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1.
Laser aided additive manufacturing(LAAM)was used to fabricate bulk Fe49.5Mn30Co10Cr10C0.5 interstitial multicomponent alloy using pre-alloyed powder.The room temperature yield strength(σy),ultimate tensile strength(σUTS)and elongation(εUST)were 645 MPa,917 MPa and 27.0%respectively.The as-built sample consisted of equiaxed and dendritic cellular structures formed by elemental segregation.These cellular structures together with oxide particle inclusions were deemed to strengthen the material.The other contributing components include dislocation strengthening,friction stress and grain bound-ary strengthening.The high εUTS was attributed to dislocation motion and activation of both twinning and transformation-induced plasticity(TWIP and TRIP).Tensile tests performed at-40℃and-130℃demonstrated superior tensile strength of 1041 MPa and 1267 MPa respectively.However,almost no twinning was observed in the fractured sample tested at-40℃and-130℃.Instead,higher fraction of strain-induced hexagonal close-packed(HCP)ε phase transformation of 21.2%were observed for fractured sample tested at-40℃,compared with 6.3%in fractured room temperature sample.  相似文献   
2.
Chlorpyrifos is a Malaysian Pesticide Board-approved organophosphate insecticide, which may become concentrated during fractionation. The objective of this project was to develop and validate a method to detect and quantify chlorpyrifos in food-grade fatty acids ingredients, e.g. caprylic-capric acid mixture and oleic acid (OLA) used to synthesize triacylglyceride based food additives and in the cosmetic industry. A selective ion monitoring gas chromatography–mass spectrometry method with a matrix-matched calibration curve calibration was selected. The method involved the direct injection of chlorpyrifos spiked into the fatty acids matrix. The percentage recoveries at spiking levels of 0.5, 0.75, 2.5, and 4.0 μg g−1 of chlorpyrifos in OLA and caprylic-capric acid ranged from 85.7%–101.1% to 97.2%–112%, respectively, with a relative standard deviation of within 11%. The intra-day and inter-day precision were deemed acceptable as indicated by an relative SD value of within 10%. A good linear relationship with a coefficient of correlation >0.99 for the matrix-matched calibration was achieved between 0.5 and 5 μg g−1. The limit of detection and limit of quantification corresponded to 0.5 μg g−1 for OLA and 0.55 μg g−1 for caprylic-capric acid.  相似文献   
3.
Cai  Bo  Weng  Rui  Zhang  RuiXian  Liang  Ye  Zhang  LiXian 《中国科学:技术科学(英文版)》2021,64(2):353-363
This paper addresses the problem of the design of controller for fuzzy semi-Markov jump systems with hidden modes against the incomplete information on probability density functions of sojourn time. Two ubiquitous circumstances in practice are taken into account, which are often ignored in other related work:(1) the phenomenon that system modes cannot be accessed entirely is considered proactively;(2) finitely accessible information on probability density functions is studied in this paper. By virtue of hidden semi-Markov chain, the underlying systems are modeled as hidden semi-Markov jump systems, which are more general than semi-Markov jump systems. Sufficient conditions on the existence of desired accessible-mode-dependent fuzzy controller are derived such that the fuzzy hidden semi-Markov jump systems is mean square stable. Based on the emission probability matrix, the presented control policy overcomes the possible mode-mismatch between the system mode and the accessible mode.Finally, an example is provided to demonstrate the effectiveness of the proposed control method.  相似文献   
4.
Radicals are closely related to human life and health and have been widely used in biology, chemistry, functional materials, etc. However, the high reactivity, disorder, and short half-lives limit their wide applications. Therefore, it remains a great challenge to prepare stable and ordered radicals. Herein, radicals are prepared with protective umbrellas (diethylmethyleneamine, DEMA) that are integrated on the surface of 2D layered materials to isolate water and oxygen and enhance the stability of radicals. Taking 2D black phosphorus (BP) as an example: triethylamine reacts with dichloromethane to form quaternary ammonium salts with further Hoffmann elimination to produce DEMA radicals that could react with one electron of a lone pair electrons in P on the surface of BP to produce P radicals, which shows a prolonged half-life of 21 days at room temperature. First-principle calculations and electron paramagnetic resonance fitting confirm that the steric hindrance constructed by dense DEMA passivation layer acts as a protective umbrella and the 2D coupling of P radicals and other P atoms in 2D BP plane to enhance the stability and strong superexchange interaction of P radicals. Furthermore, it is a general strategy to produce stable radicals integrated on the 2D plane.  相似文献   
5.
翁烨  邵德盛 《城市勘测》2022,(1):69-73,79
在多元线性回归模型中,经典最小二乘解称为最优线性无偏估计解,系数矩阵的复共线性导致最小二乘参数解变得极不稳定。针对测量系统中的病态问题求解,结合岭估计和主成分估计的优势,推导出一种新的岭估计解法,验证了该方法的可行性。利用均方误差极小化,得出不同岭参数的求解公式及新估计的精度评定方法。通过算例证明了在均方误差有意义下,新的岭估计解法优于最小二乘估计和狭义岭估计解法。  相似文献   
6.
