Potential of pulsed electric field to control Aspergillus parasiticus,aflatoxin and mutagenicity levels: Sesame seed quality

Seed processing technologies are essential for seed safety and functionality through protection of physicochemical quality, pathogen inactivation, aflatoxin detoxification and alleviation of mutagenicity. Design of a pilot-scale unit of pulsed electric fields (PEF) to treat sesame seeds with respect to quality parameters, Aspergillus parasiticus inactivation and aflatoxin reduction as well as alleviation of aflatoxin mutagenicity were prompted in this study. PEF energy ranged from 0.97 to 17.28 J achieved maximum reductions of peroxide value and acidity number of 67.4 and 85.7%, respectively, and did not change color L*, a*, b* and hue values. A 60% reduction of A. parasiticus counts occurred at the maximum PEF energy. Aflatoxins G1, G2, B1, and B2 contents decreased by 94.7, 92.7, 86.9, and 98.7%, respectively. Except for the samples treated by 2.16 J with 100 μg/plate and by 6.80 J with 10 μg/plate, PEF treatment provided elimination of aflatoxin mutagenity. It is concluded that PEF treatment can be used to treat sesame seeds with preservation of physicochemical properties, inactivation of A. parasiticus and decomposition of aflatoxins with reduced mutagenicity.     

Detailed analysis on thermal,microstructural, mechanical,and morphological features of side chain liquid crystalline polymer/isotactic polypropylene graft copolymers: Effect of grafted and ungrafted polymer units

The main scope of this comprehensive study is to investigate the effects of poly(p-benzophenoneoxycarbonylphenyl acrylate), poly(BPOCPA), which presenting as only graft units or both graft and ungrafted units in the matrix, on the fundamental features of isotactic polypropylene (IPP). The graft copolymerization of BPOCPA onto IPP was performed with the aid of bulk melt polymerization at varying monomer content levels ranging from 5% to 40%. The thermal behavior, crystal quality, mechanical performance, and surface morphology of the samples were investigated by means of differential scanning calorimeter, X-ray diffractometer (XRD), universal mechanical test, and scanning electron microscope (SEM) techniques. Thermal analyses depicted that there existed the noteworthy enhancements in both crystalline melting temperatures and percent crystallinities of matrix polymers. Furthermore, according to XRD results, a and b parameters increased significantly at low percentages of the graft units, while the parameter c decreased in all products in consistence with the content. As for the mechanical characterization, the grafting led to remarkable improvements in modulus, tensile and impact strength of the products. SEM micrographs indicated that the samples were completely homogeneous without any phase separation and the products exhibited brittle nature with some ductility.     

Estimation of target station data using satellite data and deep learning algorithms

In this study, an innovative model has been developed for wind speed estimation through the Deep Learning method using hourly wind speed data from the measurement stations of the General Directorate of Meteorology in Van and Hakkari provinces in Turkey in conjunction with simultaneous satellite images from Eumetsat. Obtained satellite images were used during the introduction of the model, while wind speed data were used at the output stage. As a result of the findings, it was found that 85% accuracy performance could be achieved to provide sufficient insight for systems that are widely established worldwide. The model, developed as a result of the study, eliminates the need to install wind measuring stations for any region on earth within the satellite field in terms of determining wind potential. Since the field of view of the Meteosat 7 satellite covers the whole of Eastern Europe, it was determined that it could predict a high rate of up to 6 hours later by the method used in image analysis. The systems to be controlled with this method will be able to examine the weather events instantly at each point in the satellite field of view and make more accurate decisions. Also, companies will be able to perform a more detailed and rapid field scan compared to existing limited methods, and reduce initial investment costs and operating costs in terms of renewable energy resources investments.     

