Synthesis and Characterization of Cationic Surfactants Based on N‐Hexamethylenetetramine as Active Microfouling Agents

Four cationic surfactants of quaternary hexammonium silane chloride based on hexamethylenetetramine and alkyl chloride were synthesized. The chemical structures of the prepared cationic surfactants were elucidated using Fourier transform infrared (FT‐IR) spectroscopy and mass spectrometry analysis. The surface and thermodynamic properties of the prepared surfactants were also studied. The performance of these cationic surfactants as microfouling agents against two strains of Gram‐negative bacteria, namely, Pseudomonas aeruginosa and Escherichia coli, and two strains of Gram‐positive bacteria, namely, Staphylococcus aureus and Bacillus subtilis, were evaluated as antimicrobial agents. The results showed that the maximum antimicrobial activity was detected for N‐hexamethylenetetramine‐N‐ethyl silane ammonium trichloride (Ah). The maximum and minimum antimicrobial activities were 73 and 60 % against S. aureus and E. coli, respectively, at a concentration of 5 mg/l, pH 7, and 37 °C.     

Level of natural hepatotoxin (Indospicine) contamination in Australian camel meat

Camel meat production for human consumption and pet food manufacture accounts for a relatively small part of overall red meat production in Australia. Reliable statistical data for the Australian production and consumption of camel meat are not available; however, it is estimated that 300,000 feral camels roam within the desert of central Australia, with an annual usage of more than 3000 camels for human consumption, 2000 for pet food manufacture and a smaller number for live export. Despite a small Australian camel meat production level, the usage of camel meat for pet food has been restricted in recent years due to reports of serious liver disease and death in dogs consuming camel meat. This camel meat was found to contain residues of indospicine, a non-proteinogenic amino acid found in certain Indigofera spp., and associated with mild to severe liver disease in diverse animals after dietary exposure to this hepatotoxin. The extent of indospicine-contaminated Australian camel meat was previously unknown, and this study ascertains the prevalence of such residue in Australian camel meat. In this study, indospicine levels in ex situ (95 samples collected from an abattoir in Queensland) and in situ (197 samples collected from camels after field culling in central Australia) camel meat samples were quantitated using a validated ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). The quantitation results showed 46.7% of the in situ- and 20.0% of the ex situ-collected camel meat samples were contaminated by indospicine (more than the limit of detection (LOD) of 0.05 mg kg^–1 fresh weight). The overall indospicine concentration was higher (p < 0.05) in the in situ-collected samples. Indospicine levels detected in the present study are considered to be low; however, a degree of caution must still be exercised, since the tolerable daily intake for indospicine is currently not available for risk estimation.     

Study of the behavior of mechanically stabilized earth (MSE) walls subjected to differential settlements

The limit equilibrium (LE) analysis has been used to design MSE walls. Presumably, the deflection of MSE walls can be limited to an acceptable range by ensuring sufficient factors of safety (FOSs) for both external and internal stabilities. However, unexpected ground movements, such as movements induced by excavations, volume changes of expansive soils, collapse of sinkholes, and consolidations of underlying soils, can induce excessive differential settlements that may influence both the stability and the serviceability of MSE walls. In this study, a numerical model, which was calibrated by triaxial tests and further by a specially-designed MSE wall tests, investigated the behavior of an MSE wall as well as the influence of various factors on the performance of the MSE wall when the wall facing settled relatively to the reinforced zone. The numerical results showed that the differential settlement would cause substantial vertical and horizontal movements for the MSE wall, as well as an increase in lateral earth pressure and geosynthetic reinforcement strain. The maximum horizontal movement and increase of the lateral earth pressure occurred at about 1.0 m above the toe. The differential settlement resulted in a critical plane that coincided with the plane of 45°+?/2. The maximum increase of the strain for each geogrid layer occurred in that plane, and the bottom layer had the greatest strain increase among all layers of reinforcement. The study further indicated that the surcharge, backfill friction angle, tensile stiffness of geogrid, reinforcement length and MSE wall height had noticeable influences on horizontal and vertical movements, and strain in geosynthetics. According to the results, the MSE wall that had a higher factor of safety would have less movements and geosynthetic strain increase. In contrast, only the friction angle, tensile stiffness and MSE wall height showed some degree of influence on the lateral earth pressure due to differential settlements.     

