The effect of concentration of adsorbing solids on the partition coefficient

The results of a number of laboratory studies are presented to demonstrate an inverse relationship between concentration of adsorbing solids and partition coefficient. Various functional forms which define the relation are developed and correlated with the data. A power-law dependence of partition coefficient on concentration of solids is shown. The significance of this relationship in assessing the fate of hydrophobic pollutants in natural water systems is discussed.     

Development of an automated process planning and production activity control system for the manufacturing of engineered work surfaces

This paper describes the design and implementation of an Automated Process Planning and Production Activity Control system for a make-to-order business and presents a formal methodology for the development of integrated manufacturing systems. The research is based on concepts developed in a project undertaken in a job shop Case Study facility, producing precision-engineered work surfaces. Industry today is facing numerous challenges on many fronts demanding improved availability and dissemination of processing information. On the demand side there is increased pressure on the manufacturer to meet deadlines and provide the customer with a prompt, efficient service, with accurate lead-time information, and a product of the utmost quality, on time. On the supply side there is increasing competition, variety in the market, a diverse product range, varying processing times and extremely short lead times. The nature of today's business world means that real-time information is a requirement and not an extra. This paper documents the design, structure and implementation of an Automated Process Planning system, which completely automates and integrates Order Entry stages from order receipt to order release. The developed system, namely the Manufacturing Optimization Information System, or MOIS, relays information to and from shop floor operators via a Production Activity Control system at each of the manufacturing stations. The MOIS is part of ongoing research endeavouring to integrate order processing, Process Planning and production control activities with a combined dynamic scheduling and material optimization module in a holistic manufacturing optimization system. The two specific aims of this paper are very clear; first, to bridge the theory-practice gap between theoretical concepts and real industrial issues surrounding Process Planning and Production Control. Secondly, to outline the design, structure and evolution of an integrated Automatic Process Planning and Production Activity Control system, installed in a make-to-order enterprise.     

Solubilisation of calcium and magnesium from the marine red algae Lithothamnion calcareum

Marine minerals are a potential source of calcium and magnesium for nutritional supplementation. This study analysed the solubilisation of calcium and magnesium from the skeletal remains of Lithothamnion calcareum. Scanning electron microscopy analysis demonstrated a nonporous microstructure. Spectrophotometric determination showed that the calcium and magnesium contents were 30.01 and 6.22% (w/w), respectively. Solubilisation of calcium and magnesium was highly pH dependent. The temperature‐dependent solubilisation of calcium fitted the shrinking core model. The apparent activation energy for calcium solubilisation was 28.6 kJ mol^?1. Inclusion of caseinophosphopeptides (CPPs), casein‐derived mineral binding peptides, during the solubilisation of calcium and magnesium appeared to decrease the extent of calcium solubilisation at pH 6.0 and 8.0. The results herein have implications for the choice of optimal pH conditions for the sustained release of calcium and magnesium from marine mineral sources.     

The influence of train properties on railway ground vibrations

This paper uses a sensitivity analysis to quantify the dominant train properties (mass and spacing of wheels and bogies) that contribute to ground-borne vibration generation, with the aim of reducing the complexity of train–track numerical models. This research is significant because ground-borne vibration from railways is a growing problem, particularly in urban areas. Despite this fact, attempting to predict vibration levels is complex because there are many variables that contribute to the overall dynamic response. Therefore, a deterministic approach is commonly used, that ignores many of these variables. Thus, this paper identifies the variables that can be ignored, while highlighting those that are highly influential on vibration generation. For this purpose, a previously validated 2.5D finite elements-boundary elements approach is used to simulate dynamic train–track interaction. It is computed many times for a variety of modelling variables to investigate the effect of each on the ground-borne vibration levels in the far field. It is found that increases in unsprung mass of the train causes a large increase in vibration levels. Furthermore, changes in wheel/bogie spacing and semi-sprung mass are found to have a minimal effect on vibration generation.     

Jungian family sandplay with bereaved children: Implications for play therapists.

Jungian family sandplay (JFS) with bereaved clients, especially young children, may assist family members in communicating their intrapersonal world of grief through symbolic methods. Specifically, play therapists using JFS provide the opportunity for children to share feelings with caretakers that may be developmentally difficult to verbalize. With JFS, children use nonthreatening images to portray feelings and struggles associated with the death of a loved one. The focus of this article is the importance of including caretakers and family members in bereaved children’s sandplay. In addition, we include a clinical vignette to illuminate the potential benefits of incorporating JFS with bereaved children. We conclude with implications for play therapists. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Unique and common mechanisms of change across cognitive and dynamic psychotherapies.

