Electro-copolymerisation of indene and styrene

Electroinitiated cationic copolymerisation of indene and styrene was investigated by constant potential electrolysis. Effects of copolymerisation potential and temperature on the copolymer composition and the reactivity ratios are discussed. The reactivity ratios of the monomers were calculated according to the integrated Lewis-Mayo equation.     

Instructional texts rewritten by five expert teams: Revisions and retention improvements.

700 undergraduates were tested in 3 experiments on original or rewritten versions of 52 instructional texts about Army job tasks, general science, philosophy, and history. Five experts had rewritten various sets of the texts and stated hypotheses about the efficacious features of their revisions. We tested their hypotheses and several others. Recall and recognition tests were given immediately and after a 24-hr delay. Results showed that revisions made by 3 of the 5 experts improved retention of text information. The kind and number of revisions and improvements varied across the text sets. Most expert hypotheses were not supported, and they made many revisions they were declaratively unaware of. Some of our hypotheses about the revision features were supported, but different features were effective for different sets of texts. It was concluded that some experts have effective knowledge about improving instructional text, but it exists primarily in procedural form. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Study of liquid injection impact on the performance of new refrigerant mixtures

In this paper, the test results of liquid injection impact on the performance of new alternative refrigerant mixtures such as: R-410A, R-507, R-407C and R-404A are discussed, analysed and presented. The test results were obtained using an air-source heat pump set-up with enhanced surface tubing under various liquid injection ratios. Performance tests were conducted according to the ARI/ASHRAE standards. The performance data demonstrated that as liquid injection ratio increases, compressor head pressure and discharge temperature decrease. This has a positive effect in protecting the compressor. The effect of liquid injection on mixture behaviour varies from one mixture to another depending upon the mixture's composition. Furthermore, liquid injection appears to have a significant influence on R-410A behaviour compared to the other mixtures in question. Copyright © 2002 John Wiley & Sons, Ltd.     

Preparation and Characterization of Inorganic Fluorides—Fullerenes Compounds

Reaction of metallic fluorides: WF₆ TaF₅, NbF₅ and TiF₄ with C₆₀/C₇₀ extract was performed at appropriate temperatures. M0F₅ and BF₃ fluorides do not react. Chemical formulas based on mass uptake show MF_n/C₆₀ ratios up to 2.00. Compounds were analysed by means of X-ray diffraction, FT-IR and NMR spectroscopies. The presence of neutral fluorides and associated anionic species is put forward and it is shown that MF_n compounds do not act as fluorination agents. Electrical conductivity measurements are also presented.     

In vitro cytotoxicity and DNA damage production in Chinese hamster ovary cells and topoisomerase II inhibition by 2-[2''-(dimethylamino)ethyl]-1, 2-dihydro-3H-dibenz[de,h]isoquinoline-1,3-diones with substitutions at the 6 and 7 positions (azonafides)

The p53 tumor suppressor gene encodes a phosphoprotein which when overexpressed can induce growth arrest at the G1 and G2/M phases of the cell cycle, promote differentiation and apoptosis. This paper demonstrates that p53 can associate with trk tyrosine kinase. Expression of a murine temperature-sensitive (ts) p53 mutant in PC12 cells overexpressing trk (a model system to analyse cellular differentiation and signal transduction induced by NGF) induces morphological changes in the absence of NGF stimulation at 32 degrees C but not at 37 degrees C. In cells differentiated by p53, trk, but not EGFr, was hyperphosphorylated on tyrosine. Furthermore trk was not phosphorylated when expressed in Saos-2 cells (human osteosarcoma cells that lack expression of both endogenous trk and p53) at either temperature. However, transfection of ts p53 into these cells induces trk phosphorylation at 32 degrees C in the absence of NGF stimulation. Association of trk and p53 can be detected in NIH3T3 and PC12 cells co-expressing trk and the ts p53 mutant, in NIH3T3 and PC12 cells transfected with trk alone, and in untransfected PC12 cells, showing that overexpressed and/or endogenous trk associates with endogenous, low levels of p53. These data suggest a novel function for p53 which involves the stimulation of signal transduction pathways (mediating morphological properties of cells), possibly through association with and hyperphosphorylation of trk.     

