Mechanical properties and microstructure changes of proton exchange membrane under immersed conditions

In this study, mechanical tensile stress–strain response and microstructure changes of proton exchange membranes (PEM) in immersed conditions are studied. The effects of water pretreatment and immersion time on stress–strain responses of Nafion^®?212 membranes are discussed. It is found that in the water immersion it took 24 h for the membrane to reach saturation equilibrium. Compared with dry membrane, immersed Nafion membrane shows a lower stress level at 30°C, but a higher stress level at 70°C. In situ small angle neutron scattering (SANS) experiments show that with the increase of temperature and water uptake, domains of the membrane become ordered and stay stable at around 60°C. Based on the observation, the relationship between the microstructure and mechanical properties is explained. POLYM. ENG. SCI. 54:2215–2221, 2014. © 2013 Society of Plastics Engineers     

“Growing Smarter Over Time”: An Emergence Model for Administrating a New Media Writing Studio

This article reports on efforts to create an administrative structure for learning and teaching multimodal composing that depends not on the leadership of a new media writing expert but on the collaboration of relative novices organized according to principles of emergent learning. Based on four years’ experience in a grant-funded program that supports new media composing in multiple disciplines, I report on the benefits of a bottom-up, emergent approach while raising questions about the long-term sustainability of such an approach. I conclude by describing efforts to create more top-down support for new media composing, while remaining committed to serving the teachers and students who are the real agents of change.     

Underrepresented students in STEM: The transition from undergraduate to graduate programs.

We used longitudinal tracking data from Cohorts I and II of the Gates Millennium Scholars (GMS) Program to test whether this intervention program and being a STEM (science, technology, engineering, and mathematics) undergraduate major helped underrepresented students transition into STEM graduate degree programs in 2006–2007. We found that being a GMS Scholar increased the odds of being currently enrolled in a graduate program and in a STEM graduate field, regardless of whether the student was a STEM undergraduate major. We also found that STEM undergraduate majors were more likely to transition into these graduate degree programs, and that being an undergraduate STEM major was especially beneficial to GMS Scholars. These findings varied considerably across underrepresented groups. We found that undergraduate intervention programs can both retain and insert underrepresented students at the STEM graduate level, thus potentially adding needed diversity at these educational levels. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Effects of osteoporosis on AIS 3+ injury risk in motor-vehicle crashes

Older occupants in motor-vehicle crashes are more likely to experience injury than younger occupants. One possible reason for this is that increasing age is associated with increased prevalence of osteoporosis, which decreases bone strength.Crash-injury data were used with Bayes’ Theorem to estimate the conditional probability of AIS 3+ skeletal injury given that an occupant is osteoporotic for the injury to the head, spine, thorax, lower extremities, and upper extremities. This requires the conditional probabilities of osteoporosis given AIS 3+ injury for each of the body regions, which were determined from analysis of the Crash Injury Research and Engineering Network database. It also requires information on probability of osteoporosis in the crash-involved population and the probabilities of AIS 3+ skeletal injury to different body regions in crashes. The latter probabilities were obtained from the National Automotive Sampling System-Crashworthiness Data System (NASS-CDS) database. The former was obtained by modeling the probability of osteoporosis in the US populations using data from the 2006 National Health Examination Nutrition Survey and applying this model to the estimate of the crash-involved population in NASS-CDS. To attempt to account for the effects of age on injury outcome that are independent of osteoporosis, only data from occupants who were 60 years of age or older were used in all analyses.Results indicate that the only body region that experiences a statistically significant change in fracture injury risk with osteoporosis is the spine, for which osteoporosis increases the risk of AIS 3+ fracture by 3.28 times, or from 0.41% to 1.34% (p < 0.0001). This finding suggests that the increase in AIS 3+ injury risk with age for non-spine injuries is likely influenced by factors other than osteoporosis.     

Case Study: Modeling Tidal Transport of Urban Runoff in Channels Using the Finite-Volume Method

A coupled flow and pollutant transport model based on the finite-volume method is developed and applied to predict the tidal transport of urban runoff in a southern California network of flood control channels that drain to near-shore bathing waters. Urban runoff in southern California contains elevated levels of indicator bacteria that signal the presence of fecal pollution and pose a risk to human health, and model predictions are used to understand the transport of these pollutants toward the coastline. The model is based on 1D conservation equations for fluid mass, momentum, and pollutant mass that are solved in integral form along channel reaches. A 2D formulation is solved at channel junctions. The model incorporates the monotone upwind scheme for conservation laws approach to give a high-resolution, nonoscillatory prediction of water level, velocity, and pollutant concentration. Model predictions and field measurements of water level, velocity, and a conservative urban runoff tracer are presented and compare favorably. This case study demonstrates that this finite-volume method–based scheme results in an accurate, stable, nonoscillatory and computationally manageable model. The nonoscillatory behavior is particularly beneficial in this study, since runoff enters the channels in pulses that create large gradients in pollutant concentration.     

