Iron colloids/organic matter associated transport of major and trace elements in small boreal rivers and their estuaries (NW Russia)

The chemical status of major and trace elements (TE) in various boreal small rivers and watershed has been investigated along a 1500-km transect of NW Russia. Samples were filtered in the field through a progressively decreasing pore size (5, 0.8 and 0.22 μm; 100, 10, and 1 kD) using a frontal filtration technique. All major and trace elements and organic carbon (OC) were measured in filtrates and ultrafiltrates. Most rivers exhibit high concentration of dissolved iron (0.2–4 mg/l), OC (10–30 mg/l) and significant amounts of trace elements usually considered as immobile in weathering processes (Ti, Zr, Th, Al, Ga, Y, REE, V, Pb). In (ultra)filtrates, Fe and OC are poorly correlated: iron concentration gradually decreases upon filtration from 5 μm to 1 kD whereas the major part of OC is concentrated in the <1–10 kD fraction. This reveals the presence of two pools of colloids composed of organic-rich and Fe-rich particles. According to their behavior during filtration and association with these two types of colloids, three groups of elements can be distinguished: (i) species that are not affected by ultrafiltration and are present in the form of true dissolved inorganic species (Ca, Mg, Li, Na, K, Sr, Ba, Rb, Cs, Si, B, As, Sb, Mo) or weak organic complexes (Ca, Mg, Sr, Ba), (ii) elements present in the fraction smaller than 1–10 kD prone to form inorganic or organic complexes (Mn, Co, Ni, Zn, Cu, Cd, and, for some rivers, Pb, Cr, Y, HREE, U), and (iii) elements strongly associated with colloidal iron in all ultrafiltrates (P, Al, Ga, REE, Pb, V, Cr, W, Ti, Ge, Zr, Th, U). Based on size fractionation results and taking into account the nominal pore size for membranes, an estimation of the effective surface area of Fe colloids was performed. Although the total amount of available surface sites on iron colloids (i.e., 1–10 μM) is enough to accommodate the nanomolar concentrations of dissolved trace elements, very poor correlation between TE and surface sites concentrations was observed in filtrates and ultrafiltrates. This strongly suggests a preferential transport of TE as coprecipitates with iron oxy(hydr)oxides. These colloids can be formed on redox boundaries by precipitation of Fe(III) from inflowing Fe(II)/TE-rich anoxic ground waters when they meet well-oxygenated surface waters. Dissolved organic matter stabilizes these colloids and prevents their aggregation and coagulation. Estuarine behavior of several trace elements was studied for two small iron- and organic-rich rivers. While Si, Sr, Ba, Rb, and Cs show a clear conservative behavior during mixing of freshwaters with the White sea, Al, Pb and REE are scavenged with iron during coagulation of Fe hydroxide colloids.     

The global rainforest mapping project JERS-1:a paradigm of international collaboration for monitoring land cover change

The Global Rainforest Mapping (GRFM) project was initiated in 1995 and, through a dedicated data acquisition policy by the National Space Development Agency of Japan (NASDA), data acquisitions could be completed within a 1.5-year period, resulting in a spatially and temporally homogeneous coverage to contain the entire Amazon Basin from the Atlantic to the Pacific; Central America up to the Yucatan Peninsular in Mexico; equatorial Africa from Madagascar and Kenya in the east to Sierra Leone in the west; and Southeast Asia, including Papua New Guinea. To some extent, GRFM project is an international endeavor led by NASDA, with the goal of producing spatially and temporally contiguous Synthetic Aperture Radar (SAR) data sets over the tropical belt on the Earth by use of the JERS-1 L-band SAR, through the generation of semi-continental, 100m resolution, image mosaics. The GRFM project relies on extensive collaboration with the National Aeronautics and Space Administration (NASA), the Joint Research Center of the European Commission (JRC) and the Japanese Ministry of International Trade and Industry (MITI) for data acquisition, processing, validation and product generation. A science program is underway in parallel with product generation. This involves the agencies mentioned above, as well as a large number of international organizations, universities and individuals to perform field activities and data analysis at different levels.     