The goal of this article was to examine theoretically important mechanisms of change in psychotherapy outcome across different types of treatment. Specifically, the role of gains in self-understanding, acquisition of compensatory skills, and improvements in views of the self were examined. A pooled study database collected at the University of Pennsylvania Center for Psychotherapy Research, which includes studies conducted from 1995 to 2002 evaluating the efficacy of cognitive and psychodynamic therapies for a variety of disorders, was used. Patient samples included major depressive disorder, generalized anxiety disorder, panic disorder, borderline personality disorder, and adolescent anxiety disorders. A common assessment battery of mechanism and outcome measures was given at treatment intake, termination, and 6-month follow-up for all 184 patients. Improvements in self-understanding, compensatory skills, and views of the self were all associated with symptom change across the diverse psychotherapies. Changes in self-understanding and compensatory skills across treatment were predictive of follow-up symptom course. Changes in self-understanding demonstrated specificity of change to dynamic psychotherapy. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Challenges in modelling the evolution of stress corrosion cracks from pits

The evolution of stress corrosion cracks from pits is important in many industrial applications but continues to be a challenge in both measurement and prediction. Life prediction in these circumstances has to account for pit growth kinetics, the conditions for the transition from pits to cracks, and the growth rate of cracks in the short and long crack domain. An example of importance is the performance of steam turbine rotors in power generation. Although stress corrosion failures are comparatively rare, the consequences can be severe and occasionally catastrophic. Consequently, considerable effort is being focused on evaluating the effect of operational variables on pitting and crack growth and in developing an improved basis for structural integrity assessment. A preliminary mathematical model based on deterministic equations with statistically variable input parameters was developed for simulating the evolution of the pit depth distribution at different exposure times, and the transformation to stress corrosion cracks was based on the Kondo criteria. The model predicted some features of the damage well but recent novel measurements of the evolution of stress corrosion cracks from pits combined with finite element analysis of the strain distribution suggest that the transition from a pit to a crack is more complex than can be accounted for by the Kondo approach.     

Design of a composite sulfuric acid decomposition reactor,concentrator, and preheater for hydrogen generation processes

The Hybrid Sulfur Process, as well as similar sulfur cycles for the production of nuclear hydrogen, requires the decomposition of sulfuric acid into sulfur dioxide, oxygen, and water at temperatures above 800 °C and at pressures up to 9 MPa. The design of a reactor for this process presents numerous challenges in terms of maintaining small pressure differentials and utilizing currently available materials of construction. This paper focuses on design calculations for a composite reactor that preheats, concentrates, and decomposes sulfuric acid for use in the production of hydrogen. The decomposition reaction takes place within individual tubes of a multitube reactor.     

The first step towards a 100% renewable energy-system for Ireland

In 2007 Ireland supplied 96% of the total energy demand with fossil fuels (7% domestic and 89% imported) and 3% with renewable energy, even though there are enough renewable resources to supply all the energy required. As energy prices increase and the effects of global warming worsen, it is essential that Ireland begins to utilise its renewable resources more effectively. Therefore, this study presents the first step towards a 100% renewable energy-system for Ireland. The energy-system analysis tool used was EnergyPLAN, as it accounts for all sectors of the energy-system that need to be considered when integrating large penetrations of renewable energy: the electricity, heat, and transport sectors. Initially, a reference model of the existing Irish energy-system was constructed, and subsequently three different 100% renewable energy-systems were created with each focusing on a different resource: biomass, hydrogen, and electricity. These energy-systems were compared so that the benefits from each could be used to create an ‘optimum’ scenario called combination. Although the results illustrate a potential 100% renewable energy-system for Ireland, they have been obtained based on numerous assumptions. Therefore, these will need to be improved in the future before a serious roadmap can be defined for Ireland’s renewable energy transition.     

Alternating current electrical field effects on lettuce (Lactuca sativa) growing in hydroponic culture with and without cadmium contamination

The aim of the present study was to investigate the effect of a 10 Hz alternating current (10 Hz 1 V cm⁻¹) and a 50 Hz alternating current (50 Hz 1 V cm⁻¹) on the lettuce plant (Lactuca sativa) growing in a hydroponic (soil-free) culture. Thirty lettuce plants were pre-germinated, and then 15 of them were treated with cadmium solution (CdCl₂) of 5 mg/L in concentration. Ten plants (five plants with Cd and five plants without Cd) were subjected to a 10 Hz alternating current (AC) electrical field; 10 plants were subjected to a 50 Hz AC field. The rest of the plants were used as a control. The lettuce plants were harvested after a growth of 60 days. The chlorophyll content, biomass and metal content of the lettuce plants were determined. The biomass of the plants growing in non-contaminated medium was 28 and 106% higher under the 10 and the 50 Hz AC fields respectively compared to the control. Although the plant biomass was reduced by the presence of Cd in the growth medium, the biomass of the plants growing in Cd contaminated medium was 40 and 63% higher respectively for 10 and 50 Hz AC field compared to the plant growing in Cd contaminated medium without electrical treatment. Increased uptake of Cd in the plant shoot was found with the 50 Hz AC field. Significant accumulation and uptake of Cu in plant roots and shoots was found under both electrical treatments.