Multifield modelling and failure prediction of cellular cores produced by selective laser melting

A multifield simulation approach of cellular cores produced by additive manufacturing is presented. The analysis is aiming to derive the relation between the manufacturing process parameters and the resulting material failure behaviour. To this purpose, the selective laser melting manufacturing process is initially thermo‐mechanically simulated, followed by the mechanical analysis of the nonlinear core behaviour. The methodology is demonstrated in the case of open‐lattice body‐centred‐cubic (BCC) cellular cores.     

Estimating the development cost of custom software

In this paper an approach for the estimation of software development costs is presented. The method is based on the characterization of the software to be developed in terms of project and environment attributes and comparison with some similar completed project(s) recovered from a historical database. A case study is also presented, focusing on the calibration and application of the method on 59 information systems implementing supply chain functions in industry. Various strategies are explored, the best of which predicted effort quite effectively, with a mean estimation error of 24% with respect to the actual effort.     

Assessment of a modification to the Brinell method for determining solid wood hardness

Purpose of this study was to assess a modification to the hardness determination method in order to mitigate the effect of visual measurements on the consistency of Brinell method and accuracy of the results. The amendment has been previously proposed by other researchers and refers to the automated determination of indentation diameter and relies on the ability of modern testing machines to accurately measure indentation depth, through which the calculation of indentation diameter is possible. From the results of this study it was shown that the hardness values acquired by the proposed modification presented statistically significant difference compared to those acquired using the visual method described in EN1534 (Wood and parquet flooring—determination of resistance to indentation (Brinell)—test method, 2000). Moreover, compared to the standard methodology, the application of the proposed amendment led to hardness values which are better correlated to density as well as Janka hardness for the six different solid wood species tested. Furthermore, the proposed modification resulted to hardness values which seem to be less affected by the presence of varnish coatings.     

A review of tungsten: from environmental obscurity to scrutiny

Since its discovery, tungsten, a transition element of Group VIb of the Periodic Table of Elements, and its compounds have been considered environmentally benign. Its presence in biological and drinking water samples in Fallon, Nevada, an acute lymphocytic leukemia cluster struck community has alarmed public health, environmental and regulatory agencies. Tungsten, a metal of extraordinary properties that make it hardly substitutable, is considered an essential commodity with a wide variety of uses stretching from household necessities to highly specialized applications. This work is undertaken in order to explore aspects of environmental behavior of tungsten and its compounds. Occurrence data in terrestrial, atmospheric, aquatic and biotic systems are presented. Various aspects of environmental chemistry, fate transport across environmental interfaces and toxicology are discussed with the objective of identifying knowledge gaps and outlining directions for future research.     

Network Synchronization of an Orthogonal CDMA Satellite Communication System

This paper provides the network synchronization of an orthogonal CDMA geostationary satellite system for fixed service communications. It includes the synchronization procedures, the system architecture and the performance evaluation. The main objective is to provide network wide synchronization of all uplink orthogonal CDMA transmissions. This is achieved in steps; first by providing coarse synchronization using the uplink random access channel and then fine sync using innovative tracking control mechanisms. The uplink access channel receiver utilize a parallel/serial search method for rapid code acquisition, while the code tracking of the uplink orthogonal CDMA traffic channel is based on a delay feedback early-late gate in which the sych control resides in the receiver. The proposed system is designed to minimize the onboard complexity and satisfy the performance requirements. As shown in the performance section, the requirement that all uplink transmissions are synchronized to a reference time within 10% of the chip length can be achieved. In addition, the system analysis determines the design parameters values which optimize performance.     

Phosphate application to firing range soils for Pb immobilization: the unclear role of phosphate

