Flexible poly(styrene-ethylene-butadiene-styrene) hybrid nanofibers for bioengineering and water filtration applications

Among the thermoplastic elastomers that play important roles in the polymer industry due to their superior properties, styrene-based species and polyurethane block copolymers are of great interest. Poly(styrene-ethylene-butadiene-styrene) (SEBS) as a triblock copolymer seems to have the potential to meet many demands in different applications due to various industrial requirements where durability, biocompatibility, breaking elongation, and interfacial adhesion are important. In this study, the SEBS triblock copolymer was functionalized with natural (Satureja hortensis, SH) and synthetic (nanopowder, TiO₂) agents to obtain composite nanofibers by electrospinning and electrospraying methods for use in biomedical and water filtration applications. The results were compared with thermoplastic polyurethane (TPU) composite nanofibers, which are commonly used in these fields. Here, functionalized SEBS nanofibers exhibited antibacterial effect while at the same time improving cell viability. In addition, because of successful water filtration by using the SEBS composite nanofibers, the material may have a good potential to be used comparably to TPU for the application.     

An experimental evaluation of visual similarity for HDR images

In this paper, we investigate visual similarity for high dynamic range (HDR) images. We collect crowdsourcing data through a web-based experimental interface, in which the participants are asked to choose one of the two candidate images as being more similar to the query image. Triplets forming the query-and-candidates sets are obtained by random sampling from existing HDR data sets. Experimental control factors include choice of tone mapping operator (TMO), choice of distance metric, and choice of image feature. The image features that we experiment with are chosen from the features that are commonly used in the usual low dynamic range setting including features learned via Convolutional Neural Networks. The set of image features also includes combined features where the combination coefficients are estimated using logistic regression. We compute correlations between human judgments and quantitative features to understand how much each feature contributes to visual similarity. Combined features yield nearly 84% agreement with human judgments when applied on tone mapped images. Though we observed that using common features directly on raw or linearly scaled HDR images yield subpar correlation estimates compared to using them on tone mapped HDR images, we did not observe significant effect due to the choice of TMO on the estimates. As an application, we propose an improvement to style-based tone mapping for more correctly imparting desired styles to HDR images with different characteristics.

     

Evaluation of a university website’s usability for visually impaired students

Today websites are the tools most commonly used to access information. People with disabilities face difficulties accessing or using information, and the importance of website usability in their lives needs to be recognized. Visually impaired students need to be able to use university websites that inform them about the opportunities and events taking place on campus. This study aims to evaluate the usability of a university website by visually impaired students. In this research, six visually impaired students were interviewed. The assistive technologies they use, as well as the various web pages they wished to use unaided were identified. Following data collection, usability tests were conducted and satisfaction surveys were completed. The usability test was done with five visually impaired students. They were asked to think aloud while performing 11 tasks involving their university’s web pages, including the main page and the pages of student affairs, library and departments and then to accomplish these tasks. In this test, five tasks were not successfully completed by all students. According to the test results, finding final exam dates on the academic calendar posed major difficulties, and accessing the course schedule web page was the task that required the most time. The test results indicated the need for a search engine on each page, a text version for all pages, rearrangement of the web link sequences with tabs and more information about visuals. Suggestions related to the visually impaired students’ needs were offered.     

The use of basalt powder as a natural heterogeneous catalyst in the Fenton and Photo-Fenton oxidation of cationic dyes

The use of naturally present heterogeneous catalysts has recently been an essential issue in the Fenton and photo-Fenton processes. In this study, the uses of basalt as a catalyst for the Fenton and photo-Fenton reactions for methylene Blue (MB) and Basic Red 18 (BR18) degradations were investigated. Basalt was selected because of the presence of the iron (III) oxide in the structure. Basalt was characterized by X-Ray Fluorescence (XRF) and X-Ray Diffraction (XRD) analysis to obtain the chemical composition and the crystalline phase. The surface charge and the surface area were obtained by zeta potential and Brunauer Emmett-Teller (BET) analysis. Fourier Transform Infrared Spectroscopy (FTIR) and scanning electron microscope (SEM) were utilized to explore the functional group and the surface morphology. Fenton and photo-Fenton processes were applied to explore the best degradation method. Adsorption was also tested and the adsorption process had minimum removal efficiency (12% for MB and 17% for BR18). The removal efficiencies for MB and BR18 by the Fenton process were 87% and 28%, respectively. The photo-Fenton process had maximum removal efficiency with 100% for MB and 70% for BR18. The optimum conditions were 70 mg/L dye concentration, 5 mM H₂O₂, 1.0 g/L basalt loading and pH 2. Basalt has shown reuse capability as a catalyst for three consecutive cycles.     

