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AbstractThe performance of reliability inference strongly depends on the modeling of the product’s lifetime distribution. Many products have complex lifetime distributions whose optimal settings are not easily found. Practitioners prefer to use simpler lifetime distribution to facilitate the data modeling process while knowing the true distribution. Therefore, the effects of model mis-specification on the product’s lifetime prediction is an interesting research area. This article presents some results on the behavior of the relative bias (RB) and relative variability (RV) of pth quantile of the accelerated lifetime (ALT) experiment when the generalized Gamma (GG3) distribution is incorrectly specified as Lognormal or Weibull distribution. Both complete and censored ALT models are analyzed. At first, the analytical expressions for the expected log-likelihood function of the misspecified model with respect to the true model is derived. Consequently, the best parameter for the incorrect model is obtained directly via a numerical optimization to achieve a higher accuracy model than the wrong one for the end-goal task. The results demonstrate that the tail quantiles are significantly overestimated (underestimated) when data are wrongly fitted by Lognormal (Weibull) distribution. Moreover, the variability of the tail quantiles is significantly enlarged when the model is incorrectly specified as Lognormal or Weibull distribution. Precisely, the effect on the tail quantiles is more significant when the sample size and censoring ratio are not large enough. Supplementary materials for this article are available online. 相似文献
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Abbas Teimouri Marzieh Mahmoudsalehi Hossein Salavati 《International Journal of Hydrogen Energy》2018,43(31):14816-14833
As a series of bimetallic nanocatalysts, molybdenum/vanadium oxides supported on the silica (MoO3/V2O5/MCM-41) were prepared by the impregnation. Their catalytic activity in the oxidation of dibenzothiophene was investigated using H2O2 as an oxidant. Textures and surface properties of the prepared catalysts were characterized using FT-IR, XRD, FESEM-EDX and N2 adsorption/desorption techniques. The effects of main process variables including H2O2/DBT molar ratio, catalyst dosage, reaction temperature and reaction time were analyzed by employing the response surface methodology (RSM). The effect of the MoO3/V2O5 loading on the catalytic performance of the catalysts was also investigated. The results indicated that the catalytic activity of the catalyst was increased by enhancing the MoO3/V2O5 content. Thus, the catalyst with high MoO3/V2O5 loading (20%MoO3/20%V2O5/60%MCM-41) indicated the highest catalytic activity and could convert 99.06% of dibenzothiophene under the optimum conditions. Mass and FT-IR analysis demonstrated that the major product of dibenzothiophene oxidation was its corresponding sulfone. The catalyst could be recycled five times without any considerable reduction in its catalytic activity. The kinetics of the reaction fitted the pseudo-first-order equation pretty well. Eventually, a reaction mechanism for the catalytic oxidation of DBT in the presence of MoO3/V2O5/MCM-41 was proposed. 相似文献
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Mahmoud Hashemitabar Maryam Bahmanzadeh Ali Mostafaie Mahmoud Orazizadeh Marzieh Farimani Roshan Nikbakht 《International journal of molecular sciences》2014,15(10):17518-17540
The follicular fluid (FF) is produced during folliculogenesis and contains a variety of proteins that play important roles in follicle development and oocyte maturation. Age-related infertility is usually considered as a problem that can be solved by assisted reproduction technology. Therefore, the identification of novel biomarkers that are linked to reproductive aging is the subject of this study. FF was obtained from healthy younger (20–32 years old) and older (38–42 years old) women undergoing intracytoplasmic sperm injection (ICSI) due to male factor infertility. The FF was analyzed by two-dimensional gel electrophoresis (2-DE). The power of two-dimensional gel electrophoresis and the identification of proteins were exploited using matrix-assisted laser desorption-ionization time-of-flight/time-of-flight (MALDI-TOF-TOF) mass spectrometry. Twenty three protein spots showed reproducible and significant changes in the aged compared to the young group. Of these, 19 protein spots could be identified using MALDI-TOF-TOF-MS. As a result of MASCOT search, five unique downregulated proteins were identified in the older group. These were identified as serotransferrin, hemopexin precursor, complement C3, C4 and kininogen. A number of protein markers were found that may help develop diagnostic methods of infertility. 相似文献
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Effect of ionic strength on the reactivity ratios of acrylamide/acrylic acid (sodium acrylate) copolymerization 下载免费PDF全文
The ionic strength (IS) of polyelectrolyte solutions plays an important role in influencing reaction kinetics. The largely unstudied effect of IS on monomer reactivity ratios and copolymerization rates of acrylamide (AAm) and acrylic acid (AAc), in the form of sodium acrylate (NaAc), is investigated. Salt addition affects the nature of overall charges of the polyelectrolyte solution and diminishes the electrostatic repulsions between reacting chains. Therefore, changing the IS of the solution by incorporating salts affect not only the point estimates of the monomer reactivity ratios but also the overall behavior of the copolymerization (with a transition to azeotropic behavior). Experimental results on copolymerization rates confirm the observed trends in reactivity ratio behavior. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40949. 相似文献
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Javad Safaei-Ghomi Marzieh Kiani Abolfazl Ziarati Hossein Shahbazi-Alavi 《Journal of Sulfur Chemistry》2014,35(4):450-457
ZrP2O7 nanoparticles as an efficient catalyst have been used for the preparation of benzopyrano[2,3-b]pyridines from the four-component condensation reaction of salicylalde-hydes, thiols, and 2 equiv. of malononitrile under reflux conditions in ethanol in excellent yields and short reaction times. 相似文献