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The water sorption and diffusion in (reduced) graphene oxide‐alginate composites of various compositions is analyzed. Water sorption of sodium alginate can be significantly reduced by the inclusion of graphene oxide sheets due to the formation of an extensive hydrogen bonding network between oxygenated groups. Crosslinking alginate with divalent metal ions and the presence of reduced graphene oxide can further improve the swelling resistance due to the strong interactions between metal ions, alginate, and filler sheets. Depending on conditions and composition, the overall water barrier properties of alginate composites improve upon (reduced) graphene oxide filling, making them attractive for moisture barrier coating applications. Water sorption kinetics in all alginate composites indicate a non‐Fickian diffusion process that can be accurately described by the Variable Surface Concentration model. In addition, the water barrier properties of sodium alginate‐graphene oxide composites can be adequately predicted using a simple model that takes the orientational order of filler sheets and their effective aspect ratio into account.

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3.
Logistics is a fundamental component of the post‐harvest processes, especially in the floricultural sector where the products have to be marketed in short times after the cutting because of their fragility. In the previous years, new approaches to efficiently manage the logistical function and to reduce costs and environmental impacts have been consolidated. In this paper, the investments for two different containers for flower transportation, one disposable and one reusable, are compared, considering a specific supply chain located in central Italy. All data were provided by stakeholders. These were divided into four groups: purchasing, administration, logistical and disposal costs. For the reusable containers, a reverse logistical system, to collect the return components, was hypothesised by using the network analysis tool of the geographic information system (GIS). Results show that the use of a reusable system, which assures a production with less waste and less environmental pressures, is also economically advantageous. Reusable containers involve an initial investment but became cheaper from the second year of the investment and also remained convenient, considering all the costs related to the return collection of the items. Reusable system permits a financial advantage of approximately 140 k€ in total and 21 k€ for each year, considering all the nine years of analysis. Logistics is responsible of the great contribution of total cost in both the reusable and the disposable container (88% and 76%), probably because of the high fragmentation in the delivery service to sale points. Reverse logistics represents the 17% of the reusable container total costs. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
4.
Linear variable optical filter-based ultraviolet microspectrometer   总被引:1,自引:0,他引:1  
An IC-compatible linear variable optical filter (LVOF) for application in the UV spectral range between 310 and 400 nm has been fabricated using resist reflow and an optimized dry-etching. The LVOF is mounted on the top of a commercially available CMOS camera to result in a UV microspectrometer. A special calibration technique has been employed that is based on an initial spectral measurement on a xenon lamp. The image recorded on the camera during calibration is used in a signal processing algorithm to reconstruct the spectrum of the mercury lamp and the calibration data is subsequently used in UV spectral measurements. Experiments on a fabricated LVOF-based microspectrometer with this calibration approach implemented reveal a spectral resolution of 0.5 nm.  相似文献   
5.
X-ray screening of containers and unit load devices in the area of cargo shipping is becoming an essential and common feature at ports and airports all over the world. The detection of prohibited items in X-ray images is a challenging task for screening officers as they need to know which items are prohibited and what they look like in X-ray images. The main aim of this study was to investigate whether X-ray image interpretation competency of cargo security screeners can be increased by computer-based training. More specifically, effects of training were investigated by conducting tests before training started and after approximately three months of training. Moreover, it was examined whether viewing X-ray images in pseudo color would lead to a better detection performance compared to when X-ray images are shown in greyscale. Recurrent computer-based training resulted in large performance increases after three months. No significant difference in detection performance could be found for tests when using X-ray images in greyscale vs. pseudo color.  相似文献   
6.