Efficient manganese decorated cobalt based catalysts for hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) biofuel

2,5-dimethylfuran (DMF) is a promising compound in the production of biofuel with high-quality properties. In this study, it is aimed to develop new efficient catalysts to synthesize DMF from 5-hydroxymethylfurfural (HMF). Co, Mn/Co, and Ru/Co catalysts were prepared using the NaBH₄ reduction method. The catalysts were subjected to activity tests for the hydrogenation of HMF to DMF by changing the reaction parameters, such as temperature and time. Mn/Co catalysts prepared from metal precursors at various molar ratios of Mn/Co were found to be effective in hydrogenation reactions of HMF to DMF. A 91.8% DMF yield was achieved in the presence of a Mn/Co (50/50) catalyst without noble metal at 180°C for 4 hours. The Brunauer-Emmet-Teller (BET) method, x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), and induction coupled plasma mass spectroscopy (ICP-MS) techniques were used to characterize the efficient Mn/Co catalyst.     

Effects of ethanol,formaldehyde, and gentle heat fixation in confocal resonance Raman microscopy of purple nonsulfur bacteria

Resonance Raman microscopy is well suited to examine living bacterial samples without further preparation. Therefore, comparatively little thought has been given to its compatibility with common fixation methods. However, fixation of cell samples is a very important tool in the microbiological sciences, allowing the preservation of samples in a specific condition for further examination, future measurements, transport, or later reference. We examined the effects of three common fixatives—ethanol, formaldehyde solution, and gentle heat—on the resonant Raman spectrum of three generic bacteria species, Rhodobacter sphaeroides DSM 158^T, Rhodopseudomonas palustris DSM 123^T, and Rhodospirillum rubrum DSM 467^T, holding carotenoid‐ and heme‐chromophores in confocal Raman microscopy. In addition, we analyzed the effect of poly‐L ‐lysine coating of microscope slides, widely used for mounting biological and medical samples, on subsequent confocal Raman measurements of native and fixed samples. The results indicate that ethanol is preferable to formaldehyde as fixative if applied for less than 24 h, whereas heat fixation has a strong, detrimental effect on the resonant Raman spectrum of bacteria. Formaldehyde fixation excels at fixation times above 24 h, but causes an overall reduction in signal intensity. Poly‐L ‐lysine coating has no discernable effect on the Raman spectra of samples fixed with ethanol or heat, but it further decreases the signal intensity, especially at higher wavenumbers, in the spectra of samples fixed with formaldehyde. Microsc. Res. Tech. 74:177–183, 2011. © 2010 Wiley‐Liss, Inc.     

Fracture load and microcrack comparison of crowns manufactured from tooth‐shaped and traditional blocks

This study intended to analyze microcracks and fractographic markings on the surface of all ceramic crowns after milling and compare the fracture loads. 90 crowns were manufactured from two feldspathic (Priticrown‐Pr and Vita Mark II‐Vi) and a lithium disilicate (EmaxCAD‐Em) blocks (n = 30). Two groups (n = 15) were prepared for each ceramic. In the first group, crowns were analyzed twice via the fluorescent penetrant method for microcrack detection, after the manufacturing process and thermal cycles. The load to fracture test was applied at a crosshead speed of 0.5 mm/min until catastrophic failure. Second group crowns were directly cemented onto the Co‐Cr dies following the manufacturing process and loaded to fracture. Fractographic markings were analyzed through scanning electron microscope. Spearman correlation analysis, Kruskal–Wallis H test, Mann–Whitney U test, and Wilcoxon Signed Rank test were applied (α = .05). Fracture loads of Em crowns were higher than other groups (p < .05), with and without the aging procedure. Except for second group Pr (r = ?.532), no significant relationship was found between microcrack numbers and fracture loads (p > .05). Thermal cycling did not affect microcrack numbers and fracture loads (p > .05). Tooth‐shaped multilayered Pr blocks did not provide an advantage in terms of microcrack and fracture loads.     

Comparison of the effects of different retention appliances on the oxidant–antioxidant system

The aim was to compare oxidative stress (OS) levels with different types of retention appliance. Thirty orthodontic patients were divided into three groups: Group 1 (Essix retainer), Group 2 (lingual retainer with stainless steel retainer wire), and Group 3 (lingual retainer with fiber-reinforced material). OS was assessed in the subjects’ saliva. Saliva samples were taken from the patients at T₀ (before using the retention appliance), T₁ (first month of retention), and T₂ (third month of retention). The specimens were investigated to detect changes in total antioxidant status (TAS), total oxidant status (TOS), and oxidative stress index (OSI). TAS values in Group 2 were significantly higher than in Group 3. TOS values in Group 3 were significantly lower than in the other groups. TOS values in Group 2 were lower than in Group 1. OSI values of Group 1 were higher than those in Group 2 or 3. There was no statistically significant difference among the time periods. The type of retention appliance affected OS values. A fiber-reinforced material may have a lower OSI. OS or products can affect some systemic disease; therefore, the selection of the retainer will be important on these patients.