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1.
Daniel T. Payne Mandeep K. Chahal V clav B&rcaron ezina Whitney A. Webre Katsuhiko Ariga Francis D Souza Jan Labuta Jonathan P. Hill 《Frontiers of Chemical Science and Engineering》2020,14(1):28
Chiral 1,1’-binaphthyl-linked diporphyrin ‘tweezers’ (R)-1/(S)-1 and the corresponding zinc(II) complexes (R)-2/(S)-2 were prepared as chiral host molecules, and their utility for chiral analyses (especially enantiomeric excess (ee) determinations) were evaluated. Tris(1-n-dodecyl)porphyrins were used for the first time as the interacting units. Host capabilities of the diporphyrin tweezers were investigated by titrations with (R,R)- and (S,S)-cyclohexane-1,2-diamine (CHDA). The host molecules could be used as multichannel probes of ee by using UV-vis, circular dichroism (CD), fluorescence emission and 1H nuclear magnetic resonance (1H-NMR) methods. Chiral configurations could also be differentiated using CD or 1H-NMR spectroscopy. All three optical techniques give good resolution of ee with reasonable sensitivity considering the low concentrations used (ca. 10−6 mol·L−1). The ee determination of CHDA enantiomers using NMR spectroscopy is also possible because of the reasonably well separated resonances in the case of (R,R)- and (S,S)-CHDA. Non-metallated (R)-1/(S)-1 hosts could not be used to detect chiral information in a strongly acidic chiral guest. This work demonstrates the utility of 1,1’-binapthyl-linked chiral hosts for chiral analysis of ditopically interacting enantiomers. 相似文献
2.
John F.MOXNES Anne K.PRYTZ ?yvind FR?YLAND Stian SKRIUDALEN Steinar B?RVE Gard ?DEG?RDSTUEN 《兵工学报(英文版)》2015,(1):1-9
For the characterization of the behaviors of a metal material in events like expanding warheads, it is necessary to know its strength and ductility at high strain rates, around 104e105/s. The flyer plate impact testing produces the uniform stress and strain rates but the testing is expensive. The Taylor test is relatively inexpensive but produces non-uniform stress and strain fields, and the results are not so easily inferred for material modeling. In the split-Hopkinson bar(SHB), which may be used in compression, tension and torsion testing, the strain rates never exceeds 103/s. In the present work, we use the expanding ring test where the strain rate is 104e105/s. A streak camera is used to examine the expanding ring velocity, and a water tank is used to collect the fragments. The experimental results are compared with the numerical simulations using the hydrocodes AUTODYN, IMPETUS Afea and a regularized smooth particle(RSPH) software. The number of fragments increases with the increase in the expansion velocity of the rings. The number of fragments is similar to the experimental results. The RSPH software shows much the same results as the AUTODYN where the Lagrangian solver is used for the ring. The IMPETUS Afea solver shows a somewhat different fragmentation characteristic due to the node splitting algorithm that induces pronounced tensile splitting. 相似文献
3.
Pratik P. BHATT Venkatesh K. R. KODUR Anuj M. SHAKYA Tarek ALKHRDAJI 《Frontiers of Structural and Civil Engineering》2021,15(1):177
This paper presents the results of fire resistance tests on carbon fiber-reinforced polymer (CFRP) strengthened concrete flexural members, i.e., T-beams and slabs. The strengthened members were protected with fire insulation and tested under the combined effects of thermal and structural loading. The variables considered in the tests include the applied load level, extent of strengthening, and thickness of the fire insulation applied to the beams and slabs. Furthermore, a previously developed numerical model was validated against the data generated from the fire tests; subsequently, it was utilized to undertake a case study. Results from fire tests and numerical studies indicate that owing to the protection provided by the fire insulation, the insulated CFRP-strengthened beams and slabs can withstand four and three hours of standard fire exposure, respectively, under service load conditions. The insulation layer impedes the temperature rise in the member; therefore, the CFRP–concrete composite action remains active for a longer duration and the steel reinforcement temperature remains below 400°C, which in turn enhances the capacity of the beams and slabs. 相似文献
4.
