Dealumination–aging pattern of REUSY zeolites contained in fluid cracking catalysts

The evolution of the properties of a REUSY zeolite contained in a fluid cracking catalyst was investigated under laboratory steam deactivation procedures and in age fractions of the corresponding equilibrium catalyst (Ecat). The aging pattern, defined by the evolution of the zeolite surface area (ZSA) related to the decrease of the unit cell size (UCS), was similar between lab-steamed zeolites and Ecat fractions. A sharp drop in ZSA occurred at ca. 2.430 nm UCS. A study done by FT-IR spectroscopy suggested that zeolite dealumination initially took place more extensively on the sodalite cages and double six-member rings (D6R) of the structure and that the final collapse of the zeolite framework occurred through destruction of the 12-member rings (12M). This can be explained by a crystal fracture and break down process and disassembling of the sodalite cages in the faujasite structure. NH₃ microcalorimetry showed that strong acid sites in faujasites are destroyed by steam aging, but this effect does not lead to a reduction in the cracking activity of the Ecat form. The microactivity test (MAT) showed that the specific activity declined sharply at 2.430 nm UCS. Differences in product selectivity were related to the extent of damage of the zeolite, extra-framework alumina and mesoporosity. While further aging canceled the effect attributed to extra-framework alumina differences attributed to mesoporosity increased.     

The Intellectual Development of Science and Engineering Students. Part 2: Teaching to Promote Growth

As college students experience the challenges of their classes and extracurricular activities, they undergo a developmental progression in which they gradually relinquish their belief in the certainty of knowledge and the omniscience of authorities and take increasing responsibility for their own learning. At the highest developmental level normally seen in college students (which few attain before graduation), they display attitudes and thinking patterns resembling those of expert scientists and engineers, including habitually and skillfully gathering and analyzing evidence to support their judgments. This paper proposes an instructional model designed to provide a suitable balance of challenge and support to advance students to that level. The model components are (1) variety and choice of learning tasks; (2) explicit communication and explanation of expectations; (3) modeling, practice, and constructive feedback on high‐level tasks; (4) a student‐centered instructional environment; and (5) respect for students at all levels of development.     

Use of X-ray computed microtomography to understand why gels reduce relative permeability to water more than that to oil

X-ray computed microtomography (XMT) was used to investigate why gels reduce relative permeability to water more than that to oil in strongly water-wet Berea sandstone. XMT allows saturation differences to be monitored for individual pores during various stages of oil, water, and gelant flooding. The method also characterizes distributions of pore size, aspect ratio, and coordination number for the porous media. We studied a Cr(III) acetate–HPAM gel that reduced permeability to water (at S_or) by a factor 80–90 times more than that to oil (at S_wr). In Berea, the gel caused disproportionate permeability reduction by trapping substantial volumes of oil that remained immobile during water flooding (i.e., 43.5% S_or before gel placement versus 78.7% S_or after gel placement). With this high trapped oil saturation, water was forced to flow through narrow films, through the smallest pores, and through the gel itself. In contrast, during oil flooding, oil pathways remained relatively free from constriction by the gel.     

Introduction to the special section on racial and ethnic identity in counseling psychology: Conceptual and methodological challenges and proposed solutions.

Racial and ethnic identity development have been important topics in counseling psychology research for the last four decades. At present, however, there appears to be some confusion and debate regarding the quality of theory and measurement in the topical area. The present article serves as an introduction to this Journal of Counseling Psychology special section on "Racial and Ethnic Identity in Counseling Psychology: Conceptual and Methodological Challenges and Proposed Solutions." A rationale is provided for the special section, the place of racial and ethnic identity scholarship is located within the history of multicultural counseling research, and the invited special section contributions by K. O. Cokley (2007), J. E. Helms (2007), J. E. Trimble (2007), S. M. Quintana (2007), J. S. Phinney and A. D. Ong (2007), and J. G. Ponterotto and J. Park-Taylor (2007) are introduced. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Is evidence-based practice diverse enough? Philosophy of science considerations.

