全文获取类型
收费全文 | 840篇 |
免费 | 81篇 |
国内免费 | 1篇 |
学科分类
工业技术 | 922篇 |
出版年
2024年 | 2篇 |
2023年 | 17篇 |
2022年 | 4篇 |
2021年 | 29篇 |
2020年 | 21篇 |
2019年 | 32篇 |
2018年 | 36篇 |
2017年 | 32篇 |
2016年 | 51篇 |
2015年 | 26篇 |
2014年 | 51篇 |
2013年 | 56篇 |
2012年 | 77篇 |
2011年 | 66篇 |
2010年 | 69篇 |
2009年 | 40篇 |
2008年 | 49篇 |
2007年 | 33篇 |
2006年 | 24篇 |
2005年 | 22篇 |
2004年 | 20篇 |
2003年 | 21篇 |
2002年 | 12篇 |
2001年 | 11篇 |
2000年 | 13篇 |
1999年 | 11篇 |
1998年 | 14篇 |
1997年 | 15篇 |
1996年 | 11篇 |
1995年 | 8篇 |
1994年 | 9篇 |
1993年 | 7篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 6篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1984年 | 3篇 |
排序方式: 共有922条查询结果,搜索用时 156 毫秒
1.
First principles computational studies of spontaneous reduction reaction of Eu(III) in eutectic LiCl‐KCl molten salt 下载免费PDF全文
Using first principles calculations, we study fundamental mechanism of spontaneous reduction reaction of Eu3+ to Eu2+ in eutectic LiCl‐KCl molten salt. We decouple the reaction Gibbs free energy into enthalpy and entropy contributions by using rigorous thermodynamic formalism. Key structural features of the solvation shell are characterized by the radial distribution function and the coordination number. Compared with Eu2+, the Eu3+ ion has a more rigid framework of the solvation shells, corroborating its stronger electrostatic interaction with neighboring ligands of Cl? ions and a more favorable state on the aspect of enthalpy. Computations on vibrational frequency, however, pose significant contribution of vibrational entropy to the reaction Gibbs free energy for the reduction. Vibration frequency of Eu2+ is smaller than that of Eu3+, driving a more positive change of the entropy in the reduction reaction. Furthermore, an Eu2+ diffuses more quickly than an Eu3+ in the LiCl‐KCl molten salt with switching mechanism of ligand Cl? ions in the solvation shell. Our results propose that the spontaneity of the reduction reaction is driven by the entropic contribution by overcoming the penalty of the reaction enthalpy. 相似文献
2.
Kim Moon-Won Noh Seung-Yoon Zahir Muhammad Zeeshan Yook Se-Jin 《Journal of Mechanical Science and Technology》2021,35(5):2229-2236
Journal of Mechanical Science and Technology - In this study, the performance of a zigzag type mist eliminator with drainage channels was improved using slit plates. The collection efficiency of... 相似文献
3.
Yong Xu Yun Li Songlin Li Francis Balestra Gerard Ghibaudo Wenwu Li Yen‐Fu Lin Huabin Sun Jing Wan Xinran Wang Yufeng Guo Yi Shi Yong‐Young Noh 《Advanced functional materials》2020,30(20)
Unreliable mobility values, and particularly greatly overestimated values and severely distorted temperature dependences, have recently hampered the development of the organic transistor field. Given that organic field‐effect transistors (OFETs) have been routinely used to evaluate mobility, precise parameter extraction using the electrical properties of OFETs is thus of primary importance. This review examines the origins of the various mobilities that must be determined for OFET applications, the relevant extraction methods, and the data selection limitations, which help in avoiding conceptual errors during mobility extraction. For increased precision, the review also discusses device fabrication considerations, calibration of both the specific gate‐dielectric capacitance and the threshold voltage, the contact effects, and the bias and temperature dependences, which must actually be handled with great care but have mostly been overlooked to date. This review serves as a systematic overview of the OFET mobility extraction process to ensure high precision and will also aid in improving future research. 相似文献
4.
Noh Seung-Yoon Park Duckshin Yook Se-Jin 《Journal of Mechanical Science and Technology》2021,35(1):371-379
Journal of Mechanical Science and Technology - Fences and air curtains can effectively reduce fine dust entry into roadside bus structures, thus decreasing the exposure of passengers to particulate... 相似文献
5.