The critical properties of the mixed manganite La0.67–x Y x Ba0.23Ca0.1Mn O3 with x=0.10 and x=0.15 around the paramagnetic(PM)-ferromagnetic(FM) phase transition were investigated through various techniques. These involved modified Arrott plots, Kouvel-Fisher method and Widom scaling relation. Magnetic data, analyzed in the critical region, using the above methods, yielded the critical exponents for(x=0.10) La0.57Y0.10Ba0.23Ca0.1Mn O3(β=0.312±0.002 and γ=1.147±0.003 at T C=299.23±0.05 K). Moreover, the estimated critical exponents of(x=0.15) La0.52Y0.15Ba0.23Ca0.1Mn O3 were β=0.286±0.004 and γ=0.943±0.002 at T C=289.53±0.06 K. The critical exponents’ values were close to the theoretical values of 3D-Ising model and tricritical mean-field model. These results suggested that the present composition should be close to a tricritical point in the La0.67–x Y x Ba0.23Ca0.1Mn O3 phase diagram. Expressing the field dependence as ΔS M∝H n allowed us to establish a relationship between the exponent n and the critical exponents of the material and to propose a phenomenological universal curve for the field dependence of ΔS M. 相似文献
5.
6.
A.Molin K.GhanbariAhari B.Josiek J.Molint 《中国耐火材料》2003,12(4):7-10
Physical properties and microstructural evolution on firing of 3 types of bauxite based refractory bricks were carried out using techniques such as porosimetry,XRD and SEM.The groups differed from each other by progressive refining of the matrix or bond phase.It is revealed that such a refinement of the matrix can improve the high temperature properties of the bricks made from poor grade materials. 相似文献
7.
8.
Li Wang ping Mechanics Department Huazhong University of Science Technology Wuhan P.R.China Yeo K.S. Khoo B.C. Mechanical Production Engineering Department National University of Singapore 《水动力学研究与进展(B辑)》1999,(3)
1. INTRODUCTIONThemaingoalofthispaperistoexplorethepossibilitytolearnmoreaboutthemechanismofturbulentboundarylayerflowinteractionsanditseffectsoncompliantwallperformance.Therearecertainprerequisiteconditionstofurtherthestudyonthemechanism,i.e.theco… 相似文献
9.
摩托罗拉微控制器(MCU)具有编程语言简单、外围设备齐全、存储器模型用户友好、选择广及供应多、性能价格比高等优点,被设计者评为最容易使用的产品之一。在全球顶级的原始设备制造厂商(OEM)的无数嵌入式系统和用户最终产品中都可找到摩托罗拉的MCU,包括键盘、传呼机、电子游戏机、洗衣机、安全系统及汽车等。 相似文献
10.
本文叙述了在金(Ⅲ)-溴化物-罗丹明6G(R6G)体系中高灵敏浮选分光光度法测定微量金。在溴存在下,形成R6G-Br二溴衍生物。金的化合物用二异丙醚浮选,用1M(mol/L)硫酸洗涤浮选物,并将其溶解在甲醇中。在545nm处测量溶液的吸光度。此浮选化合物被认为是一种加合物,其化学式为[(R6G-Br~+)(AuBr_4~-)]·12[(R6G-Br_3~+)(Br_3~-)]。表现摩尔吸光系数为11.4×10~51·mol~(-1)·cm~(-1)。严重干扰的元素有Pd,Ag,Hg(Ⅱ)和Tl(Ⅲ)。金从酸性溴化物介质中萃取到二异丙醚后,仅Tl(Ⅲ)严重干扰。本文提出的方法可应用于测定泡铜样品中的痕量金。结果表明,该法的精密度和准确度较好。 相似文献