Authenticity green coffee bean species and geographical origin using near-infrared spectroscopy combined with chemometrics

To prevent the adulteration of agricultural resources and provide a solution to enhance the green coffee bean supply chain, authentication using the near-infrared spectroscopy (NIRS) technique was investigated. Partial least square with discrimination analysis (PLS-DA) models combined with various preprocessing methods were built from NIR spectra of 153 Vietnamese green coffee samples. The model combined with the standard normal variate and the first order of derivative yielded excellent performance in predicting coffee species with the error cross-validation of 0.0261. PLS-DA model of mean centre and first-order derivative spectra also yielded good performance in verifying geographical indication of green coffee with the error of 0.0656. By contrast, the predicting abilities of post-harvest methods were poor. The overall results showed a high potential of the NIRS in online authentication practices.     

Smartphone-based bulky waste classification using convolutional neural networks

Multimedia Tools and Applications - The rapid urbanization process is escalating the urban waste problem, and ineffective management has worsened the issue, leading to severe consequences to the...     

Impact of defects on the decomposition of chemical warfare agent simulants in Zr-based metal organic frameworks

Metal organic frameworks (MOFs) containing zirconium secondary building units (SBUs) in UiO-67 and related MOFs, are highly active for neutralizing both the chemical warfare agents and simulants, such as dimethyl methylphosphonate (DMMP). However, two recent publications gave conflicting reports of DMMP reaction with UiO-67 under ultra high vacuum (UHV) conditions, with one reporting chemisorption and reaction (Wang et al., J Phys Chem C, 2017, 121, 11261–11272) and the other reporting only physisorption and reversible desorption (Ruffley et al., J Phys Chem C, 2019, 123, 19748–19758) from very similar temperature programmed desorption experiments. We show that the discrepancy between these experiments may be explained by different levels of missing linker defects in the UiO-67 samples. We present density functional theory calculations showing that SBU sites having two-adjacent missing linkers exhibit reaction barriers that are about 30 kJ/mol lower than SBU sites having a single missing linker. We also show that topology of the undercoordinated sites plays an important role in the reaction barrier under UHV conditions.     

Mechanical properties of continuous bamboo fiber-reinforced biobased polyamide 11 composites

This study is devoted to the analysis of the properties of continuous bamboo fiber (BF)-reinforced polyamide 11 (PA 11) composites. The SEM observations highlighted continuity between BFs and the polymeric matrix showing a high density of hydrogen bonds. The comparative calorimetric study of the matrix and its composites showed that the crystallinity of PA 11 was not modified by the presence of bamboo fibers. The physical aging observed in PA 11 is no more observed in composites due to physical interactions between PA 11 and BFs. The mechanical properties were investigated by tensile strength and dynamic mechanical analysis. The introduction of BFs enhanced Young's modulus of the matrix by a factor of 10. The presence of BFs also improved the storage shear modulus G′ over the whole temperature range. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47623.     

Mac-A-Mal: macOS malware analysis framework resistant to anti evasion techniques

Journal of Computer Virology and Hacking Techniques - With macOS increasing popularity, the number, and variety of macOS malware are rising as well. Yet, very few tools exist for dynamic analysis...     

A geometrically nonlinear size-dependent hypothesis for porous functionally graded micro-plate

The static bending behavior of porous functionally graded (PFG) micro-plate under the geometrically nonlinear analysis is studied in this article. A small-scale nonlinear solution is established using the Von-Kármán hypothesis and the modified couple stress theory (MCST). To obtain the deflection of the plate, the Reddy higher-order plate theory coupled with isogeometric analysis (IGA) is utilized. The distribution of porosities is assumed to be even and uneven across the plate’s thickness and the effective material properties of porous functionally graded micro-plate are calculated using the refined rule-of-mixture hypothesis. The influence of power index, porosity parameter and material length scale parameter on the nonlinear behaviors of static bending of porous FGM micro-plates are also investigated using several numerical examples.

     

Throughput-based fair bandwidth allocation in OBS networks

Fair bandwidth allocation (FBA) has been studied in optical burst switching (OBS) networks, with the main idea being to map the max-min fairness in traditional IP networks to the fair-loss probability in OBS networks. This approach has proven to be fair in terms of the bandwidth allocation for differential connections, but the use of the ErlangB formula to calculate the theoretical loss probability has made this approach applicable only to Poisson flows. Furthermore, it is necessary to have a reasonable fairness measure to evaluate FBA models. This article proposes an approach involving throughput-based-FBA, called TFBA, and recommends a new fairness measure that is based on the ratio of the actual throughput to the allocated bandwidth. An analytical model for the performance of the output link with TFBA is also proposed.     

Assessment of critical buckling load of functionally graded plates using artificial neural network modeling

Neural Computing and Applications - Predicting the critical buckling loads of functionally graded material (FGM) plates using an analytical method requires solving complex equations with various...     

Pd coated one-dimensional Ag nanostructures: Controllable architecture and their electrocatalytic performance for ethanol oxidation in alkaline media

One-dimensional (1D) metal-coated Pd structures are efficient catalysts for the ethanol electro-oxidation and promising strategy for minimizing the Pd-loading toward commercialization of direct ethanol fuel cells (DEFCs). Herein, the decorated and core-shell architectures of a novel Pd coating on Ag nanowires (PdAg-NWs) are controllable by a two-step polyol method based on the galvanic replacement reaction. The integration of uniform shell with a low Pd concentration and partial hollow structure onto 1D PdAg-NWs exhibits the highest efficiency for ethanol oxidation reaction (EOR) in alkaline solution. In comparison with Pd nanoparticles (PdNPs/C), the PdAgNWs/C performes 11 times superior EOR activity, and the onset potential shifts 80 mV negatively. The presence of Ag in PdAg-NWs enhances the absorption capacity of ethanol molecules and hydroxyl ions on the active sites, and improves the catalyst tolerance to CO-like intermediates, making them a potential anodic catalyst for DEFCs.