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排序方式: 共有195条查询结果,搜索用时 15 毫秒
1.
Nanako Ueda Miroslava Vernerová Jaroslav Kloužek Pavel Ferkl Pavel Hrma Tetsuji Yano Richard Pokorný 《Journal of the American Ceramic Society》2021,104(1):34-44
Understanding the batch-to-glass conversion process is fundamental to optimizing the performance of glass-melting furnaces and ensuring that furnace modeling can correctly predict the observed outcome when batch materials or furnace conditions change. To investigate the kinetics of silica dissolution, gas evolution, and primary foam formation and collapse, we performed X-ray diffraction, thermal gravimetry, feed expansion tests, and evolved gas analysis of batch samples heated at several constant heating rates. We found that gas evolving reactions, foaming, and silica dissolution depend on the thermal history of the batch in a similar manner: the kinetic parameters of each process were linear functions of the square root of the heating rate. This kinetic similarity reflects the stronger-than-expected interdependence of these processes. On the basis of our results, we suggest that changes in furnace operating conditions, such as firing or boosting, influence the melting rate less than what one would expect without consideration of batch conversion kinetics. 相似文献
2.
Arsenic is present at high concentrations in the upper layer of Lake Biwa sediments and shows a depth profile similar to that of Mn. Adsorption experiments of As onto synthetic hydrous Mn oxide (HMO) in the presence of Mn2+ and the speciation of Mn in the sediment cores, suggest that the accumulation of As at the sediment surface results from post-depositional migration of arsenite in the sediment pore water followed by oxidation to arsenate at the sediment surface and adsorption onto Mn2+-rich HMO. 相似文献
3.
4.
Yasushi Sekine Haruka Takamatsu Sho Aramaki Kazuki Ichishima Mitsuko Takada Masahiko Matsukata Eiichi Kikuchi 《Applied Catalysis A: General》2009,352(1-2):214-222
The water gas shift (WGS) reaction over Pt and Pd catalysts supported on various perovskite oxides has been investigated at 573 K without catalyst pretreatment. The Pt and Pd catalysts on LaCoO3 support showed high catalytic activity. Interaction between Pt or Pd and the support is considered to promote the WGS reaction: Pt/LaCoO3 had high initial activity but deactivated immediately; Pd/LaCoO3 was less active than Pt/LaCoO3, but had superior stability. Catalysts were characterized using XRD, STEM, XPS, and H2-temperature programmed reduction (TPR). Results of this study showed that reduction of the support decreased the CO conversion on Pt/LaCoO3. On the other hand, Pd/LaCoO3 showed stable activity for the WGS reaction. Therefore, Pd was added to Pt/LaCoO3 for stabilizing the catalyst activity, and 0.5 wt.% Pd/1 wt.% Pt/LaCoO3 catalyst showed higher activity and stability. 相似文献
5.
Shinnosuke Miyauchi Yasuo Hattori Toshiyuki Takamatsu Yoshio Sorimachi 《应用聚合物科学杂志》1992,44(3):377-381
A method to generate a porous region near the surface of a polymer is suggested. In this method the region near the surface is swollen by immersing the polymer for a short time in a solvent. Subsequently, the polymer is introduced in a nonsolvent (for the polymer) that is, however, miscible with the solvent. The formation of the porous region is a result of (1) the swelling accompanied by the disentanglement of the surface molecular chains, and the dissolution of some of them during the immersion in the solvent, and (2) the rapid extraction of the solvent from the swollen region by the nonsolvent. The porous surface provides a matrix into which a second incompatible monomer can be polymerized so that the two otherwise incompatible polymers can adhere to one another. 相似文献
6.
