Authenticity green coffee bean species and geographical origin using near-infrared spectroscopy combined with chemometrics

To prevent the adulteration of agricultural resources and provide a solution to enhance the green coffee bean supply chain, authentication using the near-infrared spectroscopy (NIRS) technique was investigated. Partial least square with discrimination analysis (PLS-DA) models combined with various preprocessing methods were built from NIR spectra of 153 Vietnamese green coffee samples. The model combined with the standard normal variate and the first order of derivative yielded excellent performance in predicting coffee species with the error cross-validation of 0.0261. PLS-DA model of mean centre and first-order derivative spectra also yielded good performance in verifying geographical indication of green coffee with the error of 0.0656. By contrast, the predicting abilities of post-harvest methods were poor. The overall results showed a high potential of the NIRS in online authentication practices.     

Mechanical properties of continuous bamboo fiber-reinforced biobased polyamide 11 composites

This study is devoted to the analysis of the properties of continuous bamboo fiber (BF)-reinforced polyamide 11 (PA 11) composites. The SEM observations highlighted continuity between BFs and the polymeric matrix showing a high density of hydrogen bonds. The comparative calorimetric study of the matrix and its composites showed that the crystallinity of PA 11 was not modified by the presence of bamboo fibers. The physical aging observed in PA 11 is no more observed in composites due to physical interactions between PA 11 and BFs. The mechanical properties were investigated by tensile strength and dynamic mechanical analysis. The introduction of BFs enhanced Young's modulus of the matrix by a factor of 10. The presence of BFs also improved the storage shear modulus G′ over the whole temperature range. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47623.     

A geometrically nonlinear size-dependent hypothesis for porous functionally graded micro-plate

The static bending behavior of porous functionally graded (PFG) micro-plate under the geometrically nonlinear analysis is studied in this article. A small-scale nonlinear solution is established using the Von-Kármán hypothesis and the modified couple stress theory (MCST). To obtain the deflection of the plate, the Reddy higher-order plate theory coupled with isogeometric analysis (IGA) is utilized. The distribution of porosities is assumed to be even and uneven across the plate’s thickness and the effective material properties of porous functionally graded micro-plate are calculated using the refined rule-of-mixture hypothesis. The influence of power index, porosity parameter and material length scale parameter on the nonlinear behaviors of static bending of porous FGM micro-plates are also investigated using several numerical examples.

     

A cross-layer analysis of TCP/link adaptation technologies over free-space optical links with Markov error model

This paper presents a comprehensive cross-layer framework on the performance of transmission control protocol (TCP) over a free-space optical (FSO) link, which employs automatic repeat request (ARQ) and adaptive modulation and coding (AMC) schemes. Not similar to conventional works in the literature of FSO, we conduct a Markov error model to accurately capture effects of burst errors caused by atmospheric turbulence on cross-layer operations. From the framework, we quantify the impacts of different parameters/settings of ARQ, AMC, and the FSO link on TCP throughput performance. We also discuss several optimization aspects for TCP performance.     

Fabrication of tungsten oxide photoanode by doctor blade technique and investigation on its photocatalytic operation mechanism

WO₃ is a potential material candidate for construction of photoanode for solar driven water splitting. In this work, μm-thick porous WO₃ photoanode is prepared by depositing a stable ink made of WO₃ nanoparticles and Aristoflex velvet polymer in water using the doctor blade technique, followed by a sintering in air. The nature of WO₃ nanoparticles, its loading mass on F-doped tin oxide electrode as well as sintering temperature are examined in order to optimize the photocatalytic activity of the resultant WO₃ photoanode. The operation of WO₃ photoanode is investigated by varying the light illumination direction and light incident intensity as well as changing the nature of the electrolyte. Dissolved tungsten in electrolyte is quantified by ICP-MS providing insights into the influences of electrolyte nature and operating conditions to the corrosion of WO₃. It is proposed that the H₂O₂ and OH^. radical generated as by-products of the photo-driven water oxidation on the photoanode surface are harmful species that accelerate the dissolution of WO₃.     

Performance Analysis of Full-Duplex Vehicle-to-Vehicle Relay System over Double-Rayleigh Fading Channels

Mobile Networks and Applications - In this paper, we study the performance of a full-duplex (FD) relay system in vehicle-to-vehicle (V2V) communication. In this relay communication system, the...     

Experimental and optimization of material synthesis process parameters for improving capacity of lithium‐ion battery

New methods for synthesis of active materials have been developed to improve capacity and cycle life performance of lithium‐ion batteries. Past studies have focused on routes of development of materials and new processes, which might not be economical for large‐scale production. In this regard, this study examines a widely employed carbothermal reduction technology for the synthesis of lithium‐iron phosphate (LiFePO₄/C) and investigates effects of process conditions during this synthesis on final battery performance. An experimental combined genetic programming approach is used to model the effects of crucial process conditions (sintering time, the carbon content, and the sintering temperature) on the discharge capacity of the assembled battery. Experiments are conducted to collect the discharge capacity data based on varying LiFePO₄/C synthesis conditions, and genetic programming is employed to develop a suitable functional relationship between them. The results show that the battery discharge capacity is controlled significantly by adjusting sintering temperature and carbon content, while the effect of sintering time is found to be insignificant. Further, the interaction effect of the sintering time and carbon content is much more obvious than that of the sintering time and the sintering temperature. The findings from the study pave the way for the optimum design of the synthesis process of LiFePO₄/C for a higher battery performance.     

The efficient lignocellulose-based sorbent for oil spill treatment from polyurethane and agricultural residue of Vietnam

In this study, new and efficient sorbent with density 0.2 g/cm³ was fabricated by incorporating rice straw into polyurethane matrix to get an open cell structure material with high oil uptake capacity. The influences of various important factors such as amount of adding rice straw, size of rice straw particles, and adsorption time on oil adsorption capacity of new sorbent material were investigated. The results showed that the oil absorption rate occurred fast in first 15–30 min, then slowed down and reached saturation level after about 2 h of treatment. Oil adsorption capacity of the new sorbent material was relatively high, up to 12.0 g/g. In comparison with pristine polyurethane or lignocellulosic materials, the new sorbents had higher oil adsorption capacity. Some characteristics of the as-obtained sorbent, such as surface shapes and porosity, were also studied by SEM analysis.     

Particle size distribution and homogenisation efficiency in high-pressure homogenisation of wheat germ oil-water system

Wheat germ oil (WGO) is well-known as a good source of vegetable oil due to its nutrients and health benefits. Emulsification is a process that improves the incorporation of oil into food. High-pressure homogenisation (HPH) is a nonthermal and soft technique with enormous potential in oil-in-water emulsification. This paper focussed on the application of HPH for emulsification of WGO-in-water system. Influences of homogenisation pressure (100–300 bar), oil fraction (10–20% v/v) and lecithin adding (0–0.2% w/v of content) on the homogenisation were evaluated based on distribution of particles diameter and homogenisation efficiency. The increase in operating pressure and lecithin ratio decreased the particle size and increased the emulsion stability, and vice versa for oil fraction. The findings imply that the investigated factors significantly influenced particle size and emulsion system stability. The regression model between mean particle diameter and technical conditions of emulsion was established. With HPH treatment conditions of 300 bar operating pressure, 10% (v/v) oil fraction and 0.2% (w/v) lecithin created an emulsion system with a mean particle size of 3.32 µm, more than 50% of the volume of particles smaller than 1.5 µm of diameter and the homogenisation efficiency of 98.61%. HPH exhibits high efficiency and potential in WGO-in-water emulsification application.