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排序方式: 共有1041条查询结果,搜索用时 112 毫秒
1.
Titus Mulembo Gakuji Nagai Hirohisa Tamagawa Takahiro Nitta Minoru Sasaki 《应用聚合物科学杂志》2019,136(44):48167
Conventional conductive materials face challenges when utilizing them for flexible and wearable electronics and soft robotics. Carbon nanotube/polydimethylsiloxane (CNT/PDMS) composites are a promising alternative to the conventional hard conductors because they are light and can realize large deformation. To date, well dispersion of CNTs into PDMS to increase conductivity while maintaining flexibility remains challenging. We aimed at developing highly electrically conductive and flexible multi-walled carbon nanotube/PDMS (MWCNT/PDMS) composites. To this end, we proposed a method to enhance the dispersion of MWCNTs into PDMS using naphthalene and toluene. Our results showed that the addition of naphthalene and toluene into the composites improved dispersion of the MWCNTs and increased the direct current (DC) electrical conductivity. We also found that the morphology of primary aggregates of the MWCNTs influenced the DC electrical conductivity of the composites. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48167. 相似文献
2.
Minoru Goto 《International Journal of Mechanics and Materials in Design》2018,14(3):313-327
This work reports the characteristics and tribological properties of both Ag/DLC nanocomposite coatings (RF-Ag-DLC) and Cu/DLC nanocomposite coatings (RF-Cu-DLC) with hydrogen-free DLC matrix deposited by RF magnetron sputtering using a concentric composite target (CCT). The CCT consisted of a C base target and metal tablet, and the tablet was located on the center of the base target concentrically where the etching rate by Ar ions is extremely low. By changing the diameter of Ag or Cu tablets in CCT, RF-Ag-DLC with an Ag concentration ranging from 6 to 65 at.% and RF-Cu-DLC with Cu concentration ranging from 7 to 75 at.% can be prepared. These coatings show a granular structure having Ag or Cu nano-crystals with a diameter ranging from 5 to 10 nm dispersed homogeneously in the hydrogen-free DLC matrix. The friction coefficient of DLC varied depending on the species and content of metal. The transition of the friction coefficient became stable when metal-rich tribofilms formed on the counterfaces. 相似文献
3.
Development of Novel Inhibitors for Histone Methyltransferase SET7/9 based on Cyproheptadine 下载免费PDF全文
Dr. Tomoya Hirano Dr. Takashi Fujiwara Dr. Hideaki Niwa Michitake Hirano Kasumi Ohira Yusuke Okazaki Shin Sato Dr. Takashi Umehara Dr. Yuki Maemoto Prof. Akihiro Ito Prof. Minoru Yoshida Prof. Hiroyuki Kagechika 《ChemMedChem》2018,13(15):1530-1540
The histone methyltransferase SET7/9 methylates not only histone but also non‐histone proteins as substrates, and therefore, SET7/9 inhibitors are considered candidates for the treatment of diseases. Previously, our group identified cyproheptadine, used clinically as a serotonin receptor antagonist and histamine receptor (H1) antagonist, as a novel scaffold of the SET7/9 inhibitor. In this work, we focused on dibenzosuberene as a substructure of cyproheptadine and synthesized derivatives with various functional groups. Among them, the compound bearing a 2‐hydroxy group showed the most potent activity. On the other hand, a 3‐hydroxy group or another hydrophilic functional group such as acetamide decreased the activity. Structural analysis clarified a rationale for the improved potency only by tightly restricted location and type of the hydrophilic group. In addition, a SET7/9 loop, which was only partially visible in the complex with cyproheptadine, became more clearly visible in the complex with 2‐hydroxycyproheptadine. These results are expected to be helpful for further structure‐based development of SET7/9 inhibitors. 相似文献
4.
Seiji Yamashita Hideo Watanabe Takashi Shirai Masayoshi Fuji Minoru Takahashi 《Advanced Powder Technology》2011,22(2):271-276
We have successfully synthesized zinc oxide microrods perpendicularly oriented on hexagonal ZnO sheets by a simple heat treatment approach using LDH (layered double hydroxide) precursor in an aqueous solution. The synthesized ZnO microrods have an average diameter of 500 nm and length of 2–3 μm, and form highly-oriented array. In this work, the effect of heating temperature and time on morphology and orientation of ZnO microrods was studied experimentally and the formation mechanism was discussed in detail. Transformation from hexagonal precursor to ZnO microrods can be attributed to dissolution and re-precipitation of the precursor, which should be caused by its thermal unstability under heating temperature. 相似文献
5.
Minoru Morita Yutaka Kuwahara Motonobu Goto 《Journal of Materials Science: Materials in Electronics》2011,22(5):531-537
Electrically conducting adhesive films containing silver nanosized particles (AgNPs) were prepared using siloxane polyimide resin (SPI), and their physical properties were investigated. AgNPs with diameters of ca. 6 nm were prepared using oleylamine as a stabilizer. A mixture of the AgNPs and SPI was vigorously stirred, and cast on a polyethylene terephthalate support. Films were then fabricated using a doctor blade method. The heat resistance of the SPI film containing 60 wt% AgNPs was 35 °C higher than that of the SPI film without AgNPs. In addition, epoxy composite SPIAg (Epo-SPIAg) films containing a mixture of AgNPs and micro-sized silver flakes were prepared. Inclusion of AgNPs in these films strengthened their adhesion to silicon or bismaleimide triazine resin substrates. The glass transition temperature of the Epo-SPIAg films containing AgNPs was slightly higher than that of the film containing only micro-sized silver flakes. 相似文献
6.
