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在不同的温度和浓度下,在3%硝酸溶液中,利用失重法试验,得到十二烷基磺酸钠在金属锌表面的吸附热力学数据以及其对金属锌的缓蚀作用。结果表明,十二烷基磺酸钠在锌表面进行单分子层吸附,抑制锌腐蚀。温度升高,吸附能力减弱,缓蚀效率下降。对实验数据进行分析,得到相应的焓变、熵变等一系列热力学数值。 相似文献
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Jari Kolehmainen Ali Ozel Christopher M. Boyce Sankaran Sundaresan 《American Institute of Chemical Engineers》2017,63(6):1872-1891
To investigate the interplay between particle charging and hydrodynamics in fluidized beds, models for triboelectric charging and electrostatic forces were built into a computational fluid dynamics‐discrete element method model. Charge transfer was governed by the difference in effective work function between contacting materials as well as the electric field at the point of contact. Monodisperse particles were fluidized with an effective work function difference between the particles and the conducting walls. For smaller work function differences, hydrodynamics were not changed significantly as compared with an uncharged case. In these simulations, the average charge saturated at a value much lower than the value anticipated based on the work function difference, and a unimodal distribution of charges was observed. For larger work function differences, particles stuck to walls and bed height oscillations due to slugging were less pronounced. For these cases, a bimodal distribution of charges emerged due to effects from strong electric fields. © 2016 American Institute of Chemical Engineers AIChE J, 63: 1872–1891, 2017 相似文献
4.
A hybrid approach to computing electrostatic forces in fluidized beds of charged particles 下载免费PDF全文
Jari Kolehmainen Ali Ozel Christopher M. Boyce Sankaran Sundaresan 《American Institute of Chemical Engineers》2016,62(7):2282-2295
In particulate flow devices particles acquire electric charge through triboelectric charging, and resulting electrostatic forces can alter hydrodynamics. To capture this effect, the electrostatic force acting on individual particles in the device should be computed accurately. Electrostatic force is calculated using a hybrid approach consisting of: (1) long‐range contributions from an Eulerian electric field solved using the Poisson equation (2) short‐range contributions calculated using a truncated pairwise sum and (3) a correction to avoid double counting. Euler‐Lagrange simulation of flows incorporating this hybrid approach reveals that bed height oscillations in small fluidized beds of particles with monopolar charge decreases with increasing charge level, which is related to lateral segregation of particles. A ring‐like layer of particles, reported in experimental studies, forms at modestly high charge levels. Beds with equal amounts of positively and negatively charged particles are fluidized in a manner similar to uncharged particles. © 2016 American Institute of Chemical Engineers AIChE J, 62: 2282–2295, 2016 相似文献
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The polycyclic aromatic hydrocarbon (PAH), chrysene, was linked to the solid support TentaGel S-NH2 via a linker by means of synthesis. The resulting product 4-(chrysene-1-yloxy)-N-(TentaGel S)butanamide (4) was then evaluated for its ability to isolate PAHs from solution by means of π-π-interactions. 相似文献
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The oxygenase component of toluene dioxygenase from Pseudomonas putida F1 is an iron-sulfur protein (ISPTOL) consisting of alpha (TodC1) and beta (TodC2) subunits. Purified TodC1 gave absorbance and electron paramagnetic resonance spectra identical to those given by purified ISPTOL. TodC1 was reduced by NADH and catalytic amounts of ReductaseTOL and FerredoxinTOL. Reduced TodC1 did not oxidize toluene, and catalysis was strictly dependent on the presence of purified TodC2. 相似文献
8.