Processing and Properties of Textured Potassium Sodium Niobate [K,Na]NbO3 Ceramic Ribbons by Alginate Gelation Method

Random and <001> textured potassium sodium niobate – [K,Na]NbO₃ (KNN) ceramics with 1 mole% CuO sintering aid were fabricated in ribbon form through a combination of novel alginate gelation process and templated grain growth methods using platelike sodium niobate ‐ NaNbO₃ (NN) template particles. The platelike NN template particles were prepared by a two‐step molten salt synthesis method. Ribbons were drawn from alginate‐based slurries without or with 10 wt% NN template particles using 50 mm long slit nozzle with a rectangular orifice of 10 mm × 1 mm. Development of crystallographic texture as a result of varying sintering time and temperature was evaluated through the calculation of the degree of orientation as measured by the Lotgering factor (?₍₀₀₁₎) and an ?₍₀₀₁₎ of 0.81 was achieved. The electrical properties of textured ribbons were evaluated with polarization and strain versus electric field measurements.     

Investigation of hybrid‐capacitor properties of ruthenium complexes

Ru complexes were successfully produced, and their structural properties were investigated using FTIR, Raman, and single crystal XRD patterns. The HOMO, LUMO, Eg, and electronic surface potential (ESP) values of the molecules were calculated by a Gaussian program. The complexes were used for producing hybrid capacitor cells as electrode materials. According to electrochemical analysis, complex 2 showed the best CV graph between ?1 V and +1 V and had the highest current value and hysteresis area when compared with the other complexes. The performance analysis and the capacity fade of the cells were investigated. The first capacity values of the complexes were 57.5, 22.1, 16.9, and 0.0021 F/g for complexes 1 , 2 , 3 , and 4 , respectively. The capacitive mechanism of the cells as relates to molecular interactions was also investigated. We suggested that the ESP values of the molecules were directly related to the capacitive performance of the cells. In addition to this, the best cycling performance was obtained for complex 2, which has the lowest Eg value among the complexes. We speculate that the charged regions on the complex materials have a crucial role in the increasing the capacitance of the cells.     

Design and determination of stator geometry for axial flux permanent magnet free rod rotor synchronous motor

During designing a new axial flux permanent magnet free rod rotor synchronous motor, it is important to know before hand in which phase the largest angular velocity can occur, what is the ways to reduce the power consumption, how to achieve to increase or decrease the rotation speed by changing the core geometry. Therefore, presenting these preliminary information that are necessary for the design of a free rod rotor synchronous motor to the researchers is the aim of this work. In this respect, this study presents the design and geometrical dimensions of the stator for a new synchronous motor which is an axial flux permanent magnet free rod machine with three, four, five and six phases. This type of motors are an innovative approach especially for the applications used in industrial stirrers. Each type of stator is designed such that it has an appropriate number of phases. The rotating magnetic field over the stator is established by a PIC based microcontroller feeding the interface circuit to the stator wounds. The maximum angular speeds of bar magnet rotors with four different lengths and masses are calculated theoretically and determined experimentally. In addition, the effects of the distance between the rotor and stator, the angular speed of the rotor within the limits of the operation, and the volume of the liquid to be stirred to the power applied are investigated. Furthermore, the effects of the lengths and angular speeds of the bar magnet rotors to the distance between the rotor and stator are determined. In the light of the information obtained and taking into account the power used, the most appropriate parameters and variables such as the stator geometry changing with the phase used, the length of rotor, the distance between the rotor and stator and the angular speeds of rotor are determined.     

A New Active Micro-Mixing Strategy

An active micro-mixing strategy through forcing the flow by synthetic wall jets is proposed. It is based on the interaction of induced streamwise vortices in a specific way. There is a spanwise shift between two quasi-streamwise vortices in such a way that one of them compresses the wall normal vorticity layer created by the other, leading to the generation of new wall normal vortical structures. The latter are subsequently tilted by the shear to give birth to new small-scale longitudinal active structures that are efficient in mixing. The feasibility of this strategy is shown through direct numerical simulations of high spatial and temporal resolution.     

Charge-Compensated <Emphasis Type="Italic">n</Emphasis>-Type Skutterudites

Ba+Yb double-filled n-type skutterudites with a modest degree of charge compensation by Fe on the Co lattice have been synthesized and compacted by spark-plasma sintering, and their thermoelectric properties evaluated at temperatures up to 800 K. Although this approach to making n-type skutterudites seems counterintuitive, the presence of Fe leads to a reduction in the thermal conductivity while it preserves a robust Seebeck coefficient. Consequently, a high ZT in excess of 1.3 was achieved at 800 K in these Fe-containing n-type skutterudite compounds.