Synthesis of non-equilibrium phases in immiscible metals mechanically mixed by high pressure torsion
Tatsuya Miyazaki Daisuke Terada Yoji Miyajima Challapalli Suryanarayana Reiko Murao Yoshihiko Yokoyama Kazumasa Sugiyama Minoru Umemoto Yoshikazu Todaka Nobuhiro Tsuji 《Journal of Materials Science》2011,46(12):4296-4301
The structural changes in mechanically mixed metals of immiscible combinations of elements caused by bulk mechanical alloying
(MA) through the use of high pressure torsion (HPT) were investigated in Ag–Ni and Nb–Zr systems. There was no alloying between
Ag and Ni on atomic scale even after 100 rotations of HPT. On the other hand, the β-Zr phase started to appear after HPT 2
rotations in the Nb–Zr system, even though β-Zr is a high temperature phase. Further, Nb and Zr were completely mixed to form
a bcc structured single phase after HPT 100 rotations. The sequence of alloying in the Nb–Zr system during HPT was discussed.
These results clearly suggest that non-equilibrium phases can form in the Nb–Zr system by bulk MA by the use of HPT. 相似文献
7.
Lead-bismuth eutectic (LBE) is a candidate coolant for fast reactors. Its physical, chemical and neutronic properties make it a prospect coolant for the reactors. However, corrosion of structure is the main problem of utilizing LBE as a coolant. Compatibility of welded structure with LBE at high temperature should be considered clearly for feasibility of lead-bismuth-cooled fast reactors. This study was preformed to investigate the mechanical properties and corrosion characteristics of the welded ferritic-martensitic (FM) steel, HCM12A, in LBE at 650 °C for 500 h. The welding methods were TIG welding (137 mm/min; 480 W), YAG laser welding (780 mm/min; 287 W) and electron beam welding (1000 mm/min; 60 kW). The oxygen concentration of test environment was maintained at 7 x 10−7 wt% by injecting Ar-H2-steam gas mixture. Vickers hardness test and SEM/EDX analysis were conducted on the cross section of welded HCM12A. It was found that oxide layer was larger in the weld zones than base metal (BM). However, outer layer was detached on some areas. 相似文献
8.
A corrosion test was conducted to investigate the corrosion characteristics of SiC and Si3N4 in a flowing lead-bismuth eutectic (Pb-Bi) with a fluid temperature of 550 °C, a velocity of 1 m/s, and an oxygen concentration of 1 × 10−6 wt% for an exposure time of 2000 h. The weight losses of the SiC and Si3N4 specimens were lower than those of corrosion-resistant steels tested under the same condition. The specimens showed excellent resistance against an element dissolution and an oxidation in the Pb-Bi flow. The surface was slightly damaged due to some stresses of the Pb-Bi flow and/or those generated by adhered Pb-Bi in the test procedure. 相似文献
9.
Martensitic stabilization caused by deformation in a TiNi shape memory alloy was studied.Special attention was paid to the deformed microstructures to identify the cause of martensitic stabilization.Martensitic stabilization was demonstrated by differential scanning calorimetry for the tensioned TiNi shape memory alloy.Transmission electron microscopy revealed that antiphase boundaries were formed because of the fourfold dissociation of[110]B19'super lattice dislocations and were preserved after reverse transformation due to the lattice correspondence.Martensitic stabilization was attributed to dislocations induced by deformation,which reduced the ordering degree of the microstructure,spoiled the reverse path from martensite to parent phase compared with thermoelastic transformation,and imposed resistance on phase transformation through the stress field. 相似文献
10.
Shoichi MATSUDA Naomichi SAJI Minoru YAGA Masaaki ISHIKAWA Kenyu OYAKAWA 《热科学学报(英文版)》2010,19(3):228-233
This paper will present the characteristics of flow behavior and thermal field of both free and
impingement jet issued from a circular orifice nozzle at Re=8900.The flow behavior of a single round
jet and impingement jet was observed by smoke flow visualization recorded by a high speed camera
using 5000 frame per second.Heat transfer coefficient on the impingement surface was measured by
means of infrared camera (TVS-8500,Avio) with a two-dimensional array of Indeum-Antimony (In Sb)
sensors varying in the separation distance between the nozzle and the target plate.The heat transfer
coefficient changes in time and spatial.Therefore,the root mean square distribution of the heat
transfer was obtained from the data.As a result,it was confirmed that the longitudinal vortex was
observed outside of the ring vortex,and then the longitudinal vortex was penetrated in the jet
flow.Moreover,the high value of root mean square of the heat transfer coefficient has spread radially
in stripy manner,which is caused as the results of the longitudinal vortexes flowing in the radial
direction on the impingement plate. 相似文献
impingement jet issued from a circular orifice nozzle at Re=8900.The flow behavior of a single round
jet and impingement jet was observed by smoke flow visualization recorded by a high speed camera
using 5000 frame per second.Heat transfer coefficient on the impingement surface was measured by
means of infrared camera (TVS-8500,Avio) with a two-dimensional array of Indeum-Antimony (In Sb)
sensors varying in the separation distance between the nozzle and the target plate.The heat transfer
coefficient changes in time and spatial.Therefore,the root mean square distribution of the heat
transfer was obtained from the data.As a result,it was confirmed that the longitudinal vortex was
observed outside of the ring vortex,and then the longitudinal vortex was penetrated in the jet
flow.Moreover,the high value of root mean square of the heat transfer coefficient has spread radially
in stripy manner,which is caused as the results of the longitudinal vortexes flowing in the radial
direction on the impingement plate. 相似文献