Fault tolerance in FFT arrays: Time redundancy approaches

Fault tolerance in VLSI/WSI FFT arrays acquires relevance when defects and run-time faults become significant, due to large dimensions of processors and arrays. Then, both restructuring to overcome end-of-production defects and reconfiguration to overcome run-time faults are required, to achieve the dual purposes of higher yield and higher reliability.Adopting as basic FFT network the two-dimensions array that directly corresponds to the FFT flow graph, the usual structure redundancy techniques tailored for two-dimensions arrays reconfiguration are not well applicable, since the limited locality of this network leads to relevant area increase due to the augmented interconnection structure.In this paper,time redundancy is suggested as a viable alternative for the two-dimensions FFT array; two different solutions are presented, one based oninter-stage reconfiguration, the other one adoptingintra-state reconfiguration, both allowing for survival to multiple faults with limited increase of network complexity and very small hard-core sections. As usual in many time redundancy methods, both approaches result in a processing speed equal to half the processing speed granted by an ideal, fault-free device.Reliability and survival ratios to multiple faults are evaluated for the two cases, taking into account also the area increments necessary for fault tolerance. The reliability evaluations allow for a direct comparison of the two solutions.     

Effect of electricity tariff on the optimum insulation-thickness in building walls as determined by a dynamic heat-transfer model

Thermal insulation is one of the most effective energy-conservation measures in buildings. Despite the widespread use of insulation materials in recent years, little is known regarding their optimum thickness under dynamic thermal conditions. Insulated concrete blocks are among the units most commonly used in the construction of building walls in Saudi Arabia. Typically, the insulation layer thickness is fixed at a value in the range 2.5–7.5 cm, regardless of the climatic conditions, type and cost of insulation material, and other economic parameters. In the present study, a numerical model based on a finite-volume, time-dependent implicit procedure, which has been previously validated, is used to compute the yearly cooling and heating transmission loads under steady periodic conditions through a typical building wall, for different insulation thicknesses. The transmission loads, calculated by using the climatic conditions of Riyadh for a west-facing wall, are fed into an economic model in order to determine the optimum thickness of insulation (L_opt). The latter corresponds to the minimum total cost, which includes the cost of insulation material and its installation plus the present value of energy consumption cost over the lifetime of the building. The optimum insulation thickness depends on the electricity tariff as well as the cost of insulation material, lifetime of the building, inflation and discount rates, and coefficient of performance of the air-conditioning equipment. In the present study, the effect of electricity tariff on the computed optimum insulation thickness is investigated. Different average electricity tariffs are considered; namely, 0.05, 0.1, 0.2, 0.3 and 0.4 SR/kWh (designated as Cases 1–5, respectively; 1 US$ = 3.75 Saudi Riyals). Results using moulded polystyrene as an insulating material show that the values of L_opt are: 4.8, 7.2, 10.9, 13.7 and 16.0 cm for Cases 1–5. Under the conditions of optimal insulation thickness for each electricity tariff, Case 1 gives the lowest total cost of 17.4 SR/m², while Case 5 gives the highest total cost of 53.1 SR/m². Corresponding thermal performance characteristics in terms of yearly total and peak transmission loads, R-value, time lag and decrement factor are presented.     

Oxidized Fullerene Derivatives Containing Hydroxyl, Nitro and Fluorine Groups

Oxidation of fullerene was performed with fuming nitric acid and a soluble orange compound was synthesized and identified as polyhydroxy-polynitro fullerene. The formation of fullerene derivatives containing oxygen and fluorine were attempted by different methods using F₂, HF aqueous solution and fuming nitric acid. Resulting compounds were generally characterized by X-ray diffraction and IR and NMR spectroscopy.