsat TM/ETM+ images, acquired in 1991, 1995, and 2000, respectively, were utilized to document the historical morphological changes in impervious surface and vegetation coverage and to analyze the relationship between these changes and those occurred in LST. Three fraction endmembers, i.e., impervious surface, green vegetation, and shade, were derived with an unconstrained least-squares solution. A hybrid classification procedure, which combined maximum-likelihood and decision-tree algorithms, was developed to classify the fraction images into land use and land cover classes. Correlation analyses were conducted to investigate the changing relationships of LST with impervious surface and vegetation coverage. Results indicate that multi-temporal fraction images were effective for quantifying the dynamics of urban morphology and for deriving a reliable measurement of environmental variables such as vegetation abundance and impervious surface coverage. Urbanization created an evolved inverse relationship between impervious and vegetation coverage, and brought about new LST patterns because of LST's correlations with both impervious and vegetation coverage. Further researches should be directed to refine spectral mixture modeling by stratification, and by the use of multiple endmembers and hyperspectral imagery.     

东昆仑造山带花岗岩类Pb-Sr-Nd-O同位素特征

本文报道了东昆仑造山带三叠纪辉长岩、花岗岩类及其包裹体的Pb、Sr、Nd和O同位素组成。东昆仑造山带花岗质岩石全岩和长石Pb同位素组成相差不大，具明显的造山带Pb同位素特征；Sr同位素初始值(ISr)变化于0．70144～0．70972之间，暗示幔源成因；εNd值变化于-4．49939～-9．19258之间，具壳源成因特点；Nd同位素模式年龄(tDM)在1．38～1．761Ga之间，与中元古代变质岩相当；O同位素组成变化范围7．8～9．5，表明花岗岩类成岩物质主要来自地壳。综合岩石的同位素组成，结合矿物学、岩石地球化学的研究，表明花岗岩浆主要起源于地壳，但与来自地幔的基性岩浆曾发生过混合作用，从而导致同位素组成趋于一致。     

混合二维泊松过程的分解算法及其在提取地震丛集模式中的应用.

将一定范围内的地震数据假设为背景地震和丛集地震的叠加，并同时认为背景地震和丛集地震分别满足不同参数的二维泊松过程．通过引入N阶距离概念，将叠加的二维泊松过程转化为一维的混合密度函数，在对距离阶数进行选择的基础上，最终采用遗传算法进行混合密度分解，以达到提取地震丛集模式的效果．文中将该算法应用于我国西南地区松潘及龙陵主震前丛集地震的提取，并与C值的时间扫描结合，深化了这两次大地震前地震活动图象的认识．      

The algorithm of decomposing superim-posed 2-D Poisson processes and its applica-tion to the extracting earthquake clustering pattern

IntroductionClusteringearthquakesareusuallyconsideredasomensofstrongearthquakesorasignaloftectonicmovement.Thus,theyarenotonlyoneoftheprimaryevidencestopredictearthquakesbutalsoasignificantindicatortorecognizetectonicmovement(MEI,etal,1993;EarthquakePre-dictionandPreventionDepartmentofChinaSeismologicalBureau,1998).Ongeneralconditions,webelievethatclusteringearthquakesexistrelativelytobackgroundearthquakes,howtoeffectivelyseparateonefromtheotherbecomesthekeypointofextractingtheclusteringea…     

Sorption of carbon dioxide–methane mixtures

The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH₄ and CO₂ to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO₂ and CH₄, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH₄ and other gases in comparison with the isotherms of sorption of CO₂ and a CO₂/CH₄ mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO₂ molecules to the system: coal with a higher degree of metamorphism—CH₄, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs.     

The influence of coupled physical swelling and chemical reactions on deformable geomaterials

Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials.