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Wireless Personal Communications - Image transmission from space borne equipment is a challenging task owing to its restrictions on bandwidth and memory requirement. Many of the state of art...  相似文献   
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In the present paper, nanocrystalline hierarchical ZSM-5 zeolites were successfully synthesized by the hydrothermal method in the presence of tetrapropylammonium hydroxide as a single template with the gel composition of 58SiO2:Al2O3:20TPAOH:1,500H2O. The prepared zeolite catalysts were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, Nitrogen adsorption–desorption (BET), scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HR-TEM) techniques. The formation of pure and highly crystalline ZSM-5 zeolite phase is confirmed by XRD. The IR vibration band at 550 cm?1 is assigned to the double 5-rings of MFI-type zeolites. N2 adsorption–desorption isotherms showed that the synthesized product had high BET surface area and possessed composite pore structures with both micro and mesopores. The catalytic performance of hierarchical ZSM-5 zeolite was investigated in the selective oxidation of benzyl alcohol (BzOH) with hydrogen peroxide (H2O2) under mild conditions. The results showed that the conversion of BzOH and the selectivity to benzaldehyde were about 94 and about 99 % respectively, when using 0.08 g ZSM-5 catalyst with acetonitrile as the solvent and H2O2 as the oxidant at 90 °C. This catalyst can be retrieved and reprocessed for five times without a significant loss in its activity and selectivity.  相似文献   
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Modified sulfobetaine bearing tertiary amide spacer between the counterions is synthesized and polymerized by reversible addition–fragmentation chain transfer polymerization technique. The tertiary amide spacer influences various characteristics of the zwitterionic polymer. The modified polyzwitterion, PZI, forms coacervates in deionized water. The coacervates are thoroughly characterized by scanning electron microscopy, transmission electron microscopy, and transmittance studies. The ability to form coacervate complexes with functional ingredients has been demonstrated by encapsulating renewable resource actives like ferulic acid. The coacervate complexes have been studied by optical microscopy, transmission electron microscopy, and automated sunscreen sun protection factor analyzer. Synergism is noticed in the coacervate complex. Because of its ability to form self‐coacervates, this novel addition to the zwitterionic family is potentially useful for encapsulating many functional ingredients through coacervate complex formation. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46178.  相似文献   
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Organic molecular scintillating crystals are noted for their good timing and particle discrimination process. Trans-stilbene is one such candidate noted for its good particle detection characteristics for the past five decades. Progressive strengthening of detection characteristics of trans-stilbene has been attempted by improving crystal perfection. A series of timing resolution studies have been carried out for the Bridgman grown trans-stilbene crystals under different experimental conditions. The results were compared with the previously reported values. Pulse shape discrimination process has been carried out for 241Am and 252Cf sources and good discrimination has been obtained for gamma-alpha and gamma-neutron sources from the grown organic phosphor crystal. Electronic Publication  相似文献   
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The max-min fair scheduling problem in wireless ad-hoc networks is a non-convex optimization problem. A general framework is presented for this optimization problem and analyzed to obtain a dual problem, which involves solving a series of optimization sub-problems. In the limit of infinite bandwidth ( ), the scheduling solution reduces to simultaneous transmission (spread spectrum) on all links (Negi and Rajeswaran, INFOCOM '04 (March 2004)). This motivates the analysis of the scheduling problem in the Ultra Wide Band (UWB) regime ( , but finite), a model for certain practical radios. A quadratic (in 1/W) lower bound to the single link capacity function is developed, which simplifies the dual sub-problem to a quadratic optimization (Negi and Rajeswaran, GLOBECOM '04, (Dec. 2004)). The solution to this sub-problem is then obtained under both total power and power spectral density constraints. This solution is utilized to iteratively construct the schedule (sub-band sizes) and power allocation, thus optimally solving the UWB max-min fair scheduling problem, to within any desired precision. Simulations on medium sized networks demonstrate the excellent performance of this scheme. A cellular architecture (not necessarily UWB) may also be considered in this framework. It is proved that Frequency Division Multiple Access is the optimal scheduling for a multi-band cellular architecture. This work was supported in part by the National Science Foundation under Career award 0347455. Arjunan Rajeswaran received his Masters degree in Electrical and Computer Engineering from Carnegie Mellon University in 2003. Since August 2003, he has been pursuing his doctoral research at Carnegie Mellon. His reserach interests lie in the area of wireless networks. His focus is in the application of information and communication theoretic tools towards wireless network design. Several IEEE publications reflect his curent research on Medium Access Control design and performance. Arjunan received the best student paper award at IEEE/ACM Broadnets 2004. Gyouhwan Kim received his B.S. and M.S. degree in Electronic Engineering from Sogang