The Einstein relation in nanostructured materials: simplified theory and suggestion for experimental determination

An attempt is made to study the Einstein relation for the diffusivity–mobility ratio (DMR) in quantum wells (QWs) and quantum well wires (QWWs) of tetragonal compounds on the basis of a newly formulated electron energy spectrum taking into account the combined influences of the anisotropies in effective electron mass, the spin–orbit splitting, and the presence of crystal field splitting, respectively. The results for quantum-confined III–V compounds form a special case of our generalized analysis. The DMR has also been studied for QWs and QWWs of II–VI and IV–VI materials. Taking QWs and QWWs of CdGeAs₂, InAs, CdS and PbSe as examples, it was found that the DMR increases with increasing carrier statistics and decreasing film thickness respectively in various oscillatory manners emphasizing the influence of dimensional quantizations and the energy band constants in different cases. An experimental method of determining the DMR in nanostructures with arbitrary dispersion laws has also been suggested and the present simplified analysis is in agreement with the suggested relationship. The well-known results for nanostructures with parabolic energy bands have also been obtained as special cases from this generalized analysis under certain limiting conditions.     

Fatty acids from Macoma sp. of bivalve mollusc

Fatty acids of the total lipids of flesh and hepatopancreas of Macoma sp. have been determined. The level of 20:5w3 (ca 17%), a biologically important fatty acid, was found to be considerably high. Other major component fatty acids were 16:0, 16:1, 18:1 and 22:4w6. High levels of 22:5w6 (8%), 22:5w3 (8%) and 22:6w3 (ca 15%) were found in flesh lipid. Nonsaponifiables were also high (28–30%). Alkyl ether acyl glycerols were found in flesh (1.3%) and hepatopancreas (3.8%).     

Cisapride reduces neonatal postoperative ileus: randomised placebo controlled trial

AIM: To assess the efficacy of cisapride in reducing ileus persisting to the tenth postoperative day after neonatal abdominal surgery. METHODS: A prospective, randomised, double blind trial comparing rectal cisapride (1.4-2.3 mg/kg/day) with placebo over seven days was undertaken in 33 neonates. RESULTS: Seven of 12 (58%) patients receiving placebo and eight of 11 (73%) receiving cisapride achieved a first sustained feed during treatment. Of those receiving cisapride, the first sustained feed occurred at 2.3 days (SEM 0.6) compared with 4.7 days (SEM 0.8) with placebo. By the seventh day the mean daily net enteral balance was 69 (SEM 18) ml/kg in the cisapride subgroup and 17 (SEM 8) ml/kg for those receiving placebo. Stool was passed on 6.3 (SEM 0.4) treatment days in the cisapride subgroup compared with 4.1 (SEM 1.0) treatment days in the placebo subgroup. CONCLUSION: Cisapride is effective in neonates with a prolonged ileus after abdominal surgery.     

Surface tailoring of an ethylene propylene diene elastomeric terpolymer via plasma‐polymerized coating of tetramethyldisiloxane

In the research presented here, we explore the use of a low‐energy plasma to deposit thin silicone polymer films using tetramethyldisiloxane (TMDSO) (H(CH₃)₂? Si? O? Si? (CH₃)₂H) on the surface of an ethylene propylene diene elastomeric terpolymer (EPDM) in order to enhance the surface hydrophobicity, lower the surface energy and improve the degradation/wear characteristics. The processing conditions were varied over a wide range of treatment times and discharge powers to control the physical characteristics, thickness, morphology and chemical structure of the plasma polymer films. Scanning electron microscopy (SEM) shows that pore‐free homogeneous plasma polymer thin films of granular microstructure composed of small grains are formed and that the morphology of the granular structure depends on the plasma processing conditions, such as plasma power and time of deposition. The thicknesses of the coatings were determined using SEM, which confirmed that the thicknesses of the deposited plasma‐polymer films could be precisely controlled by the plasma parameters. The kinetics of plasma‐polymer film deposition were also evaluated. Contact angle measurements of different solvent droplets on the coatings were used to calculate the surface energies of the coatings. These coatings appeared to be hydrophobic and had low surface energies. X‐ray photoelectron spectroscopy (XPS) and photoacoustic Fourier‐transform infrared (PA‐FT‐IR) spectroscopy were used to investigate the detailed chemical structures of the deposited films. The optimum plasma processing conditions to achieve the desired thin plasma polymer coatings are discussed in the light of the chemistry that takes place at the interfaces. Copyright © 2004 Society of Chemical Industry     

