Evaluation of small-scale combustion of an insensitive high explosive formulation containing 3-nitro-1,2,4-triazol-5-one (NTO), 2,4-dinitroanisole (DNAN), and 1,3,5-trinitroperhydro-1,3,5-triazine (RDX)

ABSTRACT

Energetic materials are often disposed by open-burning or open-detonation as it is a cost-effective and efficient means of destroying explosive material, and often minimizes the need to transport hazardous explosives to treatment facilities. This practice is often scrutinized for the negative environmental impact of the odorous and unsightly toxic gaseous emissions as well as the resulting deposition residues, which often contain unburned energetic materials. With the increasing use of Insensitive High Explosive compositions in munitions, it is essential that the potential environmental impact of their disposal is assessed before their extensive use to prevent the kind of contamination incidents experienced with legacy explosives. Therefore, the aim of this work was to develop a controlled laboratory experiment to identify the gaseous emissions and the energetic material residues that are generated through the combustion of the IHE components 3-nitro-1,2,4-triazol-5-one (NTO), 2,4-dinitroanisole (DNAN), and 1,3,5-trinitroperhydro-1,3,5-triazine (RDX). A sealed vial containing small (mg) quantities of energetic material was heated until the energetic material combusted. Gas chromatography/mass spectrometry (GCMS) was used to calculate the oxygen consumption and to identify the gases that were generated. The solid residues were analyzed by high-performance liquid chromatography (HPLC) to quantify unburned energetic material. Results showed that DNAN was the most resistant to burning, thus leaving significant quantities of unreacted starting material in the vial. An interesting observation for the IHE formulation was that DNAN also inhibited the combustion of NTO and RDX. The gases emitted during the open burning of IHE components and mixtures included CO, CO₂, and N₂O as expected, but the proportions differed when the components and mixture were compared, reflecting the influence of DNAN on the burning behavior. From our data, we concluded that open-burning DNAN-based formulations is an environmentally unfavorable waste-management practice for the disposal of IHEs mainly due to generation of solid residues as well as unburnt DNAN.     

Rethinking Enterprise Architecture for Sustainable Energy System Development

The development of a sustainable energy system throughout an enterprise is a complex task, which requires an agile holistic approach. Such an approach needs to include a variety of objectives including energy strategy formation and strategic decision-making, which are directly related to the analysis and management of the main areas of sustainable development:The economic, technological, environmental, and social. These multidimensional requirements of sustainability are often difficult to achieve within the enterprise, because these aspects are interrelated and influenced by various internal and external environment factors. This paper first reviews the main challenges for an energy system, and then demonstrates how a strategic agile enterprise architecture driven approach could effectively guide the sustainable energy system development. The study presented in this paper provides a holistic approach that contributes to the advancement and usage of literature dealing with issues of sustainable energy system development and agile enterprise architecture, which has not been discussed before to any great extent.     

Ecological Landscape Planning: A gaming approach in education

An understanding of the complex problems of land-use competition requires an appreciation of natural processes, cultural values, economic imperatives and political agendas. This integrated understanding is an important component of the study programme for higher education students seeking a professional qualification in landscape architecture. A repertoire of game templates is introduced as an initial step in formulating a conceptual framework for the curriculum/games designer to explore the potential of play in ecological landscape planning. The concepts of social action space, permissible action space and motivational action space are used to investigate the qualities of each template for further game design development. The abstraction of these concepts may assist the designer to move beyond the usability of games into viewing their value as a learning method.     

Whale Optimization Algorithm Approach for Performance Optimization of Novel Xmas Tree-Shaped FinFET

Silicon - Today, Fin shaped Field Effect Transistors (FinFETs) are the framework of the sub-nanometer technology node. The leading semiconductor industry deploys it in low-power (LP) and...     

Sage of Lacock

Abstract

‘The good is oft interred with their bones.’ Much of what has been written of William Henry Fox Talbot has done him meagre justice: criticism for patenting his inventions, accusations that he patented the ideas of others, denigration of the importance of his discoveries. Though acknowledged as a scientist, his place as an artistic worker in the medium he invented has not been appreciated.     

Control and care: landlords and the governance of vulnerable tenants in houses in multiple occupation

Houses in multiple occupation (HMOs) in which tenants share facilities are housing an increasing proportion of vulnerable adults who have limited affordable housing options. However, knowledge about how these types of property are managed is limited. In this paper, we examine the governance function of HMO landlords from the perspective of landlords/landlord agents and the tenants that live within their properties. The landlord exercises control through formal and informal risk assessment of tenants and close surveillance of them. These control mechanisms may also involve direct or indirect provision of support and care to some tenants. This illustrates the complex relationship between care and control and the extent to which both are integral to the housing management of vulnerable tenants living in HMOs. We suggest that this dual function calls for a critical examination of what constitutes a ‘good landlord’.