Phosphate treatment has emerged as a widely accepted approach to immobilize Pb in contaminated soils and waste media, relying on the formation of the highly insoluble mineral pyromorphite as solubility-controlling phase for Pb. As such, phosphate treatment has been proposed as a Best Management Practice (BMP) for firing ranges where Pb occurs in its metallic forms and several other phases (carbonates, oxides). While pyromorphite thermodynamically has the potential to control Pb solubility at low levels, its formation is kinetically controlled by pH, the solubility of the phosphate source, and the solubility of Pb species. Treatability studies have shown that excess quantities of soluble and acidic phosphate sources, such as phosphoric acid, are necessary for successful in situ treatment. Even under these conditions, Extended X-ray Absorption Fine Structure (EXAFS), the only reliable method to identify and quantify Pb speciation, showed that Pb conversion to pyromorphite in in situ treated soils was less than 45% after 32 months. Furthermore, the use of lime (CaO) to restore soil pH in acidified soil treatments inhibited further conversion. Additionally, phosphate treatment is known to reduce bioavailability through pyromorphite formation in the intestinal tract, and the phytoaccumulation of Pb; both desirable effects for Pb-impacted areas. Given the costs of phosphate treatment, the use of biogenic phosphate sources, such as bone meal, may be a more environmentally sustainable approach toward this end. In the many studies focusing on phosphate treatment, the attendant P leaching and eutrophication have been largely overlooked, along with other issues such as the enhanced leaching of oxyanionic contaminants, such as Se, As and W. The success and sustainability of applying phosphate as a BMP in firing range soils therefore remain questionable.     

Application of the Rietveld method to assess chromium(VI) speciation in chromite ore processing residue

The Rietveld method allows the quantification of crystalline phases and amorphous material identified by X-ray powder diffraction (XRPD) and other diffraction methods. The method assists in determining the speciation of contaminants in solid matrices both qualitatively and quantitatively in a statistically defensible approach, as it does not focus on a microscale. Rietveld was applied to chromite ore processing residue (COPR), a cementitious waste containing hexavalent chromium. Calcium aluminum chromium oxide hydrates (CACs) were the crystalline phases identified by XRPD that bind Cr(6+) in COPR according to their chemical formula. Rietveld quantification, combined with mass balances on Cr(6+), showed that CACs may bind Cr(6+) in variable percentages, ranging from 25% to 85%. Analysis of duplicate samples showed that material variability is the predominant factor of uncertainty in evaluating the role of CACs in Cr(6+) speciation, provided that a consistent quantification strategy is pursued. The choice of strategy was performed on the basis of the pertinent literature, preliminary analyses of the equipment and the software settings, and mass balances. The correlation between the average CAC-bound Cr(6+) concentration and the total Cr(6+) for five samples (R(2)=0.94), extracted from different zones and soil borings, suggests that CACs are a primary sink for Cr(6+) in COPR.     

Survival of Escherichia coli O157:H7 in Galotyri cheese stored at 4 and 12 degrees C

Post-process contamination of fresh acid-curd cheeses with Escherichia coli O157:H7 may pose a risk considering the low infectious dose and the ability of the pathogen to survive in acidic foods. To evaluate its survival in Galotyri, a traditional Greek acid-curd cheese, portions (0.5 kg) of two commercial fresh products, one artisan (pH 3.9+/-0.1) and the other industrial (pH 3.7+/-0.1), were inoculated with approximately 3.0 or 6.5 log cfu g(-1) of a five-strain cocktail of E. coli O157:H7, including rifampicin-resistant derivatives of the strains ATCC 43895 and ATCC 51657, and stored aerobically at 4 and 12 degrees C. Survival was monitored for 28 days by plating cheese samples on tryptic soy agar with 100 mg l(-1) rifampicin (TSA+Rif), SMAC and Fluorocult E. coli O157:H7 agar media. The pathogen declined much faster (P<0.05) in the industrial as compared to the artisan cheeses at both temperatures. Thus, while E. coli O157:H7 became undetectable by culture enrichment after 14 days at 4 degrees C in industrial samples, irrespective of the inoculation level, populations of 1.4-1.9 and 4.2-5.1 log cfu g(-1) survived after 28 days in the corresponding artisan cheeses with the low and high inocula, respectively. Survival was longer and greater (P<0.05) on TSA+Rif than on SMAC and Fluorocult, indicating the presence of acid-injured cells. Interestingly, survival of E. coli O157:H7 after 14-28 days in cheeses was better at 12 degrees C than at 4 degrees C, probably due to yeasts which grew on the surface of temperature-abused cheeses. The large difference in the pathogen's inactivation between the industrial and artisan cheeses at 4 degrees C could not be associated with major differences in pH or type/concentration of organic acids, suggesting another anti-E. coli O157:H7 activity by the industrial starter. The high survival of the pathogen in artisan Galotyri under conditions simulating commercial storage should be of concern.