采用表面活性剂辅助水热法制备出LiNi1/3Co1/3Mn1/3O2/V2O5三元正极复合材料,探讨了该复合材料形貌、结构并研究了其电化学性能.实验结果表明,使用十二烷基苯磺酸钠(SDBS)作为表面活性剂,用1%V2O5对材料进行包覆,获得了均匀、紧密的复合材料颗粒.在2.5~4.6 V电压、0.5 C放电倍率条件下,首次放电量达到201.516 mAh/g,容量保持率高,具备良好的循环稳定性与倍率性能.表明所制备的LiNi1/3Co1/3Mn1/3O2/V2O5三元正极复合材料具有良好的电化学性能.  相似文献   
7.
王付胜  陈韬  窦盛  翁赛 《太阳能学报》2022,43(5):187-192
多电平逆变器包含大量的半导体开关,以级联H桥光伏逆变器为例,针对开关管开路故障提出一种快速故障诊断和处理方法。在载波的顶端或底端采样每个H桥模块的输出电压,将其作为判断开关管开路故障的判据。诊断完成后,采取相应的措施降低故障程度。该方法可在一个载波周期内完成故障开关管的精确定位。实验结果验证了该方法的有效性。  相似文献   
8.
Endoplasmic reticulum (ER) stress response is an adaptive program to cope with cellular stress that disturbs the function and homeostasis of ER, which commonly occurs during cancer progression to late stage. Late-stage cancers, mostly requiring chemotherapy, often develop treatment resistance. Chemoresistance has been linked to ER stress response; however, most of the evidence has come from studies that correlate the expression of stress markers with poor prognosis or demonstrate proapoptosis by the knockdown of stress-responsive genes. Since ER stress in cancers usually persists and is essentially not induced by genetic manipulations, we used low doses of ER stress inducers at levels that allowed cell adaptation to occur in order to investigate the effect of stress response on chemoresistance. We found that prolonged tolerable ER stress promotes mesenchymal–epithelial transition, slows cell-cycle progression, and delays the S-phase exit. Consequently, cisplatin-induced apoptosis was significantly decreased in stress-adapted cells, implying their acquisition of cisplatin resistance. Molecularly, we found that proliferating cell nuclear antigen (PCNA) ubiquitination and the expression of polymerase η, the main polymerase responsible for translesion synthesis across cisplatin-DNA damage, were up-regulated in ER stress-adaptive cells, and their enhanced cisplatin resistance was abrogated by the knockout of polymerase η. We also found that a fraction of p53 in stress-adapted cells was translocated to the nucleus, and that these cells exhibited a significant decline in the level of cisplatin-DNA damage. Consistently, we showed that the nuclear p53 coincided with strong positivity of glucose-related protein 78 (GRP78) on immunostaining of clinical biopsies, and the cisplatin-based chemotherapy was less effective for patients with high levels of ER stress. Taken together, this study uncovers that adaptation to ER stress enhances DNA repair and damage tolerance, with which stressed cells gain resistance to chemotherapeutics.  相似文献   
9.
目的:为提高柚子皮的利用率和高值化利用,开发添加柚子皮全粉的鱼糜制品,研究不同粒径的柚子皮全粉对鱼丸品质特性和蛋白二级结构的影响。方法:采用粒径筛分和气流粉碎处理技术制备不同粒径的柚子皮全粉,并以市售膳食纤维为对照,研究不同粒径的柚子皮全粉对冷藏和冻藏鱼丸的持水力、凝胶强度、质构及色泽等品质特性的影响。基于红外光谱分析不同粒径的柚子皮全粉对鱼丸蛋白质结构的影响规律。结果:与空白组鱼丸对比,冷藏24 h后,添加不同粒径的柚子皮全粉和膳食纤维,导致冷藏鱼丸的持水力、凝胶强度、硬度和咀嚼性降低(P<0.05)。冻藏7 d后,添加粒径<150 μm柚子皮全粉,鱼丸的持水力显著高于空白组和添加市售膳食纤维的鱼丸(P<0.05),其凝胶强度和弹性均与空白组无明显差异(P≥0.05)。随着柚子皮全粉颗粒粒径的减小,对鱼丸的持水力提高作用降低,鱼丸的硬度和咀嚼性显著降低。冻藏鱼丸FTIR光谱分析显示,添加<150 μm柚子皮全粉使鱼丸的β-折叠结构增加,蛋白凝胶分子结构的有序性提高。结论:较大颗粒的柚子皮全粉(<150 μm)更适用于生产加工冻藏鱼丸,可起到明显改善鱼丸持水力的作用。不同粒径的柚子皮全粉对冻藏鱼丸蛋白二级结构的影响显著。  相似文献   
10.
There is growing interest in developing intracellular RNA tools. Herein, we describe a strategy for N3-kethoxal (N3K)-based bioorthogonal intracellular RNA functionalization. With N3K labeling followed by an in vivo click reaction with DBCO derivatives, RNA can be modified with fluorescent or phenol groups. This strategy provides a new way of labeling RNA inside cells.  相似文献   
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