Performance of a CO2 sorbent for indoor air cleaning applications: Effects of environmental conditions,sorbent aging,and adsorption of co-occurring formaldehyde

Indoor air cleaning systems that incorporate CO₂ sorbent materials enable HVAC load shifting and efficiency improvements. This study developed a bench-scale experimental system to evaluate the performance of a sorbent under controlled operation conditions. A thermostatic holder containing 3.15 g sorbent was connected to a manifold that delivered CO₂-enriched air at a known temperature and relative humidity (RH). The air stream was also enriched with 0.8-2.1 ppm formaldehyde. The CO₂ concentration was monitored in real-time upstream and downstream of the sorbent, and integrated formaldehyde samples were collected at different times using DNPH-coated silica cartridges. Sorbent regeneration was carried out by circulating clean air in countercurrent. Almost 200 loading/regeneration cycles were performed in the span of 17 months, from which 104 were carried out at reference test conditions defined by loading with air at 25°C, 38% RH, and 1000 ppm CO₂, and regenerating with air at 80°C, 3% RH and 400 ppm CO₂. The working capacity decreased slightly from 43-44 mg CO₂ per g sorbent to 39-40 mg per g over the 17 months. The capacity increased with lower loading temperature (in the range 15-35°C) and higher regeneration temperature, between 40 and 80°C. The CO₂ capacity was not sensitive to the moisture content in the range 6-9 g/m³, and decreased slightly when dry air was used. Loading isothermal breakthrough curves were fitted to three simple adsorption models, verifying that pseudo-first-order kinetics appropriately describes the adsorption process. The model predicted that equilibrium capacities decreased with increasing temperature from 15 to 35°C, while adsorption rate constants slightly increased. The formaldehyde adsorption efficiency was 80%-99% in different cycles, corresponding to an average capacity of 86 ± 36 µg/g. Formaldehyde was not quantitatively released during regeneration, but its accumulation on the sorbent did not affect CO₂ adsorption.     

Characterization of nitrogen-fixing cyanobacteria in the Brazilian Amazon floodplain

The diversity of the free-living nitrogen-fixing cyanobacterial community in the floodplain sediments along the Solimões and Amazon Rivers and some of their tributaries (Japurá, Negro and Madeira) was investigated. Five cyanobacterial genera were morphologically identified, four of which (Nostoc, Calothrix, Cylindrospermum and Fischerella) have not previously been isolated from the Brazilian Amazon floodplain. Nostoc strains were the most commonly found heterocyst-forming cyanobacteria. Five strains (N. muscorum CENA18 and CENA61, N. piscinale CENA21, Cylindrospermum sp. CENA33 and Fischerella sp. CENA19) were selected for growth measurement, ability to fix N₂ and phylogenetic analysis, based on their widespread distribution and morphological distinction. Molecular analyses employing 16S rRNA sequences indicated that some of the isolates may represent novel cyanobacterial species. Dinitrogen fixed by these strains was measured indirectly as acetylene reduction activity and ranged from 11.5 to 22.2 nmol C₂H₄ μg Chl a⁻¹ h⁻¹. These results provide evidence of widespread and importance of nitrogen-fixing cyanobacteria as a source of N inputs in the Amazonian ecosystem.     

MODELLING THE IMPACTS OF DOMESTIC WATER CONSERVATION ON THE SUSTAIN ABILITY OF THE URBAN SEWERAGE SYSTEM

A computer model was developed to evaluate the impact of various technologies for water conservation in domestic households, in terms of the Impact on the operation of downstream infrastructure. These technologies, which include (a) low-flush toilets, (b) greywater re-use, and (c) re-use of rainwater from roof runoff for toilet flushing, were compared using indicators of sustainability to measure water consumption, sewerage-system operational performance and process treatment efficiency. The results demonstrated that rainwater re-use is potentially the most sustainable strategy in terms of the benefits associated with water conservation and reduction in sewage discharges from combined-sewer overflows (CSOs). The benefits were observed without the problems associated with increased sedimentation in sewers during dry weather, associated with other water-conservation strategies such as reduced-flush toilets, greywater re-use and the resultant increase in pollutants from CSOs during wet weather.     