Cellular automaton-based algorithms for the dispersion of mobile wireless sensor networks

Due to the advent of sensor technology and its applications, mobile wireless sensor networks (MWSNs) have gained a significant amount of research interest. In a typical MWSN, sensors can move within the network. We develop a set of probabilistic and deterministic cellular automaton (CA)-based algorithms for motion planning problems in MWSNs. First, we consider a scenario where a group of sensors are deployed and they need to disperse in order to maximise the area covered by the network. In this variant of the problem we do not explicitly consider that the sensors should maintain the connectivity of the network while they move. Second, we consider a scenario where the sensors are initially randomly distributed and they need to disperse autonomously to both maximise the coverage of the network and maintain its connectivity. We carry out extensive simulations of both deterministic and randomised variants of the algorithms. For the first variant of the problem we compare our algorithms with one previous algorithm and find that our algorithm yields better network coverage than the earlier algorithm. We also find that probabilistic algorithms have better overall performance for the second variant. CA algorithms rely only on local information about the network and, hence, they can be used in practice for MWSN problems. On the other hand, locality of the algorithm implies that maintaining connectivity becomes a non-trivial problem.     

Effects of fiber surface grafting by functionalized carbon nanotubes on the interfacial durability during cryogenic testing and conditioning of CFRP composites

Carbon fiber reinforced epoxy (CE) composite is ideal for a cryogenic fuel storage tank in space applications due to its unmatched specific strength and modulus. In this article, inter-laminar shear strength (ILSS) of carbon fiber/epoxy (CE) composite is shown to be considerably improved by engineering the interface with carboxyl functionalized multi-walled carbon nanotube (FCNT) using electrophoretic deposition technique. FCNT deposited fibers from different bath concentrations (0.3, 0.5, and 1.0 g/L) were used to fabricate the laminates, which were then tested at room (30°C) and in-situ liquid nitrogen (LN) (−196°C) temperature as well as conditioning for different time durations (0.25, 0.5, 1, 6, and 12 h) followed by immediate RT testing to study the applicability of these engineered materials at the cryogenic environment. A maximum increment in ILSS was noticed at bath concentration of 0.5 g/L, which was ~21% and ~ 17% higher than neat composite at 30°C and − 196°C, respectively. Short-term LN conditioning was found to be detrimental due to developed cryogenic shock, which was further found to be compensated by cryogenic interfacial clamping upon long-term exposure.     

Bacteria foraging optimization in antenna engineering: An application to array fault finding

Finding fault elements in linear antenna arrays using bacteria foraging optimization (BFO) is presented. One of the better options of array diagnosis is to perform it by measuring the radiated field, because in this case, removal of the array from its working site is not required and thereby not interrupting its normal operation. This task of fault finding from far‐field data is designed as an optimization problem where the difference between the far‐field power pattern obtained for a given configuration of failed element(s) and the measured one is minimized w. r. t. the excitations of the array elements. This set of excitations on comparison with the excitations of the original array gives the idea of the fault position and their type, such as either complete fault or partial fault. BFO being relatively new to microwave community when compared with other soft‐computing techniques, its performance was observed w. r. t. time of computation and convergence of the iterative process. Possibility of finding the faults from random sample points and use of minimum number of sample points for array fault finding are the novelties of the present work. © 2012 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2013.     

Stiction – definition, modelling, detection and quantification

Stiction or high static friction is a common problem in spring-diaphragm type control valves, which are widely used in the process industry. Recently, there have been many attempts to understand, define, model and detect stiction in control valves. There are several methods for detecting stiction, but quantification of the actual amount of stiction still remains a challenge. This paper discusses briefly the definition and modelling of stiction. Then it demonstrates a new method to detect and quantify the actual amount of valve stiction using routine operating data. The proposed method is completely data-driven. No additional excitation or experimentation of the plant is required.     

Multilevel segmentation of Hippocampus images using global steered quantum inspired firefly algorithm

Applied Intelligence - Microscopic Image segmentation has a crucial role in detecting and diagnosing numerous critical diseases like Alzheimer’s disease, Kidney disease, Cancer, many...