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Silicon - Following our interest in exotic silylenes, here we compare and contrast 20 novel five-membered cyclic silylenes, including saturated (sila)0–4 cyclopentasilylenes (1–10) and... 相似文献
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Hamed Safajou Mojgan Ghanbari Omid Amiri Hossein Khojasteh Farzad Namvar Sahar Zinatloo-Ajabshir Masoud Salavati-Niasari 《International Journal of Hydrogen Energy》2021,46(39):20534-20546
Recently, nanocomposite photocatalysts based on semiconductors have attracted much attention due to their suitable bandgap. Combination of tow of several semiconductors can slow down the electron-hole recombination. In this regard, we have depicted an eco-friendly and green fabrication technique to synthesize RGO/Cu nanocomposite by the reduction of graphene oxide and Cu2+ ion utilizing spearmint extract as a reductant and capping agent. The sample was identified by FTIR, XRD, FESEM, EDS, HRTEM, and CV. The results of photocatalytic performance revealed that RGO/Cu is an efficient catalyst for degrading organic pollutants. This compound can eliminate Rhodamine B (RhB) and Methylene blue (MB) 91.0% and 72.0%, respectively. 相似文献
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Rheological,crystal structure,barrier, and mechanical properties of PA6 and MXD6 nanocomposite films
Maryam Fereydoon Seyed H. Tabatabaei Abdellah Ajji 《Polymer Engineering and Science》2014,54(11):2617-2631
In this study, rheological, crystal structure, barrier, and mechanical properties of polyamide 6 (PA6), poly(m‐xylene adipamide) (MXD6) and their in situ polymerized nanocomposites with 4 wt % clay were studied. The extent of intercalation and exfoliation as well as type of crystals, crystallinity, and thermal transitions were investigated using X‐ray diffraction (XRD) and differential scanning calorimetry (DSC), respectively. Dynamic rheological measurements revealed that incorporation of nanoclay significantly increases complex viscosity of MXD6 nanocomposites at low frequencies, which was related to the formation of a nanoclay network and exchange reaction between MXD6 chains. The comparative study of dynamic characteristics (G′ (ω) and G″ (ω)) for aliphatic and aromatic polyamide nanocomposites with their neat resins as well as the relaxation spectra for both polymer systems confirmed the possibility of the aforementioned phenomena. Although, the crystallinity of MXD6 films was lower as compared to PA6 films, the permeability to oxygen was more than 5 times better for the former. Incorporating 4 wt% clay enhanced the barrier property, tensile modulus, and yield stress of PA6 and MXD6 nanocomposite films in both machine and transverse directions without sacrificing much puncture and tear resistances. The PA6‐based films showed higher tear and puncture strength as compared to MXD6 films. POLYM. ENG. SCI., 54:2617–2631, 2014. © 2013 Society of Plastics Engineers 相似文献
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Mojgan Goudarzi Mehdi Mousavi-Kamazani Masoud Salavati-Niasari 《Journal of Materials Science: Materials in Electronics》2017,28(12):8423-8428
In present study, for the first time, ZnO nanoparticles have been synthesized via a simple, novel, solvent and template free solid-state thermal decomposition of the mixed Zn(NO3)·6H2O and cochineal powders as a novel starting reagent at 600?°C for 3 h. The as-prepared product was analyzed by XRD, EDS, SEM, TEM, FT-IR and DRS. Besides, the effect of cochineal powder on the morphology and particle size of ZnO nanoparticles was investigated. The results exhibited that cochineal powder prevents the sintering of nanoparticles and leads to formation of uniform particles. Moreover, the efficiency of ZnO nanoparticles as a photocatalyst for the decolorization of methylene orange (MO) has been evaluated and 90% degradation of MO was obtained after 120 min. 相似文献
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Hesam Ghasemi Pierre J. Carreau Musa R. Kamal Seyed H. Tabatabaei 《Polymer Engineering and Science》2012,52(2):420-430
Polyethylene terephthalate (PET) nanocomposite films were prepared by cast extrusion followed by uniaxial stretching, using chill rolls. Transmission electron microscopy (TEM) and wide angle X‐ray diffraction (WAXD) showed that the clay layers were aligned in the machine direction (MD) in the PET/clay nanocomposite (PCN) films. Differential scanning calorimetry (DSC) showed that PCN films have higher crystallinity than the neat PET films, possibly due to the nucleating role of the silicate layers. The PCN films became hazier as the clay content increased, but the film transparency remained in the acceptable range. Oxygen permeability of the PCN films decreased by 23% compared to the neat PET film. This is comparable with predictions of models proposed in the literature. Silicate incorporation brought about 20% increase in the tensile modulus, while the puncture and tear propagation resistance were reduced, due to brittleness of the PCN films. The measured modulus (1.7 GPa) was somewhat smaller than the values predicted using the Pseudoinclusion model (2.1 GPa). POLYM. ENG. SCI., 2012. © 2011 Society of Plastics Engineers 相似文献