Fully renewable limonene‐derived polycarbonate as a high‐performance alkyd resin

Limonene‐derived polycarbonate‐based alkyd resins (ARs) have been prepared by copolymerization of limonene dioxide with CO₂, catalysed by a β‐diiminate zinc–bis(trimethylsilyl)amido complex, and subsequent chemical modification with soybean oil fatty acids using triphenylethylphosphonium bromide as the catalyst. This quantitative partial modification was realized via epoxy–carboxylic acid chemistry, affording ARs with higher oil lengths, lower polydispersities and higher glass transition temperatures (T_g) in comparison to a conventional polyester AR based on phthalic acid, multifunctional polyol pentaerythritol and soybean fatty acid. The novel limonene polycarbonate AR and the conventional polyester AR were evaluated as coatings and both the physical drying (without the presence of the oxidative drying accelerator Borchi® Oxy Coat) and chemical curing (with Borchi® Oxy Coat) processes of these coatings were monitored by measuring the König hardness and complex modulus development with time. A better performance was obtained for the alkyd paint containing polycarbonates modified with fatty acids (FA‐PCs), which showed a faster chemical drying, a higher König hardness and a higher T_g in coating evaluation, demonstrating that the fully renewable FA‐PCs are promising resins for alkyd paint applications. © 2019 Society of Chemical Industry     

Adaptive reuse of office buildings into housing: opportunities and risks

One way of adapting and reusing vacant office buildings is conversion into housing. Former research has shown possibilities for this type of conversion, and has delivered instruments for determining the conversion potential of vacant offices. Although adaptation and renovation of outdated offices can prove to be a successful property (real estate) strategy, conversions into housing still only occur on a small scale. There are several reasons for this, including uncertainty about financial feasibility and little knowledge about the opportunities and risks of building conversions. A meta-study of the conversion of 15 office buildings into housing in the Netherlands is used to reveal the drivers for office-to-housing conversions as well as the opportunities and risks that arise in the conversion process. The findings show that various legal, financial, technical, functional and architectonic issues define the opportunities and risks of building conversions. These insights can be used to support the decision-making processes for dealing with vacant office buildings in order to minimize the risks and increase the opportunities.     

Effect of calcium and/or barium crosslinking on the physical and antimicrobial properties of natamycin-loaded alginate films

The preparation of alginate films with suitable properties requires a two-step contact with reticulating agents: initially a weakly structured pre-film is formatted which is further crosslinked in a second stage by immersion in a more concentrated solution. The present work evaluated the effects of a combined crosslinking procedure using calcium and barium ions on the physical and morphological properties of alginate-based films containing natamycin as antimicrobial agent. The release behavior of natamycin in water was evaluated as well as the antimicrobial activity against four target microorganisms, which are common cheese product contaminants. Films attributes were affected by the type of ion used in the second stage while the natamycin release rate and the antimicrobial activity were influenced by the ion used in the first stage. Films crosslinked with Ba²⁺ in the first and Ca²⁺ in the second stage (Ba–Ca films) exhibited physical properties very similar to films crosslinked with calcium in both stages. Release kinetics of natamycin in water fitted well to Fick's second law diffusional model, with effective diffusivity values ranging from 0.40 × 10⁻¹¹ to 1.74 × 10⁻¹¹ cm²/s. Ba–Ca films presented the lowest natamycin diffusion coefficient and the smallest inhibition zone diameter against the four microorganisms tested.     

Color preferences for different topics in connection to personal characteristics

Studies on color preferences are dependent on the topic and the relationships with personal characteristics, particularly personality, but these are seldom studied in one population. Therefore a questionnaire was collected from 1095 Dutch people asking for color preferences about different topics and relating them to personal characteristics. Color preferences regarding different topics show different patterns and significant differences were found between gender, age, education and personality such as being technical, being emotional or being a team player. Also, different colors were mentioned when asked for colors that stimulate to be quiet, energetic, and able to focus or creative. Probably, due to unconsciousness of contexts, many people had no color preference, a result that in the literature seldom is mentioned. Blue was the overall favorite color; however, most males chose for blue (25%) while most females had no color preference (18%). Black was the overall favorite color for clothing, mainly chosen by females (40%), while males primarily chose blue (27%). For building interiors subjects preferred white. For moods, subjects preferred white for being quiet or being able to focus, red for being energetic and had no color preference for being creative. It is concluded that color preferences are dependent upon the topic, and personal characteristics. The findings are important for architects, interior designers, fashion designers and product designers to have a basic idea of preferred colors for different objects by different types of people. © 2013 Wiley Periodicals, Inc. Col Res Appl, 40, 62–71, 2015     

