Chromium evaporation and oxidation characteristics of alumina-forming austenitic stainless steels for balance of plant applications in solid oxide fuel cells

The chromium (Cr) evaporation behavior of several different types of iron (Fe)-based AFA alloys and benchmark Cr₂O₃-forming Fe-based 310 and Ni-based 625 alloys was investigated for 500 h exposures at 800 °C to 900 °C in air with 10% H₂O. The Cr evaporation rates from alumina-forming austenitic (AFA) alloys were ~5 to 35 times lower than that of the Cr₂O₃-forming alloys depending on alloy and temperature. The Cr evaporation behavior was correlated with extensive characterization of the chemistry and microstructure of the oxide scales, which also revealed a degree of quartz tube Si contamination during the test. Long-term oxidation kinetics were also assessed at 800 to 1000 °C for up to 10,000 h in air with 10% H₂O to provide further guidance for SOFC BOP component alloy selection.     

Characteristics of pigments,modification, and their functionalities

Novel treatments of pigments with inorganic materials have tremendous industrial and commercial prospects. Specific treatment of pigment has a marked effect on its behavior during application. The treatment allows a broad modification of the surface characteristics of pigment particles which leads to improved functionalities. Surface modification of pigments is achieved via coating, polymerization with modifying reagent, treatment with derivatives or polymers, which alter either the optical, conductivity or dispersibility during processing and application. These and many other distinguishing factors that affect the characteristics of pigments such as the class, crystal structure, particle morphology, particle size, hiding power, pigment volume concentration, surface character, and surface treatment have been reviewed. Various organic pigments such as those from fungus and bacteria, and the various families of pigment types such as metallic pigment, light interference, and diffractive pigments which presents decorative quality such as leafing, nonleafing, pearlscent, and Fabry‐Perot effects on substrates have also been reviewed in addition to those from inorganic sources with emphasis on the structure and physiochemical modifications using metal and nonmetal Ions.     

Using shear force,sarcomere length,particle size,collagen content,and protein solubility metrics to predict consumer acceptance of aged beef tenderness

In this study, the relationship between sensory evaluation and several objective metrics of beef tenderness was tested. Objective metrics included shear force, sarcomere length, collagen content, myofibrillar, and sarcoplasmic protein solubility and particle size analysis. These results were compared to consumer panel scores of tenderness for the same aged beef striploin (longissimus lumborum muscle) samples. There was found to be a significant relationship between sarcomere length, shear force, and particle size with tenderness scores. Collagen content and protein solubilities were not associated to tenderness scores (p > 0.05). Sarcomere length contributions for explaining tenderness variation were overlapped by the contributions of shear force (collinearity). Independent models demonstrated that the lower 95% confidence interval of the fitted regression line exceeded 50% acceptance of tenderness when shear force values <42.6 N and when particle size values <198 μm. We can recommend these as thresholds for consumer acceptance of beef tenderness, although considerations of sample type, analytical methodology, and consumer demographics should be made prior to their adoption. This provision was based on the variation in tenderness scores evident between individual panelists and experimental striploins.     

Attitudes towards regionalism in a rapid growth suburb

A key issue confronting our newer suburbs is the stance they should take towards efforts at regional cooperation and coordination of major policy areas. This article analyzes the preferences on this issue held by residents in a rapid growth suburb in the St. Louis metropolitan area. Through factor analysis, four identifiable dimensions of regionalist preferences were obtained from questionnaire responses--administrative cooperation, land-use cooperation, mass transit cooperation, and regional basic services cooperation. Correlational analyses between these dimensions of regionalist preferences and selected community status characteristics, social situation characteristics, and local political participation status of respondents reveal no systematic covariation. Thus municipal policies which influence the population mix within a community with respect to the life situation characteristics measured in this study are not likely to be useful instruments for influencing the preferences, pro or con, of the community towards regionalist policies. Further, local political participants are found to be representative of the larger community's regionalist policy preferences.     

Review

THE EXPERIENCE OF NATURE: A PSYCHOLOGICAL PERSPECTIVE by Rachel Kaplan & Stephen Kaplan, Cambridge University Press, 1989, 337pp, £10.95 (p/b), 0-521-34939-7.

THE ECOLOGY OF URBAN HABITATS by 0. L. Gilbert, Chapman & Hall, London, 1989, 369pp, 0-412-28270-4, £35.00.

DIRECTORY FOR THE ENVIRONMENT: ORGANISATIONS IN BRITAIN AND IRELAND 1986-7, Michael J. C. Barker, ed., London: Routledge & Kegan Paul, 1986. Second edition, pp. xviii + 278, £18.99, PB, ISBN 0-7102-0961-4.

THE URBAN ENVIRONMENT: A SOURCEBOOK FOR THE 1990s, Gerald Dawe, ed., Birmingham: Centre for Urban Ecology, 1990, pp. 636, £55.00, PB, ISBN 0-907272-07-X.

PLANTS IN THE LANDSCAPE (2nd Edn.), by Philip L. Carpenter and Theodore D. Walker, W. H. Freeman, New York and Oxford, 1990, 401 pp., ISBN 0-7167-1808-1, £29.95 HB.

SPORTS GEOGRAPHY by John Bale, E. & F. N. Spon, 1989, 0-419-14390-4, £16.95 PB.

THE POLITICS OF PARK DESIGN: A HISTORY OF URBAN PARKS IN AMERICA by Galen Cranz, ISBN 0 262 53084 8, 347pp, London: M.I.T. Press, 1989, £11.25, P.B.     

Membrane performance enhancer evaluations on pilot- and full-scale membrane bioreactors

Recently developed polymeric membrane performance enhancer product, MPE50, was tested in various pilot‐ and full‐scale membrane bioreactors (MBRs). The Initial MPE50 dosage was determined by visual jar tests and by using various bench‐top filtration tests. Different amounts of MPE50 were dosed, and the particle size and supernatant clarity of the mixed liquor were monitored visually. Bench‐top filtration tests were also conducted. A 50% higher MPE50 dosage is recommended to be added to the pilot/full‐scale bioreactors because, based on experience, some of the soluble microbial products in the mixed liquor do not completely react with polymer during the relatively short bench‐test mixing time interval. With the addition of 400 mg/L MPE50 to a pilot MBR, the design flow was increased twofold without any significant transmembrane pressure (TMP) increase for 1 day. The control TMP surged within a few hours without MPE50. Long‐term field trials in a full‐scale plant also showed a substantial flux increase. In addition to flux enhancement, MPE50 helped to remove foam from the bioreactors and improved plant aesthetics, safety and general operating performance.     

Anaerobic biological treatment of phenolic wastewater at 15-18 degrees C

Low-temperature, or psychrophilic (<20 degrees C) anaerobic digestion has been proven feasible for the mineralisation of simple wastewaters. In this study, hybrid expanded granular sludge bed-anaerobic filter (EGSB-AF) bioreactors were used to evaluate the feasibility of psychrophilic digestion for the treatment of phenol-containing wastewater. Efficient chemical oxygen demand and phenol removal were observed at organic and phenol loading rates of 5 kg COD m(-3)d(-1) and 0.4-1.2 kg phenol m(-3)d(-1) (400-1200 mg phenol [l wastewater](-1)), respectively. There was no long-term accumulation of volatile fatty acids in the reactor systems. Methanogenic activity was developed under psychrophilic conditions but anaerobic methane-producing populations remained mesophilic throughout the trial of 415 days.