Toward High-Performance Dihydrophenazine-Based Conjugated Microporous Polymer Cathodes for Dual-Ion Batteries through Donor–Acceptor Structural Design

Recent studies have demonstrated that dihydrophenazine (Pz) with high redox-reversibility and high theoretical capacity is an attractive building block to construct p-type polymer cathodes for dual-ion batteries. However, most reported Pz-based polymer cathodes to date still suffer from low redox activity, slow kinetics, and short cycling life. Herein, a donor–acceptor (D–A) Pz-based conjugated microporous polymer (TzPz) cathode is constructed by integrating the electron-donating Pz unit and the electron-withdrawing 2,4,6-triphenyl-1,3,5-triazine (Tz) unit into a polymer chain. The D–A type structure enhances the polymer conjugation degree and decreases the band gap of TzPz, facilitating electron transportation along the polymer skeletons. Therefore the TzPz cathode for dual-ion battery shows a high reversible capacity of 192 mAh g⁻¹ at 0.2 A g⁻¹ with excellent rate performance (108 mAh g⁻¹ at 30 A g⁻¹), which is much higher than that of its counterpart polymer BzPz produced from 1,3,5-triphenylbenzene (Bz) and Pz (148 and 44 mAh g⁻¹ at 0.2 and 10 A g⁻¹, respectively). More importantly, the TzPz cathode also shows a long and stable cyclability of more than 10 000 cycles. These results demonstrate that the D–A structural design is an efficient strategy for developing high-performance polymer cathodes for dual-ion batteries.     

Multimedia image quality assessment based on deep feature extraction

Multimedia Tools and Applications - Measurement of visual quality is of significant importance to many image processing tasks. The target of image quality assessment (IQA) is to design effective...     

Low-fouling polysulfone ultrafiltration membranes with amphiphilic sulfobetaine polyamide as additive

In this study, amphiphilic sulfobetaine polyamide (sPA) oligomers with sulfobetaine as end groups and arylamide as backbone were synthesized as the pore-forming additive for the preparation of polysulfone membranes. This additive showed good solubility and compatibility with the membrane casting solution due to the self-assembly behaviors of sPA in organic solvent. Moreover, the effects of hydrophobic chain length and additive dosage on membrane morphology, hydrophilicity, permeability, antifouling, and mechanical properties were systematically studied. In view of these results, it can be concluded that the higher content and smaller size of sPA in the casting solution correlated with better filtration and separation performances of the membranes. Results showed that the pure water flux increased from 68.2 L m⁻² hr⁻¹ for the pristine membrane to a maximum of 205 L m⁻² hr⁻¹ for the blend membrane, meanwhile, the protein rejection ratio was above 95.2% and the flux recovery ratio was promoted from 68.3% to above 85.0%. The fouling resistance of the blend membranes was further demonstrated by significantly reduced protein/bacteria adhesion. And consistent high-performances in filtration and separation were demonstrated after the blend membranes were treated at 90°C.     

Sensitivity analysis of Johnson-Cook material parameters on adiabatic shear in different directions

ABSTRACT

This study investigates the effects of strain, strain rates, and forming directions (RD-rolling direction, TD-transverse direction, and ND-normal direction) on adiabatic shear, via dynamic impact compression tests using the Split Hopkinson Pressure Bar (SHPB) apparatus. A modified Johnson-Cook (J-C) constitutive model is proposed, which used to analyse the influence of the constitutive parameters on the sensitivity of adiabatic shear, employing a finite element software. The different sensitivities of adiabatic shear under different directions are explained by combining microscopic analysis and results from mechanical responses. The results show that the sensitivity of adiabatic shear can be related to the time of stress collapse in the following trend: ND?>?TD?>?RD; the sensitivities of these constitutive parameters on adiabatic shear are calculated and compared.     

从整流角度分析离子膜电解槽运行中发生的问题

从整流角度探讨离子膜电解槽运行中停电的原因并对电解槽常发生的问题加以归类,从中可看出哪些与整流有关,哪些与整流无关;提出了对电解槽所发生的问题应作具体分析并客观对待的观点。     