Genetic Deficiency and Pharmacological Stabilization of Mast Cells Ameliorate Pressure Overload-Induced Maladaptive Right Ventricular Remodeling in Mice

Although the response of the right ventricle (RV) to the increased afterload is an important determinant of the patient outcome, very little is known about the underlying mechanisms. Mast cells have been implicated in the pathogenesis of left ventricular maladaptive remodeling and failure. However, the role of mast cells in RV remodeling remains unexplored. We subjected mast cell-deficient WBB6F1-KitW/W-v (Kit^W/Kit^W-v) mice and their mast cell-sufficient littermate controls (MC^+/+) to pulmonary artery banding (PAB). PAB led to RV dilatation, extensive myocardial fibrosis, and RV dysfunction in MC^+/+ mice. In PAB Kit^W/Kit^W-v mice, RV remodeling was characterized by minimal RV chamber dilatation and preserved RV function. We further administered to C57Bl/6J mice either placebo or cromolyn treatment starting from day 1 or 7 days after PAB surgery to test whether mast cells stabilizing drugs can prevent or reverse maladaptive RV remodeling. Both preventive and therapeutic cromolyn applications significantly attenuated RV dilatation and improved RV function. Our study establishes a previously undescribed role of mast cells in pressure overload-induced adverse RV remodeling. Mast cells may thus represent an interesting target for the development of a new therapeutic approach directed specifically at the heart.     

Continuously Changing Information on a Global Scale and its Impact for the Internet-of-Things

This article analyzes the challenges of supporting continual changes of context information in Internet-of-Things applications. These applications require a constant flow of continuously changing information from sensor based sources in order to ensure a high quality-of-experience. However, an uncontrolled flow between sources and sinks on a global scale wastes resources, such as computational power, communication bandwidth, and battery time. In response to these challenges we present a general approach which focuses on four layers where we provide a proposed solution to each layer. We have realized the general model into a proof-of-concept implementation running on devices with limited resources, where we can moderate the information exchange based on relevance and sought after quality-of-experience by the applications. In conclusion, we evaluate our solution and present a summary of our experiences regarding the impact of continuously changing information on the Internet-of-Things.     

Gender bias in journals of gender studies

The causes of gender bias favoring men in scientific and scholarly systems are complex and related to overall gender relationships in most of the countries of the world. An as yet unanswered question is whether in research publication gender bias is equally distributed over scientific disciplines and fields or if that bias reflects a closer relation to the subject matter. We expected less gender bias with respect to subject matter, and so analysed 14 journals of gender studies using several methods and indicators. The results confirm our expectation: the very high position of women in co-operation is striking; female scientists are relatively overrepresented as first authors in articles. Collaboration behaviour in gender studies differs from that of authors in PNAS. The pattern of gender studies reflects associations between authors of different productivity, or ??masters?? and ??apprentices?? but the PNAS pattern reflects associations between authors of roughly the same productivity, or ??peers??. It would be interesting to extend the analysis of these three-dimensional collaboration patterns further, to see whether a similar characterization holds, what it might imply about the patterns of authorship in different areas, what those patterns might imply about the role of collaboration, and whether there are differences between females and males in collaboration patterns.     

A micromechanically motivated finite element approach to the fracture toughness of silicon nitride

Silicon nitride is often used, when high fracture toughness and strength is needed. For a safe and economic structural design with this material, a prediction of its resistance against thermal and mechanical loads is important. The finite element method together with a continuum damage mechanics model allows for such calculations. The parameters of the suggested model have been adjusted to three-dimensional micromechanical finite element simulations, which include models for the microstructure, the thermoelasticity and the fracture. The material model is used for four-point bend test simulations. The results are compared to recent experiments.