In its policy rationale for evidence-based practice in psychology (EBPP), the APA Presidential Task Force on Evidence-Based Practice (see record 2006-05893-001) claims to have constituted itself with "scientists and practitioners from a wide range of perspectives and traditions, reflecting the diverse perspectives within the field" (p. 273). We applaud this attention to diversity but contend that an entire perspective of the debate was omitted in the Task Force's newly approved policy and its underlying report. The failure to consider a philosophy of science perspective led the Task Force to make a number of epistemological assumptions that are not based on evidence or rationale and that thus violate the very spirit of evidence-based decision making. In this comment, we reveal a few of these assumptions and discuss their detrimental consequences. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Session impact in counseling process research: Comment on Elliott and Wexler (1994) and Stiles et al. (1994).

R. Elliott and M. M. Wexler (see record 1994-27938-001) have introduced the Session Impacts Scale (SIS), and W. B. Stiles et al (see record 1994-27969-001) have undertaken a new factor analysis of the Session Evaluation Questionnaire (SEQ) with a British sample of clients. These 2 measures of session-level psychotherapy effects have great potential as research tools. In this comment on the 2 articles, issues of retest reliability, the connection of session-level measures to research strategies based on other units of analyses, and suggested uses of the SIS and the SEQ are discussed. The importance of context-sensitive session impact research and of a comprehensive theory relating session impacts to therapy outcome is also stressed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Routine Highway Bridge Inspection Condition Documentation Accuracy and Reliability

Routine inspection is the most common form of highway bridge inspection to satisfy the requirements of the National Bridge Inspection Standards. The accuracy and reliability of documentation generated during these inspections are critical to the allocation of Department of Transportation construction, maintenance, and rehabilitation resources. Routine inspections are typically completed using only the visual inspection technique and rely heavily on subjective assessments made by bridge inspectors. In light of this, and given the fact that visual inspection may have other limitations that influence its reliability, the Federal Highway Administration initiated an investigation to examine the reliability of visual inspection as it is currently applied to bridges in the United States. This paper will summarize results from this study related to the accuracy and reliability of routine inspection documentation. A number of important conclusions were developed from the experimental study. Generally, it was found that all structural condition documentation is collected with significant variability. Specifically, 95% of primary element condition ratings for individual bridge components will vary within two rating points of the average and only 68% will vary within one point. Documentation generally collected to support condition ratings also has significant variability as exemplified by the number and types of field notes and photographs taken by inspectors. With respect to the use of element-level inspections, it was found that element usage was generally consistent with the Commonly Recognized Element Guide. However, there is significant variability in the condition state assignments of those elements and in some cases the condition states are not applied correctly to particular elements.     

Numerical methods for colorimetric calculations: Sampling density requirements

This article quantifies errors arising from various integration methods and from sampling density in the numerical estimation of colorimetric integrals, e.g., tristimulus values. Both data sampling density and various numerical integration method errors will be distinguished. A test is presented to quantify sampling interval requirements for accurate colorimetric calculations for various illuminants. © 1992 John Wiley & Sons, Inc.     

Self-efficacy and work-related performance: The integral role of individual differences.

The present study estimated the unique contribution of self-efficacy to work-related performance controlling for personality (the Big 5 traits), intelligence or general mental ability, and job or task experience. Results, based on a meta-analysis of the relevant literatures, revealed that overall, across all studies and moderator conditions, the contribution of self-efficacy relative to purportedly more distal variables is relatively small. Within moderator categories, there were several cases in which self-efficacy made unique contributions to work-related performance. For example, self-efficacy predicted performance in jobs or tasks of low complexity but not those of medium or high complexity, and self-efficacy predicted performance for task but not job performance. Overall, results suggest that the predictive validity of self-efficacy is attenuated in the presence of individual differences, though this attenuation does depend on the context. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Pushing Boundaries in the History of Computing

Crossing topical, analytical, and theoretical boundaries can lead us to more nuanced and satisfying histories of computing, while also providing fresh insights about computing in the contemporary context.