Permeability of high-performance concrete subjected to elevated temperature (600 °C)

Permeability is one of the most important parameters to quantify the durability of high-performance concrete. Permeability is closely related with the spalling phenomenon in concrete at elevated temperature. This parameter is commonly measured on non-thermally damaged specimens. This paper presents the results of an experimental investigation carried out to study the effect of elevated temperature on the permeability of high-performance concrete. For this purpose, three types of concrete mixtures were prepared: (i) control high-performance concrete; (ii) high-performance concrete incorporating polypropylene fibres; and (iii) high-performance concrete made with lightweight aggregates. A heating–cooling cycle was applied on 160 × 320 mm, 110 × 220 mm, and 150 × 300 mm cylindrical specimens. The maximum test temperature was kept as either 200 or 600 °C. After the thermal treatment, 65 mm thick slices were cut from each cylinder and dried prior to being subjected to permeability test. Results of thermal gradients in the concrete specimens during the heating–cooling cycles, compressive strength, and splitting tensile strength of concrete mixtures are also presented here. A relationship between the thermal damage indicators and permeability is presented.     

Prediction of compressive strength of self-compacting concrete containing bottom ash using artificial neural networks

The paper presents a comparative performance of the models developed to predict 28 days compressive strengths using neural network techniques for data taken from literature (ANN-I) and data developed experimentally for SCC containing bottom ash as partial replacement of fine aggregates (ANN-II). The data used in the models are arranged in the format of six and eight input parameters that cover the contents of cement, sand, coarse aggregate, fly ash as partial replacement of cement, bottom ash as partial replacement of sand, water and water/powder ratio, superplasticizer dosage and an output parameter that is 28-days compressive strength and compressive strengths at 7 days, 28 days, 90 days and 365 days, respectively for ANN-I and ANN-II. The importance of different input parameters is also given for predicting the strengths at various ages using neural network. The model developed from literature data could be easily extended to the experimental data, with bottom ash as partial replacement of sand with some modifications.     

Effect of metakaolin on the near surface characteristics of concrete

Results on an investigation dealing with the effect of metakaolin (MK) on the near surface characteristics of concrete are presented in this paper. A control concrete having cement content 450 kg/m³ and w/c of 0.45 was designed. Cement was replaced with three percentages (5, 10, and 15%) of metakaolin weight. Tests were conducted for initial surface absorption, sorptivity, water absorption and compressive strength at the ages of 35, 56, and 84 days. Test results indicated that with the increase in MK content from 5 to 15%, there was a decrease in the initial surface absorption, decrease in the sorptivity till 10% metakaolin replacement. But at 15% MK replacement an increase in sorptivity was observed. All mixtures showed low water absorption characteristic i.e. less than 10%. Compressive strength shared an inverse relation with sorptivity. Higher MK replacements of 15% are not helpful in improving inner core durability, even though it helps in improving surface durability characteristics.     

Response of Aspergillus flavus,Aspergillus niger and Penicillium citrinum to oxidative stress induced by Fenton’s reagent

The presence of fungi in water systems represents a threat to human health. Hydrogen peroxide is known for its disinfecting properties and easy decomposition to water and oxygen. Its activity can be enhanced by the addition of iron as a catalyst, a reagent known as Fenton?s reagent. In the present study, different Fenton concentrations were investigated on the spores of Aspergillus flavus, Aspergillus niger and Penicillium citrinum at different time intervals. The results indicate that complete inactivation of spores was noticed after 60 min of exposure to both 2 and 3% H₂O₂ catalyzed by 0.025 g Fe²⁺/100 ml for A. niger, and 3% H₂O₂ catalysed by 0.075 g Fe²⁺/100 ml for P. citrinum. The activity of two antioxidant enzymes, superoxide dismutase (SOD) and catalase (CAT), was determined in mycelial mat harvested after 7 days. Their activities were either highly increased or reached their minimum values prior to inactivation of spores.     

