微量物质对海洋的大气输入

在过去的十年中，显而易见，大气是许多自然物质和污染物从大陆输送到海洋的重要途径。这些物质的大气输入对海洋生物过程和海洋化学循环有正或负的影响。例如：很明显，大气是许多区域的重要营养成分如铁，氮等的重要输送途径。在本报告中，我们评价了这些地区的期的数据，发展向海洋的微量元素，矿物气溶胶，含氮物质合成有机物的大气通量的全球范围的估算值；比较了这些物质通过大气和河流输入的海洋比率。     

综合气体地球化学测量

本文在综合大量资料的基础上,总结了气体地球化学的发展历史,对有关综合气体测量在发展过程中出现的一些术语,阐述了一点浅见,介绍了综合气体测量的采样方法、理论依据,提出了综合气体测量的发展方向。     

Characteristics of carbonaceous particles in Beijing during winter and summer 2003

Campaigns were conducted to measure Organic Carbon (OC) and Elemental Carbon (EC) in PM2.5 during winter and summer 2003 in Beijing. Modest differences of PM2.5 and PM10 mean concentrations were observed between the winter and summer campaigns. The mean PM2.5/PM10 ratio in both seasons was around 60%, indicating PM2.5 contributed significantly to PM10. The mean concentrations of OC and EC in PM2.5 were 11.2±7.5 and 6.0±5.0μg m-3 for the winter campaign, and 9.4±2.1 and 4.3±3.0 μg m-3 for the summer campaign, respectively. Diurnal concentrations of OC and EC in PM2.5 were found high at night and low during the daytime in winter, and characterized by an obvious minimum in the summer afternoon. The mean OC/EC ratio was 1.87±0.09 for winter and Z39±0.49 for summer. The higher OC/EC ratio in summer indicates some formation of Secondary Organic Carbon (SOC). The estimated SOC was 2.8 μg m-3 for winter and 4.2μg m-3 for summer.     

气温日较差研究进展:变化趋势及其影响因素

从日较差的变化趋势、影响因素以及人类活动对气候变化影响的指示3个方面对日较差的研究进行了总结和概括。观测数据以及气候模式模拟的结果表明,全球气温日较差在近半个多世纪以来呈下降趋势,而这种下降趋势不仅仅是自然变化的结果,还受到人类活动的影响。辐射、云量、气溶胶、下垫面的变化、水汽、降水以及航迹云等因素都能对日较差的变化造成影响。日较差的"周末效应"以及城市化过程中日较差的变化相对于平均气温的变化,能够更有效地指示人类活动对气候变化的影响。     

A Closure Study of Aerosol Hygroscopic Growth Factor during the 2006 Pearl River Delta Campaign

Measurements of aerosol physical, chemical and optical parameters were carried out in Guangzhou, China from 1 July to 31 July 2006 during the Pearl River Delta Campaign. The dry aerosol scattering coefficient was measured using an integrating nephelometer and the aerosol scattering coefficient for wet conditions was determined by subtracting the sum of the aerosol absorption coefficient, gas scattering coefficient and gas absorption coefficient from the atmospheric extinction coefficient. Following this, the aerosol hygroscopic growth factor, f(RH), was calculated as the ratio of wet and dry aerosol scattering coefficients. Measurements of size-resolved chemical composition, relative humidity (RH), and published functional relationships between particle chemical composition and water uptake were likewise used to find the aerosol scattering coefficients in wet and dry conditions using Mie theory for internally- or externally-mixed particle species [(NH₄)₂SO₄, NH₄NO₃, NaCl, POM, EC and residue]. Closure was obtained by comparing the measured f(RH) values from the nephelometer and other in situ optical instruments with those computed from chemical composition and thermodynamics. Results show that the model can represent the observed f(RH) and is appropriate for use as a component in other higher-order models.     

气溶胶对我国中东部地区秋季降水的影响

通过分析近50年来中国中东部地区降水资料发现,秋季降水与其他季节相比有明显减少趋势(每10年下降约54.3 mm),尤其自1980年代以来呈直线下降趋势(每10年降水减少5.6%)。从降水形成三个基本条件(水汽输送条件、稳定度条件、云微物理条件)出发,探究秋季降水减小的原因。结果表明,大气稳定度(对流抑制能(convective inhibition,CIN)以28.67(J/kg)/(10年)的速率增加,对流有效位能(convective available potential energy,CAPE)以12.81(J/kg)/(10年)的速率减小以及云微物理性质的变化(云滴有效粒子尺度减小)是导致秋季降水减少的直接原因,而这两个因素的变化与近20多年来气溶胶的大量增多有着非常密切的关系。因此,由空气污染造成的气溶胶浓度的增加可以作为导致中国中东部地区秋季降水减少的其中一个重要原因。由于秋季天气系统较稳定,主要受到大尺度系统影响,动力作用影响大于热力作用,所以减少了复杂中小天气系统和热力作用对降水的影响,故而更加突显出气溶胶对秋季降水的影响。     

恒河流域和蒙古国南部AERONET站沙尘气溶胶光学物理特性对比分析

沙尘气溶胶作为气溶胶的重要类型之一,对全球和区域水分循环以及亚洲季风系统有着重要影响.利用气溶胶自动观测网(AERONET)印度Kanpur和蒙古国Dalanzadgad两个站点数据,采用阈值法提取了沙尘和人为气溶胶信息并进行了对比分析.结果表明,Kanpur站受印度夏季风影响较大,沙尘气溶胶和人为源气溶胶的排放具有叠加效应,远源输送可能是Kanpur站沙尘气溶胶的主要来源.Dalanzadgad站受东亚夏季风影响较小,春季大风带来了大量的沙尘,这可能与大风天气和植被覆盖度低等因素有关,是春季气溶胶光学厚度显著升高的主要影响因素之一,沙尘具有局地起源特征;在其他时段,人为源气溶胶是当地大气气溶胶的主要来源,但总排放量相对较低.此外,Kanpur站所在的恒河流域大气颗粒物绝对含量远远高于Dalanzadgad所在的蒙古国南部地区.在沙尘天气中,两站颗粒物的光学物理特性相似.