Intersections of inequality in homeownership in Sweden

Abstract

Inequalities relating to ownership of housing have become a major issue de jour in many Western societies. This article examines how the distribution of homeownership in Sweden relates to two factors widely seen as significant to such inequalities, namely parental tenure status and place of birth. We use longitudinal registry data to examine the bearing of these two factors on individual-level tenure progression since the beginning of the 1990s for persons at different stages of their housing careers. We extend existing understandings of Swedish homeownership patterns by demonstrating that inequalities relating to place of birth and parental tenure intersect with one another in ways that substantially advantage certain subgroups while disadvantaging others, and by demonstrating that experiences of entry into homeownership have in recent years been changing in markedly different ways for these different subgroups. Overall, Swedish homeownership inequalities, far from dissipating, appear to be hardening along existing lines.     

A simplified model for estimating population-scale energy impacts of building envelope air tightening and mechanical ventilation retrofits

Changing the air exchange rate of a home affects the annual thermal conditioning energy. Large-scale changes to air exchange rates of the housing stock can significantly alter the residential sector's energy consumption. However, the complexity of existing residential energy models is a barrier to the accurate quantification of the impact of policy changes on a state or national level. The Incremental Ventilation Energy (IVE) model introduced here combines the output of simple air exchange models with a limited set of housing characteristics to estimate the associated change in energy demand of homes. The IVE model was designed specifically to enable modellers to use existing databases of housing characteristics to determine the impact of ventilation policy change on a population scale. The IVE model estimates of energy change when applied to US homes with limited parameterization are shown to be comparable to the estimates of a well-validated, complex residential energy model.     

Exploring scenarios for the future of energy management in UK property

The most appropriate responses to the energy management of buildings from now until 2050 are investigated through a process of scenario planning. A qualitative, explorative approach was undertaken to develop four 2050 scenario end-states resulting from an axis of two critical uncertainties not closely correlated: the attitudes of society towards sustainability; and the availability of energy. These scenarios were applied to the property industry through expert workshops, from which trends and themes were identified. The findings are that the property industry should prepare for a transitional period with an uncertain outlook. Therefore, it would be prudent for this industry to focus on resilient performance under a diverse set of futures, and plausible shock events, rather than optimizing for today's conditions. This could be challenging in a sector that works on relatively long time scales. Aspects that should be incorporated into property industry strategy are suggested: responding to the potential effects of climate change; understanding what drives communities and investing in buildings that are significant to the community's functions; considering transport links as key to successful property investments; adopting the latest technological innovations; and becoming more ‘full service’ and interdisciplinary. A need for a paradigm shift in the industries' practices was also identified.

Les réponses les plus appropriées à la gestion énergétique des bâtiments d'ici 2050 sont étudiées en ayant recours à un processus de planification par scénarios. Une approche qualitative exploratrice a été adoptée afin de développer quatre conclusions de scénario pour 2050, résultant d'un axe formé par deux incertitudes cruciales qui ne sont pas étroitement corrélées: les attitudes de la société envers la durabilité et la disponibilité de l'énergie. Ces scénarios ont été appliqués à l'industrie de l'immobilier par l'intermédiaire d'ateliers d'experts, grâce auxquels des tendances et des thèmes ont été identifiés. Il en ressort que l'industrie de l'immobilier devrait se préparer à une période de transition offrant des perspectives incertaines. En conséquence, il serait prudent que cette industrie concentre ses efforts sur le maintien de solides performances face à différents avenirs possibles, et à des évènements chocs plausibles, plutôt que sur une optimisation par rapport aux conditions d'aujourd'hui. Ceci pourrait être difficile dans un secteur qui travaille sur des échelles de temps relativement longues. Il est suggéré des aspects qui devraient être intégrés à la stratégie de l'industrie de l'immobilier: répondre aux effets potentiels du changement climatique; comprendre ce qui constitue le moteur des collectivités et investir dans des bâtiments qui soient significatifs pour les fonctions de la collectivité; considérer les liaisons de transport comme essentielles pour des investissements immobiliers réussis; adopter les dernières innovations technologiques; et devenir davantage « un service complet » et interdisciplinaire. A également été identifiée la nécessité d'un changement de paradigme dans les pratiques des industries.

bâtiments, gestion énergétique, planification future, secteur de l'immobilier, résilience, scénarios, incertitude     

Equivalent linear limit states

The replacement of any limit state function by an equivalent linear function is discussed in detail and it is shown that there are several methods by which such an equivalence may be established. In the case of multiple failure mode problems the definition of fully equivalent linear functions requires the additional consideration of mode correlations. The manner in which this may be carried out is discussed and it is shown that, for most practical cases, a relatively simple analysis is likely to be sufficient to define the set of equivalent linear limit states, with the advantage that the established theory of such linear limit states may then be employed in the majority of reliability analyses.