Boreal temperature variability inferred from maximum latewood density and tree-ring width data, Wrangell Mountain region, Alaska

Variations in both width and density of annual rings from a network of tree chronologies were used to develop high-resolution proxies to extend the climate record in the Wrangell Mountain region of Alaska. We developed a warm-season (July–September) temperature reconstruction that spans A.D. 1593–1992 based on the first eigenvector from principal component analysis of six maximum latewood density (MXD) chronologies. The climate/tree-growth model accounts for 51% of the temperature variance from 1958 to 1992 and shows cold in the late 1600s–early 1700s followed by a warmer period, cooling in the late 1700s–early 1800s, and warming in the 20th century. The 20th century is the warmest of the past four centuries. Several severely cold warm-seasons coincide with major volcanic eruptions. The first eigenvector from a ring-width (RW) network, based on nine chronologies from the Wrangell Mountain region (A.D. 1550–1970), is correlated positively with both reconstructed and recorded Northern Hemisphere temperatures. RW shows a temporal history similar to that of MXD by increased growth (warmer) and decreased growth (cooler) intervals and trends. After around 1970 the RW series show a decrease in growth, while station data show continued warming, which may be related to increasing moisture stress or other factors. Both the temperature history based on MXD and the growth trends from the RW series are consistent with well-dated glacier fluctuations in the Wrangell Mountains and some of the temperature variations also correspond to variations in solar activity.     

Determination of Roughness Lengths for Heat and Momentum Over Boreal Forests

The roughness length for momentum (z_0m), zero-plane displacementheight (d), and roughness length for heat (z_0h) are importantparameters used to estimate land-atmosphere energy exchange. Although many different approaches have been developed to parameterizemomentum and heat transfer, existing parameterizations generally utilizehighly simplified representations of vegetation structure. Further, a mismatch exists between the treatments used for momentum and heat exchange and those used for radiative energy exchanges. In this paper, parameterizations are developed to estimate z_0m, d, and z_0h for forested regimes using information related to tree crown density and structure. The parameterizations provide realistic representationfor the vertical distribution of foliage within canopies, and include explicit treatment for the effects of the canopy roughness sublayer and leaf drag on momentum exchange. The proposed parameterizationsare able to realistically account for site-to-site differences in roughness lengths that arise from canopy structural properties.Comparisons between model predictions and field measurements show good agreement, suggesting that the proposed parameterizations capture the most important factors influencing turbulent exchange of momentumand heat over forests.     

北半球海冰强迫作用下大气可预报性研究

使用LASG/IAP GOALS耦合模式中的全球大气环流模式分量AGCMR15L9的计算结果，在其他外强迫维持气候值不变的情况下，用方差分析的方法，以外部方差与总方差之比R_e作为衡量标准，考察该模式关于海冰的季节和跨季节潜在可预报性的大小。结果发现，从总体上看，北半球海冰变化所造成的潜在可预报性较小，只有在大气低层的一些气候要素，如温度、湿度的结果中，才存在R_e＞0.5的现象。潜在可预报性结果的局地特征比较明显，高值往往发生在海冰年际变率大的区域里。与中低纬海温在中高纬地区的影响相比，不排除海冰的作用更大的可能性。另外，如果分区域看，北半球某些区域的海冰，在若干挑选出的其区域海冰面积发生大异常年份中的潜在可预报性可能会比不做挑选的总体结果要大。这说明北半球某些区域海冰在面积发生较大异常的时候，可能对同期或（及）后期环流有着比较重要的影响。     

Landscape controls on long‐term runoff in subhumid heterogeneous Boreal Plains catchments

We compared median runoff (R) and precipitation (P) relationships over 25 years from 20 mesoscale (50 to 5,000 km²) catchments on the Boreal Plains, Alberta, Canada, to understand controls on water sink and source dynamics in water‐limited, low‐relief northern environments. Long‐term catchment R and runoff efficiency (RP^?1) were low and varied spatially by over an order of magnitude (3 to 119 mm/year, 1 to 27%). Intercatchment differences were not associated with small variations in climate. The partitioning of P into evapotranspiration (ET) and R instead reflected the interplay between underlying glacial deposit texture, overlying soil‐vegetation land cover, and regional slope. Correlation and principal component analyses results show that peatland‐swamp wetlands were the major source areas of water. The lowest estimates of median annual catchment ET (321 to 395 mm) and greatest R (60 to 119 mm, 13 to 27% of P) were observed in low‐relief, peatland‐swamp dominated catchments, within both fine‐textured clay‐plain and coarse‐textured glacial deposits. In contrast, open‐water wetlands and deciduous‐mixedwood forest land covers acted as water sinks, and less catchment R was observed with increases in proportional coverage of these land covers. In catchments dominated by hummocky moraines, long‐term runoff was restricted to 10 mm/year, or 2% of P. This reflects the poor surface‐drainage networks and slightly greater regional slope of the fine‐textured glacial deposit, coupled with the large soil‐water and depression storage and higher actual ET of associated shallow open‐water marsh wetland and deciduous‐forest land covers. This intercatchment study enhances current conceptual frameworks for predicting water yield in the Boreal Plains based on the sink and source functions of glacial landforms and soil‐vegetation land covers. It offers the capability within this hydro‐geoclimatic region to design reclaimed catchments with desired hydrological functionality and associated tolerances to climate or land‐use changes and inform land management decisions based on effective catchment‐scale conceptual understanding.     

