白浮泉形成及断流原因分析

本研究在分析已有资料的基础上,通过资料分析和水化学测试,查明白浮泉主要接受东北部兴寿地区同一含水层顺层流动补给和北部十三陵地区地表水沿大宫门古河道补给,在化庄地区水流受相对隔水层阻挡,沿山前基岩破碎带排泄形成的.随着区域大气降水的减少和十三陵水库采取的防渗措施,以及地下水开采量增加,白浮泉接受的补给量大幅减少,导致其断流.本研究通过资料搜集、水化学分析等手段查明了白浮泉形成和断流原因,为白浮泉复涌提供了基础资料支撑.     

PREPARATION OF ETHYLENE GLYCOL ACETATE THROUGH CATALYTIC OXIDATION OF ETHYLENE——ONE-STEP PROCESS WITH SIMULTANEOUS INTRODUCTION OF OXYGEN AND ETHYLENE INTO A Pd-Cu CATALYTIC SOLUTION

Ethylene glycol acetate can be prepared from ethylene by employing PdCl_2-CuCl_2-Cu(OAc)_2 in anacetic acid solution,usually involves two steps-acetoxylation and the regeneration of catalyst.In thispaper,a one-step process has been studied with oxygen and ethylene introduced simultaneously in a singlereactor.It was observed that there must be enough partial pressure of oxygen to oxidize Cu~+ to Cu~(2+)by keeping oxygen content at 8-10% in the raw binary gas mixture of oxygen and ethylene,whereby theactivity of the catalytic system could be maintained without formaton of CuCl residue.By using nitrogen as a diluent,the ratio of O_2/C_2H_2 could be kept in the non-explosive range.Itis claimed that 95% of the converted ethylene from the feed gas exists as ethylene glycol monoacetateand diacetate.     

Organoiron Polyelectrolytes: Synthesis and Characterization of Cationic Cyclopentadienyliron Complexes of Polyarylether-Imines

The synthesis of an aromatic ether complex of cyclopentadienyliron containing two terminal aldehyde groups was achieved via metal-mediated nucleophilic aromatic substitution reactions. This dialdehyde monomer was subsequently reacted with a variety of aliphatic and aromatic diamines to produce the corresponding soluble cationic organoiron polyether-imines. These cationic organometallic polymers were characterized using IR, ¹H, and ¹³C NMR, viscosity and thermogravimetric analysis. Viscosity measurements showed that these polymers exhibited polyelectrolyte effects in DMSO solutions. Thermogravimetric analysis showed that decoordination of the iron moieties occurred at about 300°C for polymers with aliphatic spacers in their backbones, while the cyclopentadienyliron moieties were cleaved from the polymers with aromatic spacers in their backbones at about 200°C. Photolytic demetallation of the organoiron polymers resulted in the removal of the pendent cyclopentadienyliron moieties and allowed for the isolation of their organic analogs. While the organoiron polymers were soluble in polar organic solvents, the corresponding organic polymers exhibited very limited solubilities or were insoluble. The organic polymers had glass transition temperatures between 101 and 120°C     

工业生产中软测量建模方法及其应用研究

软测量技术是基于推断控制理论的一门新兴工业技术.本文在介绍软测量技术的基本原理及其构成要素的基础上,详细介绍了工业生产中用于过程控制的常用的一些建模方法及其优缺点,同时也指出了其在工业生产控制中的实际应用.最后对其发展和应用状况进行了展望.     

稀土氧化物La2O3/Y2O3增韧补强ZTA陶瓷材料及其耐磨性能研究

针对单一相ZrO_2增韧Al_2O_3(ZTA)陶瓷在提高韧性的同时不能合理兼顾其耐磨性能,利用稀土氧化物能促进复合陶瓷材料热压烧结的工艺特点,将La_2O_3/Y_2O_3添加到ZTA陶瓷材料中,XRD衍射图谱表明:La_2O_3/Y_2O_3的添加可以有效阻碍ZrO_2不稳态晶型相变,促进介稳态t-ZrO_2的形成。当添加量为4%(质量分数)时,烧结后晶粒分布最为均匀,致密程度高,其维氏硬度、抗弯强度、断裂韧性分别比相应未添加稀土氧化物的ZTA材料提高了8%、21%、33%,且La_2O_3与Al_2O_3会发生原位反应生成片状LaAl_(11)O_(18),这种片晶不仅可以阻碍Al_2O_3、ZrO_2颗粒长大,还可通过晶粒拔出等增韧机制提高材料韧性。摩擦磨损试验结果表明:稀土氧化物的添加能提高ZTA陶瓷材料的耐磨性能,添加量为4%时其磨损率最低。     

基于遗传算法的RPRPR五杆机构实现轨迹综合与分析

基于五杆机构的基本理论和三角形稳定性原理,提出能够精确实现“任意给定轨迹”的RPRPR五杆机构;建立精确实现“任意给定轨迹”五杆机构的优化模型;分析补偿速度、加速度和转动速度、加速度的数值计算方法;采用遗传算法求解优化模型;实例表明该机构和计算方法的正确性。     

受钢工况钢包壁应力场的模拟与分析

ANSYS程序是进行热和结构分析的好工具,它在钢包上的应用非常广泛。以钢包二维截面为研究对象,分别讨论受钢工况下耐火材料物性参数和不同的工作层厚度对包壁应力场分布的影响,从而为钢包设计提供一些依据。     

Na2WO4-ZnO-WO3体系的粘度特性研究

Na2WO4-ZnO-WO3熔盐体系是熔盐镀钨所用的重要体系，研究了该体系摩尔组成在Na2WO4：40％～100％，ZnO：0％～37．5％。WO3:0％～60％范围内的粘度。结果表明：体系在温度约850℃时发生结构上的变化，导致体系粘度随WO3含量变化的规律或ZnO含量变化的规律在约850℃发生改变。     

晋城市加强农机培训服务能力的对策

通过调查晋城市农民对农机技术培训的需求,分析了农机培训存在的问题,结合当前农机培训工作的现状,提出加强农机培训的对策.     

Formation and O2/CO2 combustion characteristics of real-environment coal char in high-temperature oxy-fuel conditions

Oxygen-fuel combustion is a promising technology for CO₂ emission reduction. The high-temperature entrained flow reactor and high-temperature drop tube furnace were used to analyses the formation and O₂/CO₂ combustion characteristics of real-environment coal char in high-temperature oxy-fuel conditions. It proposed “inflection point standard” of high-temperature flame method for the preparation of real-environmental oxy-fuel coal char according to the flame method. The results show that the ratios of C=O/C-O and C=O/C_ar increase in the coal char compared with the raw coals. The trend of C=O/C_ar in oxy-fuel condition is opposite to that in the inert atmosphere, due to the effect of high-concentration CO₂. To achieve the burnout rate similar to air combustion for coal char, with the increase of coal rank, the O₂ concentration should be enhanced. The optimal O₂ concentration for the oxy-fuel combustion of JC anthracite is 30%, while that of other low-rank coals could be lower than 30%. The combustion characteristic of JC anthracite is with the highest sensitivity to temperature and O₂ concentration.