Optimal temperature policies for catalytic transport reactors under periodic operation

The influence of inlet gas concentration cycling on the optimal temperature policy of catalytic transport reactors is studied theoretically. The model considered is based on plug flow of gas and catalyst particles with negligible interand intra-particle diffusional resistances and concentration dependent deactivation kinetics. To utilise the concentration of the reactant and the activity of the deactivating catalyst fully a proper temperature sequence along the reactor is needed. Thus, a general optimal temperature policy using the continuous minimum principle is derived for the reactor under periodic operation. The model equations are solved analytically for gas concentration, activity and temperature profiles. Resonance behaviour (maximum in conversion with pulse width) is obtained using the optimal temperature policy for certain sets of parameters. The effects of activation energy groups, reaction and deactivation constant groups and inlet temperature on the optimal temperature policy under periodic operation are evaluated. In all cases an improvement in conversion with the optimal temperature policy under periodic operation over that with an isothermal policy under periodic operation is obtained. A suboptimal policy, comprising constant temperature over different reactor sections, which is useful for implementation purposes is also discussed.     

Fine grinding of silicon wafers: a mathematical model for the chuck shape

Fine grinding of silicon wafers is a patented technology to manufacture super flat semiconductor wafers cost-effectively. Two papers on fine grinding were previously published in this journal, one discussed its uniqueness and special requirements, and the other presented the results of a designed experimental investigation. As a follow up, this paper presents a study aiming at overcoming one of the technical barriers that have hindered the widespread application of this technology, namely, the difficulty and uncertainty in chuck preparation. Although the chuck shape is critically important in fine grinding, there are no standard procedures for its preparation. Furthermore, the information on the relation between the set-up parameters and the resulting chuck shape is not readily available. In this paper, a mathematical model for the chuck shape is first developed. Then the model is used to predict the relations between the chuck shape and the set-up parameters. Finally, the results of the pilot experiments to verify the model are discussed.     

MELOC-X: extended memory and location optimized caching for large mobile ad hoc networks of UAVs

Effective caching in mobile ad hoc network increases data availability. However, caching at strategic locations with reduced (controlled) number of copies is needed for many military applications involving UAVs to address security concerns, less maintenance overhead and maintaining availability. In general, existing cooperative caching approaches are deficient in finding the reduced number of strategic cache locations. One such technique to reduce the number of strategic cache locations without affecting the efficacy of data access for a small network topology of UAVs is called “memory and location optimized caching scheme (MELOC)”. However, having a single broker and metadata broadcast across the whole network in MELOC lead to severe performance hindrance in case of a large network topology of UAVs. Moreover, frequent cache replacements due to a change in network topology do not favor cache hit and bandwidth conservation in case of large mobile networks consisting of UAVs. In this paper, we design and evaluate an extended version of “MELOC called MELOC-X”, which suits large network topologies of UAVs by overcoming the above challenges. Our comparison with one such recent scheme with similar objectives showcased a significant improvement in performance. We also evaluate the impact of this scheme with respect to different metrics including the average number of hops, the average roundtrip time (i.e., average query latency), cache hits and mobility to access cached data through extensive simulations.     

POLYBiNN: Binary Inference Engine for Neural Networks using Decision Trees

Journal of Signal Processing Systems - Convolutional Neural Networks (CNNs) and Deep Neural Networks (DNNs) have gained significant popularity in several classification and regression applications....     

On the Corrosion Performance of Monel 400 in Molten LiCl-Li2O-Li at 923 K

Metallurgical and Materials Transactions A - The corrosion resistance of a Ni-Cu alloy, Monel 400, in molten LiCl-Li2O-Li at 923 K (650 °C) was investigated. Exposure testing...     

Graphene oxide reinforced polyvinyl alcohol/polyethylene glycol blend composites as high-performance dielectric material

Novel flexible dielectric composites composed of polyvinyl alcohol (PVA), polyethylene glycol (PEG), and graphene oxide (GO) with high dielectric constant and low dielectric loss have been developed using facile and eco-friendly colloidal processing technique. The structure and morphology of the PVA/PEG/GO composites were evaluated using Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, UV-vis spectroscopy (UV-vis), X-ray diffraction (XRD), scanning electron microscopy (SEM), and atomic force microscopy (AFM). The dielectric behavior of PVA/PEG/GO composites was investigated in the wide range of frequencies from 50 Hz to 20 MHz and temperature in the range 40 to 150 °C using impedance spectroscopy. The dielectric constant for PVA and PVA/PEG (50/50) blend film was found to be 10.71 (50 Hz, 150 °C) and 31.22 (50 Hz, 150 °C), respectively. The dielectric constant for PVA/PEG/GO composite with 3 wt% GO was found to be 644.39 (50 Hz, 150 °C) which is 60 times greater than the dielectric constant of PVA and 20 times greater than the dielectric constant of PVA/PEG (50/50) blend film. The PVA/PEG/GO composites not only show high dielectric constant but also show low dielectric loss which is highly attractive for practical applications. These findings underline the possibilities of using PVA/PEG/GO composites as a flexible dielectric material for high-performance energy storage applications such as embedded capacitors.     

Ventricular myxoma presenting as acute visual loss

We report a case of left ventricular myxoma with embolization to the left posterior cerebral artery, causing acute visual loss. The tumor was successfully resected and a follow-up echocardiography after 21 months revealed no evidence of tumor recurrence. The patient also had a past history of testicular seminoma. We believe that this is the first case report of an association of cardiac myxoma and testicular seminoma.     

Cyanate Ester-Based Encapsulation Material for High-Temperature Applications

Cyanate ester resin-based composite materials have been proposed as potential encapsulants for high-temperature applications. The objective of this study is to develop a cyanate ester-based encapsulant, which can also serve as a flip-chip underfill as well as for traditional encapsulation. Two different materials, quartz and alumina fillers, have been studied. The impact of shapes and sizes of the fillers on the overall thermomechanical properties has been investigated. The adhesion strengths of the materials to the ceramic substrate, Kovar lid, and silicon die have also been characterized. The modulus of the resin and the shape of the fillers play a pivotal role in minimizing thermal stress, generated by coefficient of thermal expansion mismatches. Smaller filler particles were found to have better adhesion to the cyanate ester resin. The high-temperature performance of the cyanate ester-based encapsulants was evaluated by thermal aging at 300°C for up to 500 h.