新疆哈密地区早泥盆世珊瑚动物群及其地质意义

新疆哈密地区下泥盆统发育,南部图拉尔根地区下泥盆统为大南湖组,北部三道白杨沟地区为卓木巴斯套组。在大南湖组中共发现四射珊瑚2属5种,床板珊瑚7属12种,并建立四射珊瑚组合Syringaxon moriense和床板珊瑚组合Pseudofavosites giganteus;在卓木巴斯套组共发现四射珊瑚5属7种,床板珊瑚2属2种,并建立四射珊瑚组合Orthopaterophyllum junggarense和床板珊瑚组合Pachyfavosites junggarensis。通过珊瑚在地层中的分布及组合的时代对比,确定前者的时代为早泥盆世埃姆斯期早期,后者的时代为埃姆斯期中晚期。通过与国内外典型的早泥盆世埃姆斯期珊瑚动物群的对比,认为哈密地区的珊瑚动物具有典型的早泥盆世温带动物群特征,在生物古地理区系上属于北方大区准噶尔-兴安省。     

吉林延边开山屯地区地层时代的新证据

吉林延边开山屯地区古生代地层,在构造地层学研究的基础上,取得一些地层时代的新资料在混杂岩中新发现中二叠世北方型动物群化石;对混杂岩中的花岗岩砾石,测得SHRIMP锆石U-Pb年龄(286.8±5.6Ma),代表岛弧岩浆岩结晶时间;在变蛇绿岩和糜棱岩中采取白云母样品,测得40Ar-39Ar年龄,分别为408Ma和205.7Ma。由此,可以得出开山屯地区地层时代和混杂岩形成与演化的时间表泥盆纪洋壳形成;在中石炭世—中二叠世由南向北的运移过程中,洋壳之上发生硅质和碳酸盐沉积,形成海山;洋壳与由北向南移动的兴凯地块相对运动,二叠纪时向大陆俯冲,在兴凯地块西缘(现代方位)发育岛弧活动,并在中、晚二叠世形成滑塌堆积。可能与晚三叠世的洋壳俯冲作用有关,在兴凯地块前陆边缘发生逆冲作用,形成构造岩片。     

Stratigraphy of Middle-Upper Jurassic deposits in the East Russian plate

The work is aimed at litho-, bio- and magnetostratigraphic subdivision of the Middle-Upper Jurassic sedimentary succession in the northeast of the Ul’yanovsk-Saratov depression (the East Russian plate). Problems of regional and interregional correlation of distinguished subdivisions are considered. As is shown, the ammonite biostratigraphy is most effective method for solving problems of chronostratigraphy.     

Energy Balance Of A Sparse Coniferous High-Latitude Forest Under Winter Conditions

Measurements carried out in Northern Finland on radiation and turbulent fluxes over a sparse, sub-arctic boreal forest with snow covered ground were analysed. The measurements represent late winter conditions characterised by low solar elevation angles. During the experiment (12–24 March 1997) day and night were about equally long. At low solar elevation angles the forest shades most of the snow surface. Therefore an important part of the radiation never reaches the snow surface but is absorbed by the forest. The sensible heat flux above the forest was fairly large, reaching more than 100 W m^-2. The measurements of sensible heat flux within and above the forest revealed that the sensible heat flux from the snow surface is negligible and the sensible heat flux above the forest stems from warming of the trees. A simple model for the surface energy balance of a sparse forest is presented. The model treats the diffuse and direct shortwave (solar) radiation separately. It introduces a factor that accounts for the shading of the ground at low solar elevation angles, and a parameter that deals with the partial transparency of the forest.Input to the model are the direct and diffuse incoming shortwave radiation.Measurements of the global radiation (direct plus diffuse incoming shortwaveradiation) above the forest revealed a considerable attenuation of the globalradiation at low solar elevation. A relation for the atmospheric turbidity asfunction of the solar elevation angle is suggested. The global radiation wassimulated for a three month period. For conditions with a cloud cover of lessthan 7 oktas good agreement between model predictions and measurementswere found. For cloud cover 7 and 8 oktas a considerable spread can beobserved. To apply the proposed energy balance model, the global radiationmust be separated into its diffuse and direct components. We propose a simpleempirical relationship between diffuse shortwave and global radiation asfunction of cloud cover.