Adem Sreedhar I. Neelakanta Reddy Qui Thanh Hoai Ta Gitae Namgung Eunbin Cho Jin-Seo Noh 《Ceramics International》2019,45(6):6985-6993
In this paper, novel morphology correlation between silver nanowires (AgNWs) and cobalt (Co)-doped ZnO (Co-ZnO) flake-like thin films (nanowire/flake-like) has been proposed for enhanced photoelectrochemical (PEC) water splitting activity. Here in, high-quality AgNWs/Co-ZnO heterostructures enabled superior visible light water splitting activity compared to the pure ZnO and AgNWs/ZnO. To address the strategic effect of AgNWs coupling and transition metal (Co-2?at%) doping into the ZnO host lattice, we have carried out the X-ray diffraction, field emission scanning microscopy, X-ray photoelectron spectroscopy, UV–Vis transmittance, water contact angle and PEC analyses. In this way, PEC water splitting activity was mainly examined by linear sweep voltammetry (I-V), amperometric I-t and photoconversion efficiency (η) studies. The experimental results provide clear evidence of morphology correlation between AgNWs and Co-ZnO flake-like structures for strong visible light absorption. Specifically, AgNWs/Co-ZnO composites exhibited significant enhancement in the photocurrent density (7.0?×?10?4 A/cm2) than AgNWs/ZnO (3.2?×?10?4 A/cm2) and pure ZnO (1.5?×?10?6 A/cm2). As a result, detailed AgNWs/Co-ZnO geometry has great potential for photoconversion efficiency (0.73%). In a word, the merits of controllable AgNWs/Co-ZnO heterostructure are proposed to improve the visible light harvesting and charge carrier generation for energy conversion devices. 相似文献
6.
7.
Gelation and crosslinking characteristics of photopolymerized poly(ethylene glycol) hydrogels 下载免费PDF全文
The gelation and crosslinking features of poly(ethylene glycol) (PEG) hydrogels were scrutinized through the UV polymerization processes of poly(ethylene glycol) methacrylate (PEGMA) and poly(ethylene glycol) dimethacrylate (PEGDMA) mixtures. The real‐time evolutions of the elastic moduli of the prepolymerized mixtures with different crosslinking ratios of PEGMA and PEGDMA and the photoinitiator concentrations were measured during photopolymerization. The rheological properties were compared with other properties of the PEG hydrogels, including the relative changes in the C?C amounts in the mixtures before and after UV irradiation, water swelling ratio, gel fraction, mesh size, and mechanical hardness. As the portion of PEGDMA as a crosslinker increased, the final elastic modulus and gel fraction increased, whereas the swelling ratio and scratch penetration depth at the hydrogel film surface decreased because of the formation of compact networks inside the hydrogels. These results indicate that there was a good correlation between the rheological analysis for predicting the crosslinking transition during photopolymerization and the macroscopic properties of the crosslinked hydrogels. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41939. 相似文献
8.
“Multipoint Force Feedback” Leveling of Massively Parallel Tip Arrays in Scanning Probe Lithography 下载免费PDF全文
Hanaul Noh Goo‐Eun Jung Sukhyun Kim Seong‐Hun Yun Ahjin Jo Se‐Jong Kahng Nam‐Joon Cho Sang‐Joon Cho 《Small (Weinheim an der Bergstrasse, Germany)》2015,11(35):4526-4531
Nanoscale patterning with massively parallel 2D array tips is of significant interest in scanning probe lithography. A challenging task for tip‐based large area nanolithography is maintaining parallel tip arrays at the same contact point with a sample substrate in order to pattern a uniform array. Here, polymer pen lithography is demonstrated with a novel leveling method to account for the magnitude and direction of the total applied force of tip arrays by a multipoint force sensing structure integrated into the tip holder. This high‐precision approach results in a 0.001° slope of feature edge length variation over 1 cm wide tip arrays. The position sensitive leveling operates in a fully automated manner and is applicable to recently developed scanning probe lithography techniques of various kinds which can enable “desktop nanofabrication.” 相似文献
9.
A Highly Planar Fluorinated Benzothiadiazole‐Based Conjugated Polymer for High‐Performance Organic Thin‐Film Transistors 下载免费PDF全文
10.