ZnO–SnO2 nanocubes for fluorescence sensing and dye degradation applications

ZnO–SnO₂ nanocubes were used as promising material for efficient sensing of p-nitrophenol and faster photocatalytic degradations of dyes like methyl orange (MO), methylene Blue (MB) and acid orange 74 (AO74). ZnO–SnO₂ nanocubes were prepared by the facile solution process at 50 °C using Zn(NO₃)₂·6H₂O and SnCl₂·2H₂O as a precursor in the presence of ethylenediammine. The synthesized material was examined for its morphological, structural, crystalline, optical, vibrational, and compositional studies by using field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Fourier Transform Infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS) and photoluminescence spectroscopy. FESEM studies revealed the formation of well-defined ZnO–SnO₂ nanocubes where the structural examinations revealed the formation of a crystalline tetragonal rutile phase for SnO₂ with some crystal sites doped with Zn. The as-synthesized nanocubes were explored for their photocatalytic activities towards three different dye viz. MO, MB, and AO74. Practically, complete degradation of AO74 was seen within 4 minutes of photo-irradiation in the presence of 0.05 g ZnO–SnO₂ nanocubes. However, 97.17% and 41.63% degradations were observed for MB and MO within 15 and 60 minutes, respectively. All the dye degradation processes followed the pseudo-first-order kinetic model. Moreover, the as-synthesized nanocubes were utilized to fabricate highly sensitive and selective fluorescent chemical sensor for the detection of p-nitrophenol (PNP). ZnO–SnO₂ nanocubes showed a very low detection limit of 4.09 μM for the detection of PNP as calculated according to the 3σ IUPAC criteria. Further, the as-synthesized ZnO–SnO₂ nanotubes were found to be highly selective for p-nitrophenol as compared to the other two isomers.     

Throughput-efficient coalition formation of selfish/altruistic nodes in ad hoc networks: a hedonic game approach

In this paper, we analyze the problem of throughput-efficient distributed coalition formation (CF) of selfish/altruistic nodes in ad hoc radio networks. We formulate the problem as a hedonic CF game with non-transferable utility and propose different preference relations (CF rules) based on individual/group rate improvement of distributed nodes. We develop a hedonic CF algorithm, through which distributed nodes may self-organize into stable throughput-efficient disjoint coalitions. We apply the concept of frequency reuse over different coalitions, such that the members of each coalition will transmit over orthogonal sub-bands with the available spectrum being optimally allocated among them. We study the computational complexity and convergence properties of the proposed hedonic CF algorithm under selfish and altruistic preferences, and present means to guarantee Nash-stability. In addition, we identify the scenarios in which a CF process might lead to instability (CF cycle), and we propose methods to avoid cycles and define different exit procedures if a CF cycle is inevitable. Performance analysis shows that the proposed algorithm with optimal bandwidth allocation provides a substantial gain, in terms of average payoff per link, over existing coalition formation algorithms for a wide SNR range.     

Flow forming of thin-walled precision shells

Flow forming is an innovative form of cold and chipless metal forming process, used for the production of high precision, thin-walled, net-shaped cylindrical components. During this process, the length of a thick walled tube, commonly known as a preform, is increased with a simultaneous decrease in the thickness of the preform without any change in the internal diameter. Forming of the preform is carried out with the help of one or more rollers over a rotating mandrel. By a pre-determined amount of thickness reduction in one or more number of forming passes, the work material is plastically deformed in the radial direction by compression and made to flow in an axial direction. The desired geometry of the workpiece is achieved when the outer diameter and the wall of the preform are decreased, and the available material volume is forced to flow longitudinally over the mandrel. Over the last three and a half decades the flow forming technology has undergone several remarkable advancements. The versatility of the process makes it possible to produce a wide variety of axi-symmetric, nearer to the net-shape tubular parts with a complex profile using minimum tooling changes. In this review article, process details of flow forming have been elaborated. The current state-of-the-art process has been described, and future developments regarding research and industrial applications are also reviewed.     

Radiation crosslinked polyvinyl alcohol/polyvinyl pyrrolidone/acrylic acid hydrogels: swelling,crosslinking and dye adsorption study

Iranian Polymer Journal - Hydrogels were produced from mixtures of polyvinyl alcohol (PVA), polyvinyl pyrrolidone (PVP), and acrylic acid (AAc) using γ-radiation at doses of 3, 7, and...     

A Smart Wellness Service Platform and Its Practical Implementation

Advances in the field of medical sciences and medical technology, and present-day challenges, such as an aging population, rising medical expenses, and lifestyle-related diseases, have collectively catalyzed a research ecosystem termed “smart wellness.” This article describes the establishment of a smart wellness service platform designed to empower individuals to create a sense of balance in their lives. Step-by-step details include service model, design, and architectural considerations. As a proof of concept, implementation details of a Health Improvement and Management Systems (HIMS) Hub, a Smart Wellness Service Platform deployed in six cities in South Korea, are presented. An on-site survey conducted in Busan Metropolitan City reveals the percentage of satisfied users to be 91.3%. Furthermore, data gathered from 27,236 physical evaluations of users from a Busan city center over the period of April 2013 to May 2018 reveal that males and females in their 50s and 60s account for the highest number of participants, while males in their 70s have a higher rate of participation than females in the same age group.     

Dielectric Constant,Metallization Criterion and Optical Properties of CuO Doped TeO2–B2O3 Glasses

Journal of Inorganic and Organometallic Polymers and Materials - Copper oxide doped TeO2–B2O3 glass system with empirical formula;...     

Investigation on DC/RF Performance of LG = 19 nm Heterogeneous Integrated Ga0.15In0.85As/InAs/Ga0.15In0.85As Composite Channel InP HEMT on Silicon Substrate for Future Beyond 5G and Quantum Computing Applications

Silicon - The RF/DC performances of LG = 19 nm heterogeneous integrated Ga0.15In0.85As/InAs/Ga0.15In0.85As composite channel based InP HEMT (high electron mobility transistor)...