压力注浆治理公路工程矿井采空塌陷区技术的探讨

压力注浆从根本上治理公路工程中的矿井采空塌陷区,本文对该方法的设计、施工及技术要求等若干问题进行探讨。     

钢筋混凝土梁腐蚀后疲劳性能的试验研究

对先人工腐蚀和预裂后再人工腐蚀的钢筋混凝土梁试件进行了静力荷载和高周疲劳荷载试验研究,比较了腐蚀对钢筋混凝土梁静力性能和疲劳性能的影响。研究表明,当钢筋腐蚀率较低(小于5%)时,钢筋混凝土梁的静承载力没有明显的变化,但在高周反复荷载作用下,梁疲劳承载力大为降低,特别是试验前预腐蚀的梁,疲劳寿命仅为未腐蚀梁的26%。疲劳承载力降低的原因是局部腐蚀(即使程度很小)导致梁中钢筋出现微缺陷,或使已有的微缺陷扩大,加速了钢筋微裂纹的扩展。所以,对于腐蚀环境中承受反复荷载作用的钢筋混凝土结构,设计中应特别注意腐蚀对结构疲劳性能的影响。     

短期荷载作用下钢-竹界面黏结应力和滑移分析

为研究钢-竹界面黏结应力与滑移分布,设计了两种类型的界面：型钢与竹板仅通过胶黏剂粘贴的单纯胶结型界面以及在胶黏剂粘贴基础上用螺钉加强的复合胶结型界面,并进行6个钢-竹组合试件的推出试验,得到黏结界面的剪切承载力及外贴竹板的应变。通过力学分析推导出外贴竹板正应力二阶微分方程,结合边界条件与数据拟合解得外贴竹板正应力表达式,并建立了钢-竹界面剪应力与相对滑移计算式,在此基础上提出了短期荷载作用下的钢 竹界面承载力计算方法。试验与理论分析结果表明：钢-竹界面剪切黏结性能良好,复合胶结型界面试件的破坏具有显著的延性特征;外贴竹板正应力试验值与拟合值吻合度高,以此为基础计算剪应力与相对滑移较为可靠;钢-竹界面剪应力与相对滑移分布具有两端大中间小的特征,且竹板受力端黏结界面的剪应力和滑移量明显大于黏结基体受力端黏结界面,剪应力最大值约为1.64 MPa;钢-竹界面剪切黏结承载力计算值与试验值吻合较好,其计算误差小于8%。     

Investigation on structure and properties of anion exchange membranes based on tetramethylbiphenol moieties containing copoly(arylene ether)s

Quaternary ammonium functionalized poly(arylene ether)s (QPAEs) containing 2,2′,6,6′‐tetramethylbiphenol moieties were designed and successfully synthesized via nucleophilic substitution polycondensation, bromination, quaternization and alkalization. The structure, water uptake, ion exchange capacities (IECs), hydroxide ion conductivities, and mechanical properties, as well as thermal and chemical stabilities of obtained QPAEs membranes were investigated. The QPAE‐a membrane with IEC value of 0.98 meq g^?1 demonstrated the highest ion conductivity (47.4 mS cm^?1) at 80°C. The ion transport activation energy (E_a) of QPAEs membranes varied from 8.57 to 19.95 kJ mol^?1. After chemical stability test conditioned in 1M NaOH at 60°C for 7 days, the QPAEs membranes except QPAE‐c (IEC = 0.88 meq g^?1) still exhibited high hydroxide ion conductivities (over 15 mS cm^?1) and acceptable tensile strength (～10 MPa). These properties indicate that the ionomers membranes are potential candidates for anion exchange membranes in anion exchange membrane fuel cells. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41525.     

东濮凹陷页岩油气富集条件

文中立足于东濮凹陷勘探实践,在岩心观察、有机地化和镜下薄片等资料分析的基础上,总结了页岩油气的富集条件。富集泥页岩发育决定了页岩油气的主力层位,东濮凹陷沙河街组沙三中、下为页岩油气最富集的层位,有机碳质量分数高,主要为Ⅱ1和Ⅰ型干酪根,热演化程度适中(Ro为1%~2%);沉积体系和有利岩相是页岩油气富集的重要因素,富集泥页岩主要分布在深湖—半深湖和前三角洲泥沉积体系中,其中的纹层状灰质泥岩岩相储集空间发育程度和油气富集程度均高,是最有利的岩相类型。脆性矿物体积分数和裂缝发育程度是页岩油气富集的关键,东濮凹陷脆性矿物体积分数超过60%,有利于裂缝的形成及后期压裂改造;盐岩及异常高压的发育是东濮凹陷页岩油气保存的重要原因。运用多因素叠合法预测沙三中4—5、沙三中8、沙三下1—2是最有利的勘探层位,濮卫和柳屯—海通集洼陷是最有利的目标区,并部署实施卫68￣1HF等井,取得初步成效。