University in Korea, in 1994 and 1996, respectively. Since 1996, he has been working in the CDMA cellular system development team in Samsung Electronics. Currently, he is also working toward the Ph.D degree in the Department of Electrical and Computer Engineering at Carnegie Mellon University. His main research interests are in wireless networks and communication theory. Rohit Negi received the B.Tech. degree in Electrical Engineering from the Indian Institute of Technology, Bombay, India in 1995. He received the M.S. and Ph.D. degrees from Stanford University, CA, USA, in 1996 and 2000 respectively, both in Electrical Engineering. He has received the President of India Gold medal in 1995. Since 2000, he has been with the Electrical and Computer Engineering department at Carnegie Mellon University, Pittsburgh, PA, USA, where he is an Assistant Professor. His research interests include signal processing, coding for communications systems, information theory, networking, cross-layer optimization and sensor networks.  相似文献   
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Atmospheric Pressure Plasma (APP) is being used widely in a variety of biomedical applications. Extensive research in the field of plasma medicine has shown the induction of DNA damage by APP in a dose-dependent manner in both prokaryotic and eukaryotic systems. Recent evidence suggests that APP-induced DNA damage shows potential benefits in many applications, such as sterilization and cancer therapy. However, in several other applications, such as wound healing and dentistry, DNA damage can be detrimental. This review reports on the extensive investigations devoted to APP interactions with DNA, with an emphasis on the critical role of reactive species in plasma-induced damage to DNA. The review consists of three main sections dedicated to fundamental knowledge of the interactions of reactive oxygen species (ROS)/reactive nitrogen species (RNS) with DNA and its components, as well as the effects of APP on isolated and cellular DNA in prokaryotes and eukaryotes.  相似文献   
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Imidazolium bromide, an ionic liquid surfactant acrylate, as well as its homopolymer and various copolymers are demonstrated to be superior dispersing aids for preparing aqueous multiwall carbon nanotube (MWCNT) dispersions. We demonstrate apparent complete exfoliation in water with extinction coefficients at 500 nm of about 60 cm2 mg−1 of MWCNT dispersed, a new lower bound and the highest reported extinction to date. The efficacy or efficiency of dispersion (activated by ultrasonication) is examined in terms of a quotient of extinction and weight ratio of the active monomer and MWCNT. A rank ordering of the results obtained for seven stabilizers based on the same imidazolium bromide monomer provides insights into roles of π-overlap adsorption onto MWCNT surfaces and how hydrogel properties of some of these polymers provide stability in water at higher concentrations than previously considered feasible for surfactant-stabilized and polymer-stabilized MWCNT dispersions. Simple nanocomposite film formation is demonstrated by casting and thermal diffusivity and electrical conductivity properties are examined.  相似文献   
9.
Effects of aggressive chemical environments were evaluated on the mortars prepared with ordinary portland cement (OPC) and silica fume (SF)/metakaolin (MK)/low-calcium fly ash at various replacement levels. The natural adverse chemical environmental conditions were simulated using sulfuric acid, hydrochloric acid, nitric acid, acetic acid, phosphoric acid, and a mixture of sodium and magnesium sulfates. Chemical resistance information was used in conjunction with compressive strength measurements to propose realistic OPC/mineral admixture proportions.  相似文献   
10.
The work was motivated by the increasing awareness of the need for enhancing water supplies schemes in arid lands featuring an appropriate technology for solar energy use in the desalination field in India. The fresh water crisis is already evident in many parts of India, varying in scale and intensity at different times of the year. India's rapidly rising population and changing lifestyles also increases the need for fresh water. Fresh water is increasingly taking centre stage on the economic and political agenda, as more and more disputes between and within states, districts, regions, and even at the community level arises. The conventional desalination technologies like multi stage flash, multiple effect, vapor compression, iron exchange, reverse osmosis, electro dialysis are expensive for the production of small amount of fresh water, also use of conventional energy sources has a negative impact on the environment. Solar distillation represents a most attractive and simple technique among other distillation processes, and it is especially suited to small-scale units at locations where solar energy is considerable. India, being a tropical country is blessed with plenty of sunshine. The average daily solar radiation varies between 4 and 7 kWh per square meter for different parts of the country. There are on an average 250–300 clear sunny days in a year, thus it receives about 5000 trillion kWh of solar energy in a year. In spite of the limitations of being a dilute source and intermittent in nature, solar energy has the potential for meeting and supplementing various energy requirements. Solar energy systems being modular in nature could be installed in any capacity as per the requirement. This paper consists of an overall review and technical assessments of various passive and active solar distillation developments in India. This review also recommended some research areas in this field leading to high efficiency are highlighted.  相似文献   
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