High molecular weight linear poly(phenylene sulfide sulfone)s (PPSS) were prepared by aromatic nucleophilic substitution reaction at atmospheric pressure. Influences of various polymerization conditions, such as solvent, catalyst, molar ratio, reaction temperature and time, on the molecular weight of PPSS were examined. The intrinsic viscosity of PPSS obtained under optimum synthesis conditions according to orthogonal experiments was 0.55 dl/g. The results of FT-IR, 1H-NMR, UV spectrum and Raman spectrum confirmed the linear chain nature of product. The maximum UV absorption of PPSS increased with the increase of its intrinsic viscosity. X-ray diffraction and SALS studies indicated that some local ordered structures formed in the samples annealed between 220 ○C∼240 ○C for 4 h. The improvement in thermal performance of PPSS of high molecular weight was confirmed by DSC and TGA experiments. 相似文献
MXene是一类新型二维过渡金属碳化物晶体,该类材料具有一些优异的性质,如高的电导率、低的锂离子扩散能垒、独特的金属离子吸附特性等等,但是,作为锂离子电极材料时,MXene材料容量较低,限制了它在锂离子电池领域的进一步应用。本文以Ti_3C_2(最具代表性的一种MXene材料)为基体材料,通过液相插层、水热合成以及高温热处理,成功制备出二维SnS@Ti_3C_2复合材料。研究发现,当Ti_3C_2:L-半胱氨酸的质量比为1:3时(L-半胱氨酸:Na2Sn O3·4H2O=1:4),合成出来的Sn S@Ti_3C_2在0.1 A×g~(-1)的电流密度下循环50次之后,容量达到735.8 m Ah×g~(-1),且保持稳定;在3 A×g~(-1)的电流密度下,其容量能达到525.4 m Ah g~(-1);而当电流恢复到0.1 A×g~(-1)时,其容量能恢复到689.2 m Ah×g~(-1),展现出了优异的倍率性能。 相似文献
The AC loss per cycle per unit length of a round superconducting wire has been theoretically analyzed based on the critical state model and numerically calculated from the power-law model. By using Bean’s critical state model, it is found that the distribution of critical current density Jc which increases from the center to the edge along a radial direction lowers the loss value. And the sharper the Jc varies, the more significant the loss reduction. After considering the coupling of thermoelectric interaction, the results show that the temperature in superconducting wires gradually increases and finally becomes stable. The temperature of stable state has a dependence on the Jc distribution and the rise of temperature has an important effect on the AC loss behavior. 相似文献
This paper proposes the Content Diffusion Model(CDM) for modeling the content diffusion process in information-centric networking(ICN).CDM is inspired by the epidemic model and it provides a method of theoretical quantitative analysis for the content diffusion process in ICN.Specifically,CDM introduces the key functions to formalize the key factors that influence the content diffusion process,and thus it can construct the model via a simple but efficient way.Further,we derive CDM by using different combinations of those key factors and put them into several typical ICN scenarios,to analyze the characteristics during the diffusion process such as diffusion speed,diffusion scope,average fetching hops,changing and final state,which can greatly help to analyze the network performance and application design.A series of experiments are conducted to evaluate the efficacy and accuracy of CDM.The results show that CDM can accurately illustrate and model the content diffusion process in ICN. 相似文献
Recognizing scene information in images or has attracted much attention in computer vision or videos, such as locating the objects and answering "Where am research field. Many existing scene recognition methods focus on static images, and cannot achieve satisfactory results on videos which contain more complex scenes features than images. In this paper, we propose a robust movie scene recognition approach based on panoramic frame and representative feature patch. More specifically, the movie is first efficiently segmented into video shots and scenes. Secondly, we introduce a novel key-frame extraction method using panoramic frame and also a local feature extraction process is applied to get the representative feature patches (RFPs) in each video shot. Thirdly, a Latent Dirichlet Allocation (LDA) based recognition model is trained to recognize the scene within each individual video scene clip. The correlations between video clips are considered to enhance the recognition performance. When our proposed approach is implemented to recognize the scene in realistic movies, the experimental results shows that it can achieve satisfactory performance. 相似文献
Developing high dielectric performance of polymer nanocomposites is still a long-standing issue to simultaneously inherit the high dielectric constant of nanofillers and maintain the high breakdown strength of polymer matrix. In the current study, a tri-layered nanocomposite film is fabricated by a simple and effective solution-casting and dip-coating method, where graphene oxide nanosheets (GONSs) were modified by insulating SiO2 layer (SiO2@GONSs) and polyvinylidene fluoride (PVDF)/SiO2@GONS nanocomposite inner layer was sandwiched by polycarbonate (PC) layers. The surface modification could minimize the local electric field concentration and block conductive path. Furthermore, the sandwich or tri-layered structure inhibited the relaxation and migration of space charge or impurity ions and suppressed the charge injection, thus achieving enhanced breakdown strength and discharged energy efficiency. As a result, the as-prepared tri-layered nanocomposite film exhibited a dielectric constant of 5.2 and a low dielectric loss (tanδ) of 0.013 at 1 kHz, and breakdown strength of 219 MV m?1, which was significantly higher than single-layered nanocomposite films and its counterpart without SiO2 modification. The corresponding discharged energy density was 1.20 J cm?3 with an excellent efficiency of 86.2% at 200 MV m?1. More interestingly, the insulating SiO2 modification layer and PC outer layers could also effectively restrict the relaxation or migration of impurity ions at a high temperature of 120 °C, endowing excellent high-temperature dielectric performance to the as-prepared tri-layered nanocomposite film. The combination of surface modification and sandwich structure opens up an avenue to fabricate GONS-based dielectric nanocomposites with low dielectric loss, high breakdown strength, high efficiency and high temperature tolerance.