Desalination in the gaza strip: drinking water supply and environmental impact

More than 90% of the population of the Gaza Strip depends on desalinated water for drinking purposes. About 90% of the groundwater is unacceptable for drinking as a result of contamination by nitrate and chloride. One of the major options for resolving the water problems is the utilization of desalination technology for both sea and brackish water. The objective of this article is to address desalination water management in its embryonic stage in the Gaza Strip. The sources of drinking water supply, distribution system and the environmental impact of brine water will be fingered in detail. Desalination facilities range from large seawater plants to small brackish desalination units on a home scale. Governmental, non-governmental and private desalination plants are common. The distribution system of desalinated water is a responsibility of governmental, non-governmental, private small community bodies and even individuals. Disposal of brine water is made either directly or indirectly into the sea, sewage system, poor land, channels, wadies, etc. Brine constituents have an adverse impacton the surrounding environment, e.g., sea life, soil, wastewater treatment plants and the groundwateraquifer. The lack of real environmental impact assessments, especially for mid- and home-scale units may lead to a deterioration of the environment. The fragmentation of the responsibilities of water desalination, distribution of desalinated water and the disposal of brine water suggest that urgent action should be taken (e.g., legislation or establishment of a supervisory body). In other words, strict policies and management actions are to be taken in order to alleviate the health and environmental impact of an important and uncontrolled new system.     

Plasma surface modification and characterization of collagen‐based artificial cornea for enhanced epithelialization

Argon plasma treatment enhanced the attachment of epithelial cells to a collagen‐based artificial cornea crosslinked using glutaraldehyde (GA) and glutaraldehyde‐polyethylene oxide dialdehyde (GA‐PEODA) systems. The epithelialization of untreated and treated surfaces was evaluated by the seeding and growth of human corneal epithelial cells. Characterization of polymer surface properties such as surface hydrophilicity and roughness was also made by contact angle measurement and atomic force microscopy, respectively. Contact angle analysis revealed that the surface hydrophilicity significantly increased after the treatment. In addition, AFM characterization showed an increase in surface roughness through argon plasma treatment. Based on the biological and surface analysis, argon plasma treatment displays promising potential for biocompatibility enhancement of collagen‐based artificial corneas. It was also found that the cell attachment to artificial cornea surfaces was influenced by the combined effects of surface chemistry (i.e., surface energy), polymer surface morphology (i.e., surface roughness), and polar interactions between functional groups at the polymer surface and cell membrane proteins. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Modeling of Field Effect Transistor Channel as a Nonlinear Transmission Line for Terahertz Detection

This paper revisits the theory of operation of field effect transistor in the extremely high frequency scale, where the analysis has gone beyond the conventional cutoff frequency of the transistor. In this range, which is typically the terahertz (THz) and sub-terahertz range, the transistor blocks the high frequency signal and generates a rectified signal related to the input high frequency signal. An analytical model is derived for the channel of the FET in the linear mode of operation in non-resonant THz detection conditions. A transmission line distributed circuit model is applied. This is, from the authors’ point of view, the suitable model for high frequency non-quasi static operation and the characteristic parameters of this model are derived from the differential equation governing the electron gas in the channel. A comparison is presented for the calculated photoresponse with previously published experimental one showing good agreement away from the threshold potential. Finally, the effects of coupling between the present model and the external input circuit have been taken into account including the loading effects of the antenna and a discussion is given for the effect on frequency selectivity of the FET.