Global ESRD Costs Associated with a Short Daily Hemodialysis Program in the United States

In spite of the growing evidence that daily hemodialysis (DHD) improves clinical outcomes and quality of life, the additional dialysis costs are not currently reimbursed in the United States. Nor have there been reports of the effects of DHD on end-stage renal disease (ESRD) global costs, which would help predict the financial impact of DHD on the ESRD program. Since 1996, 22 patients (20 in-center, 2 home) have switched from conventional thrice-weekly dialysis to short, daily dialysis with six treatments per week. Eighteen patients started for medical indications, and four started for nonmedical reasons. Causes of ESRD were the following: diabetes mellitus (6), hypertension (4), glomerulonephritis (6), hereditary (2), and other (4). Mean age was 56 ± 16 years. Patients had an average of 3.3 major comorbidities. Weekly conventional HD dialysis times were divided into six DHD treatments, each 2.0 ± 0.3 hours. Weekly Kt/V remained unchanged. Twenty-two patients were followed on DHD for 220 patient-months: 7 patients died after 1.8 ± 1.3 months, 2 were transplanted at 4.3 ± 3.2 months, and 2 discontinued DHD at 3.6 ± 4.8 months. Eleven patients remain on DHD at 17.4 ± 8.3 months. Actual costs per extra dialysis session are as follows: $14.30 for supplies and $3.20 for labor for setup/cleanup time (15 minutes at $12.80/hour). Annualized DHD savings are based on comparison of doses of epoetin alpha (Epogen) and blood pressure medication at the start and after 12 months of DHD. Hospitalization rates include all enrolled patients, comparing rates for the 12 months prior to DHD with the first year on DHD, or annualized rates for those on DHD less than one year. Cost assumptions are $9/ 1000 U Epogen, $1/blood pressure pill, and $1200/per day of hospitalization. Extra transportation costs were covered by the patients. No increased access problems were observed. For patients on short DHD longer than 12 months, supply and labor costs increased to $2733/patient/year; however, Epogen use was reduced 55%, and blood pressure medications were reduced 40%. For all patients who switched to DHD, hospitalization rates were reduced 24%. This resulted in a net savings of about $4241/patient/ year after 12 months on DHD. Overall ESRD costs were substantially decreased on DHD. These cost savings must be passed on to providers before DHD becomes more widely available.     

Marketing quality differentiated power

A panel discussion sponsored by the Marketing Task Force of the Demand Side Subcommittee is summarized. The panel discussed customers' growing needs for electrical services with different levels of quality and utilities' response to this change in the market. Panel members included a consumer, technical experts, and marketing experts. The discussion is particularly important to utility personnel and marketing professionals interested in marketing solutions to power quality problems     

Power relinquishment versus power sharing: Theoretical clarification and empirical comparison of delegation and participation.

This article presents a theoretical and empirical comparison of delegation and participation. Although the two processes have sometimes been treated as interchangeable, delegation and participation have evolved from two different theoretical perspectives and are used by managers under different sets of conditions. Two studies are reported that examined these differences. The experimental study examined situational factors in Vroom and Yetton's (1973) leadership model that predict differences in managers' reported preferences for delegation or participation. Results indicated that decision importance, subordinate information, and subordinate goal congruence explained 23% of the variance in managers' preferences. The correlational study examined similar situational predictors of supervisors' reported use of delegation and participation with subordinates. These results largely confirmed the findings of the experimental study and also showed supervisor workload as a significant predictor. In addition, objective measures of subordinate performance significantly correlated with the use of delegation but not with participation. The implications of the findings for research on participative decision making are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Rethinking downstream regulation: California's opportunity to engage households in reducing greenhouse gases

With the passage of the Global Warming Solutions Act of 2006 (AB32), California has begun an ambitious journey to reduce in-state GHG emissions to 1990 levels by 2020. Under the direction of executive order S-20-06, a mandated Market Advisory Committee (MAC) charged with studying market-based mechanisms to reduce GHG emissions, including cap and trade systems, has recommended taking an “upstream” approach to GHG emissions regulation, arguing that upstream regulation will reduce administrative costs because there are fewer agents. In this paper, we argue that, the total costs to society of a GHG cap and trade scheme can be minimized though downstream regulation, rather than the widely proposed upstream approach. We propose a household carbon trading system with four major components: a state allocation to households, household-to-household trading, households to utility company credit transfers, and utility companies to government credit transfers. The proposed system can also be considered more equitable than carbon taxes and upstream cap and trade systems to control GHG emissions from residential energy use and is consistent with AB32.