We have developed a reel-to-reel microchip mounting system that continuously mounts LED chips and other microchips on meter-long flexible printed circuit board (PCB) tape for 1.2-m-long standard LED light tubes. Mounting microchips on meter-long PCBs is difficult because a large chip mounter is expensive and the chip positioning stage is difficult to move in a meter-wide area with an accuracy of hundreds of micrometers. Hence, we developed a new microchip mounting system that utilizes a small chip mounter and reel winding machines. The system repeatedly moves the long PCB tape by a certain length with the reel winding machines and mounts the chips on it. The PCB tape (which is 5 mm wide) is made by fabricating long PCB tapes which are 25 cm × 26.6 m through a roll-to-roll PCB process and slitting them into meter-long tapes. The reel-to-reel system repeatedly mounts chips by adjusting their positions through image processing of the copper wiring pattern on the PCBs. Our constructed system mounted 24 LED chips with a pitch of 5 cm with an accuracy of 0.082 mm to form a 1.2-m-long LED tape. The luminance of the tape is 12.4 lx at a distance of 1 m, which is the luminance of outdoor corridor lighting. Therefore, this system can be used for meter-long tape lighting. 相似文献
7.
8.
Hideo Noda Takeichiro Takamatsu Kazumasa Aso Tosinari Nakanishi Kazufumi Yoshida Masaru Nakaiwa Tadahiro Mukaida Nobuyuki Kuratani 《Korean Journal of Chemical Engineering》2000,17(5):593-596
Various configurations of a column for performing the principle of HIDiC can be proposed, but a coaxial column which is installed
a packing in an inside tube and outer side may be one of the simplest columns for HIDiC. In order to examine whether or not
the configuration of the packed column mentioned above is appropriate to HIDiC, an experimental apparatus has been set up
and heat and mass transfer rates have been measured by using benzene-toluene system.
This paper was presented at The 5th International Symposium on Separation Technology-Korea and Japan held at Seoul between
August 19 and 21, 1999. 相似文献
9.
Abstract The use of IrOx for electrodes in PbZrxTi1?xO3 (PZT) capacitors for ferroelectric memory applications has proven to be advantageous in several respects. In comparison with Pt, IrOx often exhibits improved fatigue and provides resistance to hydrogen induced degradation at elevated temperatures. Since IrOx is often produced by sputtering in an oxygen containing environment, several forms of IrOx can be produced depending on the process conditions. This work concentrates on an analysis of the DC reactive sputtering of IrOx from an Ir metal target. As with other oxidizable metals, Ir exhibits a transition between metal and oxide mode sputtering when sputtered in oxygen containing atmospheres. Variations in the Ar/O2 gas flow ratio were used to produce Ir and IrOxfilms on both sides of the metal-to-oxide mode reactive sputtering transition. Changes in the IrOx film properties were quantified by using a combination of metrics including X-ray diffraction, sheet resistance, and stress. It was found that the, IrOx crystalline structure and other IrOx properties could be directly related to the ferroelectric switching performance of PZT capacitors with IrOxtop electrodes. A relationship between IrOx deposition processes and resistance to etch induced damage of the ferroelectric properties was also observed. 相似文献
10.
Y Okamoto T Yamazaki A Katsumi T Kojima J Takamatsu M Nishida H Saito 《Canadian Metallurgical Quarterly》1996,75(6):877-882
The genetic defect in a patient with hereditary type I protein S (PS) deficiency was investigated. All the exons and intron-exon junctions of the patient's PS gene were amplified by PCR and subjected to heteroduplex screening. Only the PCR product of exon 4 revealed heteroduplex bands. A novel nonsense mutation, Ser62 (TCA) to Stop (TGA) was found in exon 4. RT-PCR detected the aberrant mRNA in the patient's platelets, which was markedly reduced in amount and lacked the region of exon 4, suggesting that the nonsense mutation affected the mutated mRNA metabolism and induced exon skipping. The skipping of exon 4 causes an in-frame deletion of 29 amino acids which just construct the thrombin-sensitive region of the PS molecule. The loss of such an important domain as well as the quantitative decrease in the mutated mRNA appear to be responsible for the type I PS deficiency in this patient. 相似文献