A Brockman RE Paul TJ Anderson I Hackford L Phaiphun S Looareesuwan F Nosten KP Day 《Canadian Metallurgical Quarterly》1999,60(1):14-21
PATIENTS AND METHODS: The role of cerebral magnetic resonance imaging (MRI) in the diagnosis of growth hormone (GH) deficiency in children has been studied in 100 children. The diagnosis of GH deficiency was assessed at a mean age of 6.7 +/- 4.1 years: morphological abnormalities of the hypothalamic-pituitary (HP) region have been studied in three different groups: in the first group (70 cases), the neurohypophysis was present and normally located; in the second group (ten cases) it was missing; in the third group (20 cases) the neurohypophysis was ectopic (truncated stalk syndrome with ectopic neurohypophysis, small antehypophysis, thin or non-visualized stalk). RESULTS: In the majority of cases, children presenting with only one morphological abnormality of the HP region (ectopic neurohypophysis or small antehypophysis or non-visualized or thin stalk) had an isolated GH deficiency. When multiple morphological abnormalities were present, anterior pituitary deficiency was multiple in more than half the cases. Cerebral midline anomalies (above all Chiari I malformation and basipharyngeal canal) had been observed in 20% of the children presenting with GH deficiency. In the majority of cases (95%), these anomalies were associated with one or more abnormalities of the HP region. A familial case is reported: morphological anomalies of the HP region were different for both siblings. Genetic factors are evoked. CONCLUSION: The severity of the hormone deficiency is correlated to the ectopic location of the neurohypophysis, the thin appearance or non visibility of the pituitary stalk and the associated midline anomalies. 相似文献
9.
EA Ratovitski MR Alam RA Quick A McMillan C Bao C Kozlovsky TA Hand RC Johnson RE Mains BA Eipper CJ Lowenstein 《Canadian Metallurgical Quarterly》1999,274(2):993-999
Nitric oxide (NO) acts as a neurotransmitter. However, excess NO produced from neuronal NO synthase (nNOS) or inducible NOS (iNOS) during inflammation of the central nervous system can be neurotoxic, disrupting neurotransmitter and hormone production and killing neurons. A screen of a hippocampal cDNA library showed that a unique region of the iNOS protein interacts with Kalirin, previously identified as an interactor with a secretory granule peptide biosynthetic enzyme. Kalirin associates with iNOS in vitro and in vivo and inhibits iNOS activity by preventing the formation of iNOS homodimers. Expression of exogenous Kalirin in pituitary cells dramatically reduces iNOS inhibition of ACTH secretion. Thus Kalirin may play a neuroprotective role during inflammation of the central nervous system by inhibiting iNOS activity. 相似文献
10.
V Kerekatte BD Keiper C Badorff A Cai KU Knowlton RE Rhoads 《Canadian Metallurgical Quarterly》1999,73(1):709-717
Infection of cells by picornaviruses of the rhinovirus, aphthovirus, and enterovirus groups results in the shutoff of host protein synthesis but allows viral protein synthesis to proceed. Although considerable evidence suggests that this shutoff is mediated by the cleavage of eukaryotic translation initiation factor eIF4G by sequence-specific viral proteases (2A protease in the case of coxsackievirus), several experimental observations are at variance with this view. Thus, the cleavage of other cellular proteins could contribute to the shutoff of host protein synthesis and stimulation of viral protein synthesis. Recent evidence indicates that the highly conserved 70-kDa cytoplasmic poly(A)-binding protein (PABP) participates directly in translation initiation. We have now found that PABP is also proteolytically cleaved during coxsackievirus infection of HeLa cells. The cleavage of PABP correlated better over time with the host translational shutoff and onset of viral protein synthesis than did the cleavage of eIF4G. In vitro experiments with purified rabbit PABP and recombinant human PABP as well as in vivo experiments with Xenopus oocytes and recombinant Xenopus PABP demonstrate that the cleavage is catalyzed by 2A protease directly. N- and C-terminal sequencing indicates that cleavage occurs uniquely in human PABP at 482VANTSTQTM downward arrowGPRPAAAAAA500, separating the four N-terminal RNA recognition motifs (80%) from the C-terminal homodimerization domain (20%). The N-terminal cleavage product of PABP is less efficient than full-length PABP in restoring translation to a PABP-dependent rabbit reticulocyte lysate translation system. These results suggest that the cleavage of PABP may be another mechanism by which picornaviruses alter the rate and spectrum of protein synthesis. 相似文献