This study evaluates the geothermal history of Palaeozoic sedimentary rocks from the easternmost part of the Variscan external zone in the NE Czech Republic. The objective was to investigate the geothermal history of pre‐Variscan Palaeozoic carbonates in the study area, and to assess its relationship with that of the overlying Variscan flysch. In the study area, the Palaeozoic succession occurs at the surface or is overlain by Miocene sediments of the Carpathian Foredeep. Palaeozoic nappes and the main Variscan overthrust have been documented in the subsurface at the deep Pot?tát‐1borehole. Vitrinite reflectance measurements on 38 samples from the Pot?tát‐1 well and 19 samples from nearby surface outcrops and shallow boreholes were available. A 2D thermal model was created using PetroMod and the thermal maturity evolution was modelled by EASY%Ro. The thermal model was constructed based on interpretations of two NW‐SE seismic profiles (lines 5/83 and 5/84) oriented perpendicular to the main Variscan thrusts. The results were calibrated using measured vitrinite reflectance and were adjusted with 1D models from three shallow boreholes. At the Pot?tát‐1 borehole, modelled maximum palaeo‐temperatures of the Variscan flysch (Moravice Formation) ranged from 310°C at a depth of 7.3 km (the top of the preserved succession) to 395°C at the base of the succession, resulting in thermal maturities of >4%Rr. Peak maturation occurred prior to the end of Variscan thrusting. Modelling suggests that the basal heat flow for these thrust units reached a maximum value of 63 mW/m2 at 325 Ma. In addition, the modelling suggests that the maturity of the Palaeozoic carbonates was controlled by the thickness of the overlying Variscan flysch nappes. Maximum palaeo‐temperatures for the Palaeozoic carbonates ranged from 265°C at the top of the interval (at a depth of 7.1 km) to 290°C at the base, resulting in a maturity of 3.8 to >4%Rr which is within the dry gas window. The study suggests that basal heat flows in the original (pre‐thrust) Early Carboniferous sedimentary basin were slightly higher than those in the post‐thrust location for the Variscan flysch nappes. This should be taken into account when evaluating the petroleum system in the South Moravian oil province (SW Czech Republic) where a complete sedimentary sequence has not been preserved.  相似文献   
7.
The low-temperature pack chromization, a reforming pack cementation process, is employed to modify AISI 1045 steel for the application of bipolar plates in PEMFC. The process is conducted to yield a coating, containing major Cr-carbides and minor Cr-nitrides, on the substrate in view of enhancing the steel's corrosion resistance and lowering interfacial contact resistance between the bipolar plate and gas diffusion layer. Electrical discharge machining and rolling approach are used as the pretreatment to produce an activated surface on the steel before pack chromization process to reduce operating temperatures and increase deposition rates. The rolled-chromized steel shows the lowest corrosion current density, 3 × 10−8 A cm−2, and the smallest interfacial contact resistance, 5.9 mΩ cm2, at 140 N cm−2 among all tested steels. This study clearly states the performance of 1045 carbon steel modified by activated and low-temperature pack chromization processes, which possess the potential to be bipolar plates in the application of PEMFC.  相似文献   
8.
Various applications of slurry transportation through pipelines exist. A transportation problem is formulated to determine the pipe diameters and amounts of transported slurry from the production to the consumption points. The minimisation of the cost consisting of the pipe and energy cost terms is considered as the objective function. Pipe cost is given as the function of pipe diameters and the energy cost is defined as the function of pipe diameters and slurry amounts. Energy cost is obtained by using the relation that is previously determined after the experimental studies have been made for the magnetite ore. Genetic algorithm is used as the optimisation method and to apply this method a commercially available software written in the C language is used and modified. The proposed methodology to solve this non-linear programming problem is applied to a transportation system and it is found that the proposed methodology has made the complex, labour-intensive solution process very convenient for the users.  相似文献   
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10.
Zinc oxide (ZnO) was synthesized using a microwave assisted hydrothermal (MAH) process based on chloride/urea/water solution and under 800 W irradiation for 5 min. In the bath, Zn2+ ions reacted with the complex carbonate and hydroxide ions to form zinc carbonate hydroxide hydrate (Zn4CO3(OH)6·H2O), and the conversion from Zn4CO3(OH)6·H2O to ZnO was synchronously achieved by a MAH process. The as-prepared ZnO has a sponge-like morphology. However, the initial sponge-like morphology of ZnO could change to a net-like structure after thermal treatment, and compact nano-scale ZnO particles were finally obtained when the period of thermal treatment increased to 30 min. Pure ZnO nanoparticles was obtained from calcination of loose sponge-like ZnO particles at 500 °C. The analysis of optical properties of these ZnO nanoparticles showed that the intensity of 393 nm emission increased with the calcination temperature because the defects were reduced and the crystallinity was improved.  相似文献   
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